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<front>
<journal-meta>
<journal-id journal-id-type="publisher-id">IJFS</journal-id>
<journal-title-group>
<journal-title>Italian Journal of Food Science</journal-title>
<abbrev-journal-title>IJFS</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1120-1770</issn>
<publisher>
<publisher-name>Codon Publications</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="publisher-id">IJFS-37-3256</article-id>
<article-id pub-id-type="doi">10.15586/ijfs.v37i4.3256</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>SURVEY</subject>
</subj-group>
</article-categories>
<title-group>
<article-title>Streamlined life cycle assessment of packaging waste in coffee preparation and consumption</article-title>
</title-group>
<contrib-group content-type="authors">
<contrib contrib-type="author" corresp="yes"><name><surname>Moresi</surname> <given-names>Mauro</given-names></name><xref ref-type="aff" rid="aff1">1</xref><xref ref-type="aff" rid="aff2">2</xref><xref ref-type="corresp" rid="cor1"/></contrib> 
<contrib contrib-type="author"><name><surname>Cimini</surname> <given-names>Alessio</given-names></name><xref ref-type="aff" rid="aff2">2</xref></contrib>
<aff id="aff1"><label>1</label>Accademia dei Georgofili, Firenze, Italy;</aff>
<aff id="aff2"><label>2</label>Department for Innovation in the Biological, Agrofood and Forestry Systems, University of Tuscia, Viterbo, Italy</aff>
</contrib-group>
<author-notes>
<corresp id="cor1"><label>&#x002A;</label><bold>Corresponding Author:</bold> Mauro Moresi, Accademia dei Georgofili, Firenze, Italy. Email: <email>mmoresi@unitus.it</email></corresp>
<fn id="afn01"><p><bold>Academic Editor:</bold> Prof. Monica Rosa Loizzo &#x2013; University of Calabria, Italy</p></fn>
</author-notes>
<pub-date pub-type="epub">
<day>01</day>
<month>10</month>
<year>2025</year>
</pub-date>
<pub-date pub-type="collection"><year>2025</year></pub-date>
<volume>37</volume>
<issue>4</issue>
<fpage>436</fpage>
<lpage>477</lpage>
<history>
<date date-type="received"><day>11</day><month>06</month><year>2025</year></date> 
<date date-type="accepted"><day>31</day><month>07</month><year>2025</year></date> 
</history>
<permissions>
<copyright-statement>&#x00A9; 2025 Codon Publications</copyright-statement>
<copyright-year>2025</copyright-year>
<license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by-nc-sa/4.0/">
<license-p>This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0). License (<ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by-nc-sa/4.0/">http://creativecommons.org/licenses/by-nc-sa/4.0/</ext-link>)</license-p>
</license>
</permissions>
<abstract>
<p>The escalating environmental concerns surrounding packaging waste and the drive for circularity, as highlighted by the European Union&#x2019;s (EU) Packaging and Packaging Waste Regulation, necessitate a thorough assessment of consumer products. This study characterizes coffee production and consumption, including its environmental impact, and conducts a streamlined life cycle assessment (LCA) focused on the use and post-consumer phases of diverse coffee formats to quantify packaging waste per coffee cup and evaluate associated environmental burdens. Eight coffee formats&#x2014;flexible multilayer bags, pads, and various capsules (aluminum [Al], polypropylene [PP], polyethylene-aluminum-polyethylene terephthalate [PE-Al-PET], polylactic acid [PLA], and paper), alongside innovative coffee balls&#x2014;and their corresponding brewing systems (Moka pot, espresso machine, pad/capsule machine, and reusable capsules) were considered. Utilizing a functional unit of 720 kg of roasted and ground coffee (RGC), the environmental impact was assessed using the EU product environmental footprint (PEF) methodology. Results conclusively demonstrate that traditional brewing systems using RGC from multilayer bags (PEF: 613&#x00B1;10 nPt/cup) are significantly less impactful than single-serving options such as coffee balls (PEF: 1,675&#x00B1;25 nPt/cup) and particularly capsule/pad systems, such as coffee pads (PEF: 2,895&#x00B1;581 nPt/cup) or PP capsules (PEF: 2,777&#x00B1;23 nPt/cup) across normalized and weighed PEF scores. Detailed analysis further reveals substantial differences in organic and packaging waste generation (e.g., the overall waste from multilayer bags: &#x2248;12 g/cup vs. coffee pads: 22.1 g/cup), carbon footprint (e.g., greenhouse gas [GHG] for multilayer bags: 8.2 g CO<sub>2e</sub>/cup vs. PP capsules: 41 g CO<sub>2e</sub>/cup), fossil resource use, and water use per single coffee cup, underscoring the disproportionate environmental burden of single-serve options. While traditional systems demand more consumer efforts (e.g., filling portafilters and discarding spent ground coffee), their environmental benefits are clear and quantifiable. This study identifies critical environmental hotspots and provides evidence-based recommendations to align coffee consumption with evolving the EU regulations, advocating for more sustainable practices in product design and consumer choice.</p>
</abstract>
<kwd-group>
<kwd>brewing systems</kwd>
<kwd>coffee balls</kwd>
<kwd>coffee capsules/pods</kwd>
<kwd>espresso coffee</kwd>
<kwd>ground coffee</kwd>
<kwd>Life Cycle Assessment (LCA)</kwd>
<kwd>Moka pot</kwd>
<kwd>packaging and packaging waste regulation (PPWR)</kwd>
<kwd>packaging-to-ground coffee ratio</kwd>
<kwd>product environmental footprint (PEF)</kwd>
</kwd-group>
</article-meta>
</front>
<body>
<sec id="S1">
<title>Introduction</title>
<p>Coffee is a globally cherished beverage, with a prominent place in the daily lives of humans in Europe and North America. The sheer scale of its consumption is evident in the approximately 2.25 billion cups savored globally annually (<xref ref-type="bibr" rid="ref90">Yaqub, 2025</xref>). Within this global landscape, Italy exhibits a significant appetite for coffee, with a consumption of roughly 384,000 metric tons (MT) of roasted and ground coffee (RGC) in 2022 (<xref ref-type="bibr" rid="ref89">World Population Review, 2025</xref>).</p>
<p>Numerous studies have explored the environmental impacts of coffee, particularly focusing on cultivation and preparation methods. Life cycle assessment (LCA) studies consistently identify cultivation and consumer&#x2013;use phases as key contributors to greenhouse gas (GHG) emissions and other environmental burdens (<xref ref-type="bibr" rid="ref17">Coltro <italic>et al</italic>., 2006</xref>; <xref ref-type="bibr" rid="ref44">Humbert <italic>et al</italic>., 2009</xref>; <xref ref-type="bibr" rid="ref65">Noponen <italic>et al</italic>., 2012</xref>). This was also confirmed by a recent review conducted by <xref ref-type="bibr" rid="ref15">Ch&#x00E9;ron-Bessou <italic>et al</italic>. (2024)</xref>, which highlighted these phases despite significant variability observed across different coffee LCA studies. Within the cultivation phase, land use change, fertilizer use, and wastewater discharge are notable contributors, while in the consumer&#x2013;use phase, energy consumption during brewing and packaging waste generation are particularly significant.</p>
<p>Comparative LCA studies have yielded varied results depending on methodological choices, functional units, and local practices. For instance, while aluminum (Al) capsules often demonstrate favorable outcomes because of their recyclability, biodegradable options may perform poorly in landfill conditions (<xref ref-type="bibr" rid="ref22">Dubois <italic>et al</italic>., 2011</xref>). Single-serve systems generally show advantages in reducing coffee waste and improving dosage efficiency (<xref ref-type="bibr" rid="ref14">Chayer and Kicak, 2015</xref>) despite higher packaging intensity.</p>
<p>With increasing environmental awareness, the packaging stage has come under renewed scrutiny. The revised European Union (EU) Packaging and Packaging Waste Regulation (PPWR), which entered into force on 11 February 2025 after 2 years of intense negotiations between EU institutions (<xref ref-type="bibr" rid="ref81">Schwizgebel <italic>et al</italic>., 2025</xref>), marks a turning point in how packaging is assessed and managed across all member states. Unlike its predecessor, Directive 94/62/EC (European Union [EU], 1994), the PPWR is a directly applicable regulation, standardizing requirements across EU states.</p>
<p>Key PPWR mandates relevant to coffee packaging include the following:</p>
<p><list list-type="bullet">
<list-item><p>Recyclable packaging by 2030, with large-scale recycling operations in place by 2035.</p></list-item>
<list-item><p>Minimum 10% post-consumer recycled (PCR) content in plastic packaging that ensues contact with food.</p></list-item>
<list-item><p>Eco-modulation of extended producer responsibility (EPR) fees based on recyclability and environmental performance.</p></list-item>
</list></p>
<p>These rules particularly impact single-serve coffee formats, because there are insufficient solutions (<xref ref-type="bibr" rid="ref58">Marinello <italic>et al</italic>., 2021</xref>) for the treatment of such waste on a global scale from its appropriate collection to the treatment and enhancement of materials that are recovered (plastics, metals, and spent coffee grounds [SCGs]). Specifically, since coffee capsules are made from different materials, the need to separate manually poly-laminate components and coffee residues is one of the main challenges. Thus, the capsules frequently end up in undifferentiated collection mainly disposed of in landfills or incinerators, as separating the plastic part from the aluminum part is not a simple operation. Consequently, owing to the EPR schemes promoted by the PPWR, producers are potentially be enforced to innovate in capsule design or recycling systems, as they are responsible for the end-of-life management of their packaging. Furthermore, the PPWR encourages the reduction of complex materials in packaging, recognizing that the combination of different materials in coffee capsules (plastic, aluminum, and coffee) complicates recycling efforts, potentially driving the industry toward mono-material or easier-to-separate designs.</p>
<p>Considering the PPWR&#x2019;s focus on reducing packaging waste and promoting circularity, the first aim of this study is to characterize the basics of coffee in terms of varieties, types, production and consumption processes, and environmental impact. The second one was to adopt a streamlined LCA approach to evaluate the use and post-consumer phases of different coffee formats, particularly focusing on the amount of packaging waste per coffee cup. This targeted assessment was justified by the following three key factors:</p>
<p><list list-type="bullet">
<list-item><p>The PPWR&#x2019;s prioritization of minimization and recyclability of packaging waste.</p></list-item>
<list-item><p>A significant environmental burden posed by packaging in single-serve coffee systems, a segment with rapidly increasing market share.</p></list-item>
<list-item><p>The necessity of comparing environmental impacts under consistent downstream conditions, utilizing the product environmental footprint (PEF) methodology (<xref ref-type="bibr" rid="ref28">European Commission, 2018</xref>), as integrated into the SimaPro software (PR&#x00E9; Consultants, Amersfoort, NL).</p></list-item>
</list></p>
<p>By isolating these specific life cycle stages, this study effectively identifies crucial environmental hotspots. This provides a strong basis for evidence-based recommendations, helping to align coffee consumption practices and product design with the EU&#x2019;s evolving regulatory framework.</p>
</sec>
<sec id="S2">
<title>Coffee Basics</title>
<p>Coffee is the third largest consumed drink globally after water and tea. It is brewed from roasted and ground seeds of coffee plants, their constituent alkaloid (i.e., caffeine) giving such a beverage a stimulating effect. Although there are about 124 varieties of coffee plants (<xref ref-type="bibr" rid="ref88">World Bank, 2020</xref>), two species, <italic>Coffea arabica</italic> and <italic>C. canephora</italic>, supply almost all the world coffee consumption. Arabica beans contain about 1.5% of caffeine and yield a milder, sweeter, and more flavorful and aromatic brew than Robusta ones, their caffeine content being about 2.7%. <italic>C. arabica</italic> is believed to be a native of Ethiopia and is more widespread than <italic>C. canephora</italic>, but more vulnerable to fungal diseases (i.e., coffee leaf rust) and pests (i.e., coffee berry borer). It must grow at altitudes ranging from 600 to 2,000 m above sea level (asl), needs rainfall of 1.5&#x2013;2.0 m per year, and a dry period of 2&#x2013;3 months or irrigation if rainfall is of less than 1 m/year; it has specific shade requirements. On the contrary <italic>, C. canephora</italic>, native to West Africa, can grow at lower altitudes than 600 m asl. It is greatly tenacious and adaptable for its resistance to high temperatures (24&#x2013;30 &#x00B0;C) and humidity as well as attacks by insects; its high caffeine content acts as a natural pesticide.</p>
<sec id="S2_1">
<title>Green coffee production</title>
<p>Global green coffee production reached more than 178 million 60-kg bags in the 2023&#x2013;2024 season (<xref ref-type="bibr" rid="ref84">Shahbandeh, 2025</xref>), rebounding from 168.2 million 60-kg bags in 2022&#x2013;2023 and 170.8 million 60-kg bags in 2020&#x2013;2021, despite the disruptions caused by the COVID-19 pandemic (International Coffee Organization [ICO], 2022). South America accounted for approximately half of global production, with Brazil being the largest producer at 69 million 60-kg bags, followed by Vietnam with 29 million 60-kg bags (<xref ref-type="bibr" rid="ref84">Shahbandeh, 2025</xref>).</p>
<p>International coffee trade remains highly dynamic. Global imports for 2023&#x2013;2024 reached 137 million bags, led by the United States ($8.2 billion), followed by Germany ($4.12 billion), Canada, and the Netherlands (<xref ref-type="bibr" rid="ref76">Ridder, 2024</xref>).</p>
<p>Brazil, Switzerland, and Germany were the leading exporters in 2024 (<xref ref-type="bibr" rid="ref77">Ridder, 2025</xref>). Certified sustainable coffee also has shown steady growth, with Fair Trade- and UTZ-certified (UTZ also means &#x201C;good&#x201D; in the Maya language) production increasing from 0.87 million MT in 2016 to 1.7 million MT in 2023 (<xref ref-type="bibr" rid="ref83">Shahbandeh, 2024</xref>).</p>
<p>In terms of species, Arabica continues to dominate global production, accounting for 59.2% in 2020&#x2013;2021 and maintaining a 57.5% share in 2022 (98.6 million bags vs. 72.7 million bags of Robusta variety) (<xref ref-type="bibr" rid="ref57">Maletic, 2023</xref>). Arabica is primarily cultivated in South America, while Robusta dominates Asia and Oceania (60%), followed by South America (28%) and Africa (12%). In the EU27 states, imports in 2023 reflected a stable split of 63.8% Arabica and 35.6% Robusta (<xref ref-type="bibr" rid="ref27">European Coffee Federation, 2024</xref>).</p>
<p>Italy remains a key player as both importer and exporter. In 2023, the Italian coffee industry generated a turnover of approximately &#x20AC;5.2 billion, with &#x20AC;2.3 billion from exports and &#x20AC;2.9 billion from domestic sales (<xref ref-type="bibr" rid="ref49">Italia Insights, 2024</xref>). Italy ranks as the world&#x2019;s third largest importer of green coffee, outsourcing primarily from Brazil (31%), Vietnam (23%), Uganda (15%), India (8%), and Indonesia (3%) (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>). The average purchase price of green coffee stood at &#x20AC;3.1/kg, with Robusta at &#x20AC;2.4/kg and Arabica at &#x20AC;3.7/kg (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>).</p>
<p>Domestically, coffee remains deeply embedded in Italian culture, with 97% of the population consuming it regularly; 89.3% drink it at least on weekly basis and 73.9% daily (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>). Coffee is widely perceived as both an energizer (42.2%) and a social ritual (33.7%), with preparation considered important by 92% of consumers, particularly among those aged 25&#x2013;34 years (95%) (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>).</p>
<p>In 2023, domestic roasted coffee consumption through retail channels totaled 120.9-million kg, accounting for 71% of roasted coffee sales. Retail volume declined by 2.2%, compared to 2022, due to inflationary pressures; however, market value rose by 6.1% to &#x20AC;1.729 billion, as average prices increased from &#x20AC;13.2/kg to &#x20AC;14.3/kg (+8% increase) (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>).</p>
<p>Packaged ground coffee remains the leading segment (68% volume, and 45% value), while single-serve formats continue to expand. Capsules now account for 20.3% of volume and 44.2% of value, generating more than &#x20AC;639 million; coffee pods contributed &#x20AC;126 million (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>). Coffee beans represent 7.3% of volume (4.9% value), and soluble coffee remains marginal (4% volume, and 6% value).</p>
<p>Supermarkets dominate distribution (58.4% of value), followed by discount stores (15.0%), hypermarkets (12.4%), large-scale retailers (10.4%), and traditional retail (3.8%). Specialized coffee shops and online channels account for ~18% of the market (41 million kg), with 22% of consumers purchasing from specialty stores and 9% directly from roasters (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>).</p>
<p>Brewing preferences in Italy have shifted significantly over the past decade. While the Moka pot was once the dominant method, used by 87% of households in 2016 (Agenzia Giornalistica Italia [AGI], 2016), its popularity has since declined. By 2021, Moka pot usage dropped to 39%, remaining the leading home brewing method, with pod machines as a close second at 31% (YouGov(R), 2024). This trend accelerated, and by 2023, pod machines had firmly established their lead with a 42.7% market share, followed by Moka pots (28.8%) and automatic espresso machines (17.1%) (<xref ref-type="bibr" rid="ref49">Italia Insights, 2024</xref>).</p>
<p>Although RGC still represents 90% of domestic consumption, single-serve systems are driving market transformation. Exports of pods and capsules increased by 12.9% in 2024, now comprising 40% (&#x20AC;595 million) of Italy&#x2019;s coffee market (<xref ref-type="bibr" rid="ref49">Italia Insights, 2024</xref>). Aluminum capsules grew by 11% since 2016, while decline was observed in plastic and paper pods (<xref ref-type="bibr" rid="ref45">Iascone, 2020</xref>; <xref ref-type="bibr" rid="ref49">Italia Insights, 2024</xref>).</p>
<p>Finally, sustainability concerns are increasingly relevant, with 50.3% of consumers demanding greater environmental responsibility across the coffee supply chain. Industry responses include investments in ethical sourcing, eco-friendly packaging, energy efficiency, and circular economy practices (<xref ref-type="bibr" rid="ref75">Redazione Beverfood.com, 2024</xref>).</p>
<p>Globally, per capita coffee consumption varies considerably. In 2023, Brazil led with 6.4 kg per capita, followed by Canada (6.2 kg), the EU27 considered as a bloc (5.7 kg), and the United States (4.8 kg). Notable variations within the EU27 itself were noted: Finland (10.5 kg), Sweden (9 kg), Italy (5.5 kg), and France (5.2 kg). Meanwhile, emerging markets, such as Indonesia (1.3 kg) and Russia (2.0 kg), are still on an upward trend (<xref ref-type="bibr" rid="ref27">European Coffee Federation, 2024</xref>).</p>
</sec>
<sec id="S2_2">
<title>Coffee cultivation and green coffee production</title>
<p>Coffee plants were customarily cultivated in the shade of different trees to mimic the natural growing conditions of a forest understory. This method not only provides habitat for pest-eating birds and pollinators but also has several advantages, such as improved nutrient cycling, carbon sequestration and water filtration, and decreased soil erosion. Even if it is characterized by yields of 0.5&#x2013;1.0 MT per hectare (ha) and is more labor-intensive, the harvested beans have a superior flavor and thus a higher market price, being sold as a specialty coffee. In 2021, about 25% of global coffee production was shade-grown. Sun-grown coffee has been cultivated since 1960s and has caused the deforestation of large areas of Central America and other coffee-growing regions. Robusta coffee is well adapted to such a cultivation method with yields as high as 2.3&#x2013;3.4 MT/ha, thanks to greater treatment inputs (i.e., trimming, weeding, fertilizers, and pesticides). Young coffee plants, raised in nurseries, are spaced in rows with a density ranging from 1,200 to 1,800 plants/ha at the beginning of the rainy season, and start producing fruit 3&#x2013;4 years later.</p>
<p><xref ref-type="table" rid="T1">Table 1</xref> shows the main agricultural activities and inputs applied in the main coffee-growing areas, such as Brazil, India, Indonesia, Vietnam, Honduras, and Colombia, as well as the average green coffee bean (GCB) yields, as extracted from the Ecoinvent v. 3.5 database.</p>
<table-wrap id="T1" orientation="portrait" position="float">
<label>Table 1.</label><caption><p>Main agricultural activities and inputs applied in the main coffee-growing areas, such as Brazil, India, Indonesia, Vietnam, Honduras, and Colombia, as well as the average crop yields of green coffee beans (GCB) of Arabica and Robusta varieties, as extracted from the Ecoinvent v. 3.5 database.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Coffee variety</th>
<th align="left">Locality</th>
<th align="center">Average crop yield <break/>(kg GCB/ha)</th>
<th align="center">Irrigation (m<sup>3</sup>/ha)</th>
<th align="left">Fertilization and pesticide inputs <break/>(kg/ha)</th>
<th align="center">Production period <break/>(years)</th>
<th align="left">Activities</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Arabica</td>
<td align="left">Sao Paulo State, Brazil</td>
<td align="center">1,800</td>
<td align="center">1,987</td>
<td align="left">Mineral NPK fertilizer: 173-35-247<break/>Pesticide: 7.8</td>
<td align="center">20</td>
<td align="left" rowspan="8">Tree nursery; <break/>soil cultivation; planting trees; direct field emissions;<break/>land use change; seedlings, fertilizers and pesticides plus their packaging; irrigation; harvesting; GCBs drying using firewood; waste treatment; final orchard clearing.</td>
</tr>
<tr>
<td align="left">Robusta</td>
<td align="left">Sao Paulo State, Brazil</td>
<td align="center">4,200</td>
<td align="center">&#x2013;</td>
<td align="left">Mineral NPK fertilizer: 340-56-375<break/>Pesticide: 5.8</td>
<td align="center">20</td>
</tr>
<tr>
<td align="left">Arabica</td>
<td align="left">Karnataka State, India</td>
<td align="center">725</td>
<td align="center">352</td>
<td align="left">Mineral NPK fertilizer: 900-0-0<break/>Pesticide: 3.85</td>
<td align="center">20</td>
</tr>
<tr>
<td align="left">Robusta</td>
<td align="left">Karnataka State, India</td>
<td align="center">1,550</td>
<td align="center">235</td>
<td align="left">Mineral NPK fertilizer: 343-223-221<break/>Pesticide: 2.0</td>
<td align="center">20</td>
</tr>
<tr>
<td align="left">Robusta</td>
<td align="left">Lampung province, Indonesia</td>
<td align="center">900</td>
<td align="center">&#x2013;</td>
<td align="left">Mineral NPK fertilizer: 900-0-0<break/>Pesticide: 0.0</td>
<td align="center">20</td>
</tr>
<tr>
<td align="left">Robusta</td>
<td align="left">Vietnam</td>
<td align="center">2,500</td>
<td align="center">833</td>
<td align="left">Mineral NPK fertilizer: 331-127-249<break/>Pesticide: 0.5</td>
<td align="center">20</td>
</tr>
<tr>
<td align="left">Arabica</td>
<td align="left">Honduras</td>
<td align="center">1,340</td>
<td align="center">&#x2013;</td>
<td align="left">Mineral NPK fertilizer: 343-223-221<break/>Pesticide: 2.0</td>
<td align="center">20</td>
</tr>
<tr>
<td align="left">Arabica</td>
<td align="left">Colombia</td>
<td align="center">597</td>
<td align="center">2,200</td>
<td align="left">Mineral NPK fertilizer: 118-8-71<break/>Pesticide: 4.3</td>
<td align="center">20</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF1-1"><p>Notes: NPK: nitrogen-phosphorous-potassium.</p></fn></table-wrap-foot>
</table-wrap>
<p>The ripened fruits of coffee plants (i.e., coffee cherries) are processed to dry coffee seeds as freed from their pulp and skin using the dry, wet, or semi-washed process. The resulting green coffee is graded and classified on the basis of several characteristics, such as growing altitude and region, botanical variety, method of processing, roast appearance, and bean size, density, and defects. Some shade-grown coffee may be certified as organic (<xref ref-type="bibr" rid="ref35">Freitas <italic>et al</italic>., 2024</xref>).</p>
</sec>
<sec id="S2_3">
<title>Coffee processing</title>
<p>At roaster companies, GCBs are separated from fibers and powders, vacuum-cleaned, and then stored in silos. Their roasting is generally carried out in rotating drums, where coffee beans are first dried to eliminate any residual moisture and then roasted at temperatures gradually increasing up to 180&#x2013;250 &#x00B0;C for a period ranging from 7 to 20 min to obtain lighter or darker roasted coffee beans (<xref ref-type="bibr" rid="ref35">Freitas <italic>et al</italic>., 2024</xref>). Such a step allows the development of the characteristic aroma of coffee, which is derived from Maillard reactions between carbohydrates, proteins, and acids. A few precursors of the resulting volatile compounds are related to the coffee variety, weather conditions at origin, level of maturation, and processing choices. The level of roasting can give rise to pleasant (i.e., roasted notes from 2-methylpyridine, nuttiness from pyrazines, caramel notes from furans, and furanones, fruity, and sweet notes from 3-methylbutanal and ketones) or unpleasant (i.e., ashy and smoky aromas from guaiacol) aromas (<xref ref-type="bibr" rid="ref33">Fisk <italic>et al</italic>., 2012</xref>). Robusta beans can be intentionally over-roasted at near 200 &#x00B0;C to rid it of its natural harshness.</p>
<p>Roasted beans are then air-cooled to maintain their characteristic flavor and avoid any water reabsorption. A fraction of whole roasted coffee beans is directly packaged in flexible sealed bags provided with one-way vent valves, these opening to relieve increased pressure due to the release of CO and CO<sub>2</sub> trapped within cooled roasted coffee beans (<xref ref-type="bibr" rid="ref59">McCarrick <italic>et al</italic>., 2019</xref>). These are generally ground at the time of purchase or consumption. By contrast, the great majority of roasted coffee beans is immediately ground and packed by the manufacturer. Such a process is a key step&#x2014;the degree of particle fineness affecting the taste and flavor of coffee. If coffee particles are too coarse, water filters through too fast to extract wholly the aroma substances contained in coffee beans. On the contrary, too fine particles filter water too slowly and entrain smaller particles that deposit at the bottom of the cup. Not only the particle size of the coffee powder is to be adjusted but the particle size distribution is also controlled to assure a harmonious coffee taste in pre-set brewing period. For these reasons, laser particle size analyzers are used in industries to guarantee the required size of the coffee powder of choice (<xref ref-type="bibr" rid="ref87">Wang, 2021</xref>).</p>
</sec>
<sec id="S2_4">
<title>Coffee powder packaging</title>
<p>Given the ground coffee&#x2019;s extreme sensitivity to air and moisture, these causing rancidity through the oxidation of fatty components and deteriorating its aromatic qualities within a few days, specialized packaging is crucial. To combat these issues, coffee is typically packaged under vacuum or in an inert gas in hermetically sealed containers. These containers are crafted from multilayer or composite materials (often involving coextrusion or lamination of kraft paper, aluminum foil, and low-density polyethylene [PE] or polypropylene [PP]), stainless steel, or plastic cans. This construction provides essential barrier properties, strength, and storage stability, extending coffee powder&#x2019;s shelf life to 3&#x2013;5 months.</p>
<p>For ultimate freshness and convenience, ground coffee is often portioned into small, disposable, airtight containers: capsules and pods. Coffee capsules are designed to maintain coffee freshness by creating a sealed, oxygen-free environment.</p>
<p>While well-known Nespresso<sup>&#x00AE;</sup> Espresso capsules are primarily made of aluminum, other commercial capsules utilize a variety of materials, such as the following:</p>
<p><list list-type="bullet">
<list-item><p>Polypropylene, aluminum, and PE</p></list-item>
<list-item><p>Polypropylene and polyethylene terephthalate (PET)</p></list-item>
<list-item><p>Polylactate and starch (these often require additional protection from multilayer pouches made of PE, Al, and PET)</p></list-item>
<list-item><p>Polyethylene, Al, and PET with two upper and lower aluminum lids</p></list-item>
</list></p>
<p>These diverse material choices reflect ongoing efforts to balance barrier performance, cost, and environmental considerations.</p>
<p>In contrast, coffee pods are typically made of heat-sealable paper or abaca-fiber filter. To ensure their freshness, pods are commonly wrapped in PE-Al-PET pouches (<xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>).</p>
<p>Beyond traditional methods, there is a growing interest in sustainable packaging solutions. This includes the exploration of biopolymer coatings for single-serving coffee portions, aiming to reduce reliance on conventional plastics and aluminum while maintaining product integrity. Other emerging trends in coffee packaging include the following:</p>
<p><list list-type="bullet">
<list-item><p>Degassing valves: For freshly roasted coffee, which releases CO<sub>2</sub>, one-way degassing valves are often incorporated into packaging. These valves allow CO<sub>2</sub> to escape without letting in the oxygen, thus preventing package rupture and preserving freshness.</p></list-item>
<list-item><p>Sustainable materials: The industry is increasingly focused on developing and implementing more environment-friendly packaging. This includes recyclable, compostable, and biodegradable materials as well as innovative approaches such as refillable systems and reduced material usage.</p></list-item>
<list-item><p>Active packaging: This advanced packaging technology incorporates components that interact with coffee to extend shelf life and maintain quality. Examples include oxygen scavengers that actively absorb oxygen within the package (<xref ref-type="bibr" rid="ref3">Ahmed <italic>et al</italic>., 2022</xref>; <xref ref-type="bibr" rid="ref53">Kadirvel <italic>et al</italic>., 2025</xref>).</p></list-item>
<list-item><p>Smart packaging: While still nascent, smart packaging for coffee could involve indicators that signal freshness levels or even QR codes providing detailed information about the coffee&#x2019;s origin and roasting date (<xref ref-type="bibr" rid="ref86">Vasuki <italic>et al</italic>., 2023</xref>).</p></list-item>
</list></p>
<p>The evolution of coffee packaging continues to prioritize the maintenance of coffee&#x2019;s delicate aroma and flavor, extending its shelf life, and increasingly minimizing its environmental impact.</p>
</sec>
<sec id="S2_5">
<title>Coffee preparation</title>
<p>Generally, coffee is consumed just after it has been brewed, that is <italic>fresh</italic> and <italic>hot</italic>. In the Neapolitan style, not only coffee but also ceramic cup is very hot, both burning the tongue and lips and masking the full perception of coffee flavor. Generally, expert coffee tasters wait from 5&#x2013;6 minutes before assessing the quality of coffee. While the coffee flavor profile is better appreciated at 70&#x2013;85 &#x00B0;C (Environmental Product Declarations (EPD), 2019a, 2019b), the water brewing temperature should range from 90 &#x00B0;C to 96 &#x00B0;C to extract flavor and aroma from ground coffee more effectively (Henris, 2023). For this reason, the great majority of expresso coffee makers are designed to keep the temperature of water approximately constant during any brewing cycle.</p>
<p>One coffee serving is quite variable with a coffee powder dose ranging from 5 to 10 g/cup in the case of espresso coffee (EPD, 2019b), and from 14 to 19 g for preparing three cups of Moka coffee (EPD, 2019a). Different coffee capsules are used to prepare 40-mL cup of espresso (<xref ref-type="bibr" rid="ref22">Dubois <italic>et al</italic>., 2011</xref>) or Moka coffee (<xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>). Nevertheless, the volume of a coffee cup can range from 110 mL in Switzerland (<xref ref-type="bibr" rid="ref73">Quantis, 2024</xref>) or 125 mL in Germany (<xref ref-type="bibr" rid="ref11">Brommer <italic>et al</italic>., 2011</xref>) to 150 mL in Thailand (<xref ref-type="bibr" rid="ref71">Phrommarat, 2019</xref>) or 8-oz (~236.6 mL) in Canada (<xref ref-type="bibr" rid="ref14">Chayer and Kicak, 2015</xref>). Obviously, the caffeine content of a coffee cup depends on bean variety, roasting degree, brewing method, amount of ground coffee used, and serving size. For instance, Arabica and Robusta beans contain 34&#x2013;39 g and 69&#x2013;82 g of caffeine/kg of dry coffee, respectively (<xref ref-type="bibr" rid="ref52">Jeszka-Skowron <italic>et al</italic>., 2016</xref>). An 8-oz serving of brewed coffee typically contains 80&#x2013;100 mg of caffeine, while the same cup of decaffeinated coffee contains as little as 2 mg of caffeine (<xref ref-type="bibr" rid="ref60">Medical News Today, 2023</xref>).</p>
<p>Different coffee brewing methods are used globally, and are roughly divided into the following five categories (<xref ref-type="bibr" rid="ref82">Shabbir, 2024</xref>):</p>
<p><list list-type="order">
<list-item><p><italic>Gravitational potential energy-based coffee brewing</italic>: Boiling water is slowly poured over a bed of ground coffee placed on a paper filter to let water naturally drip through it and collect the extract into a container or a cup. Generally, a plastic or ceramic funnel with ribs along its sides and a large opening at the bottom is used to accommodate paper filter and ground coffee. The main devices in use, such as Harrio V60 filter, Chemex, drip coffee maker, and Kalita wave device, are shown in <xref ref-type="fig" rid="F1">Figure 1</xref>.</p>
<p>The paper filter used in the Chemex device is folded two or three times around ground coffee and this results in longer extraction period (3.5 vs. 3.0 min). Moreover, the bottom of the Kalita Wave funnel is flat and provided with three small holes, this making the coffee quality practically independent of the water pouring speed.</p></list-item>
<list-item><p><italic>Immersion- or steeping-based coffee brewing</italic>: Ground coffee of medium to coarse grind is steeped in hot water for 1.5&#x2013;4 min. This method makes use of the so-called French press, siphon (vacuum) coffee maker, or coffee bags, as shown in <xref ref-type="fig" rid="F2">Figure 2</xref>.</p>
<p>The French press, patented by Attilio Calimani in 1929, is made of a cylindrical glass container provided with an internal mesh filter (<xref ref-type="fig" rid="F2">Figure 2A</xref>). One tablespoon of ground coffee (about 5 g) and 4 oz (&#x2248;118.3 mL) of water at approximately 91 &#x00B0;C are poured to the bottom of the container. The suspension is slowly stirred and the container is closed with its lid, and filtered. After a shorter or longer steeping process depending on the preferred coffee flavor, the French press plunger is pressed down to separate the spent ground coffee from liquid brew.</p>
<p>The siphon coffee maker consists of two stacked glass vessels joined by a siphon chamber (<xref ref-type="fig" rid="F2">Figure 2B</xref>). The ground coffee is placed in the upper chamber while the water for brewing is poured into the lower one. Upon heating, the water starts to evaporate. As the water vapors formed increase the pressure over the water-free surface, the water is forced through the siphon channel into the upper chamber, where it mixes with ground coffee. A small amount of water remaining in the bottom vessel keeps the siphon full, this allowing coffee brewing in the upper chamber. By switching off the heat source, the water vapor pressure inside the lower vessel begins to decrease and the pressure in the upper vessel combined with the gravity force pushes the brewed liquid back down to the lower chamber.</p>
<p>A coffee bag is like a tea bag but filled with ground coffee (<xref ref-type="fig" rid="F3">Figure 3C</xref>). Coffee is brewed by steeping the bag in hot water for 3&#x2013;4 min.</p>
<p>It is noted that vacuum pot coffee is obtained by immersing in hot water and sucked into the lower vessel through vacuum action. Moreover, the water temperature remains practically constant throughout the entire vacuum brewing process, whereas water is pre-heated before mixing with ground coffee in the above-mentioned brewing methods as well as in espresso coffee.</p></list-item>
<list-item><p><italic>Pressure-driven coffee brewing</italic>: A small amount of pressurized hot water is forced through a bed of ground coffee of fine-medium grind pre-charged into a portafilter, which is inserted through an appropriate gasket into different devices, such as Moka pot, espresso machine, and AeroPress coffee maker (<xref ref-type="fig" rid="F3">Figure 3</xref>).</p>
<p>The water charged in the bottom vessel of Moka pot is heated using a gas-fired or electric stove and, thanks to the portafilter&#x2019;s gasket sealing, partially vaporized to make most of the water arise along the funnel tube, pass through the ground coffee bed up to be discharged in the upper vessel. On the contrary, the steam produced by the espresso machine boiler pushes hot water from the top of the machine down through the ground coffee at a very fast speed, yielding a cup of espresso coffee in just 20 s. Moka pot was invented by the Italian engineer Alfonso Bialetti in 1933, who named it after the port city of Mokha on the Red Sea coast of Yemen. Since then, this pot has become a basic coffee brewer in Italy.</p>
<p>The espresso machine was invented by Luigi Bezzera in the early 1900s, but its patent rights were acquired by Desiderio Pavoni in 1905, who introduced espresso to the Italian market. In 1961, the Faema Company (Binasco, Italy) made use of an electric pump to force water at a pressure of 9 bar through ground coffee. This coffee machine represented the prototype for the current espresso coffee machines (<xref ref-type="bibr" rid="ref5">Andrews, 2022</xref>).</p>
<p>In the 1970s, Italian Illycaff&#x00E8; SpA (Trieste, Italy) developed the so-called easy-serving espresso (ESE) pod (i.e., a portion of ground coffee enveloped in a paper filter) to be directly used in espresso coffee machines.</p>
<p>AeroPress is a manual coffeemaker invented by Alan Adler in 2004. It consists of a plastic tube ending with a twist cap accommodating a paper filter, and a plunger with an airtight silicone seal. Once the ground coffee and hot water are sequentially added to the bottom of the tube and the mixture slowly stirred for 10 s, the plunger is inserted into the plastic tube and gently pressed by collecting liquid brew in the underneath placed cup, decanter, or coffee pot, and used for serving.</p></list-item>
<list-item><p><italic>Coffee brewing using boiling water</italic>: Once water is heated up to the boiling point in a pot of different forms, ground coffee of very fine grind is added and mixed. Then, the pot is removed from the heat, and the mixture is steeped for a few minutes. As ground coffee settles to the bottom of the pot, the clear brew is served.</p>
<p><xref ref-type="fig" rid="F4">Figure 4</xref> shows the main coffee makers relying on boiling water, such as the so-called cowboy or Turkish coffee makers.</p></list-item>
<list-item><p><italic>Single-serve coffee brewing</italic>: Prefixed amount of ground coffee filling single-serve containers (i.e., pods or capsules of different materials) are used in conjunction with specialized coffee machines, where the extraction water is stored at ambient temperature or kept hot at 80&#x2013;90 &#x00B0;C to shorten the brewing period to less than 1 min. As soon as a single-serve coffee container is inserted and button pressed, the bottom of the container is pierced with a discharge nozzle, while an upper small needle allows the extraction water to be forced into the container itself to percolate through porous coffee particle bed and thus drop into the cup below. <xref ref-type="fig" rid="F5">Figure 5</xref> shows the main single-serve coffee containers currently available on the market.</p></list-item>
</list></p>
<fig id="F1" orientation="portrait" position="float">
<label>Figure 1.</label>
<caption><p>Schematic of the main coffee brewing devices acting upon gravitational potential energy: (A) Harrio V60 filter; (B) Chemex; (C) drip coffee maker; and (D) Kalita wave device.</p></caption>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g001.tif"/>
</fig>
<fig id="F2" orientation="portrait" position="float">
<label>Figure 2.</label>
<caption><p>Schematic of main coffee brewing methods involving the immersion or steeping of ground coffee in hot water: (A) French press; (B) siphon (vacuum) coffee maker; and (C) coffee bags.</p></caption>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g002.tif"/>
</fig>
<fig id="F3" orientation="portrait" position="float">
<label>Figure 3.</label>
<caption><p>Schematic of main pressure-driven coffee brewing methods: (A) Moka pot; (B) espresso machine; and (C) AeroPress coffee maker.</p></caption>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g003.tif"/>
</fig>
<fig id="F4" orientation="portrait" position="float">
<label>Figure 4.</label>
<caption><p>Schematic of the main coffee brewing methods using boiling water: (A) Cowboy and (B) Turkish coffee maker.</p></caption>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g004.tif"/>
</fig>
<fig id="F5" orientation="portrait" position="float">
<label>Figure 5.</label>
<caption><p>Schematic of the main coffee brewing methods using single-serve coffee containers: (A) Keurig<sup>&#x00AE;</sup> K-cup; (B) reusable Keurig<sup>&#x00AE;</sup> K-cup; (C) ESE pod with a heat-sealable paper filter to be wrapped in a PE-Al-PET pouch; (D) coffee capsules made of plastics, aluminum, or bioplastics; (E) compostable coffee capsules made of polylactic acid (PLA); (F) paper pulp-based capsules; (G) rechargeable stainless steel coffee capsules with a paper filter; (H) coffee balls (CoB) (CoffeeB, Migros-Genossenschafts-Bund, Z&#x00FC;rich, CH).</p></caption>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g005.tif"/>
</fig>
<p>By using such single-serve systems, the brewing process is so shortened and simplified that, contrary to the conventional espresso machines, the pod or capsule coffee machines are operated without training and effort to apportion the ground coffee needed.</p>
<p>Although ESE coffee pods were launched in the 1970s, the single-serve coffee market practically started in 1986 as Nestl&#x00E9; SA (Vevey, Vaud, Switzerland) launched Nespresso<sup>&#x00AE;</sup> coffee capsules to be brewed in novel easy-to-use coffee machines for offices (<xref ref-type="bibr" rid="ref36">Grant, 2020</xref>). Such a combined system was ideated by Eric Favre, a Nestl&#x00E9; engineer, and pre-tested by Nestl&#x00E9; in Switzerland, Italy, and Japan after a couple of years. This novel coffee brewing method was coldly received by the coffee market, and in 1988, it was repositioned as a luxury item for home consumers. Although in the 1990s, Nespresso<sup>&#x00AE;</sup> coffee pods acquired popularity in Europe, their acceptance in the United States was low, probably because of the high popularity of drip coffee maker (<xref ref-type="fig" rid="F1">Figure 1C</xref>). As Favre was forced to leave Nestl&#x00E9; in 1991, he established a successful espresso capsule company Monodor SA (now Mocoffee, Zug, Switzerland) that improved capsule design (as in the case of incinerable capsules made from PP instead of Al with an overall weight of about 12% of the capsule itself) and coffee machine, which was equipped with an integrated filter so as to be fed with filter-free capsules. His cooperation with Luigi Lavazza SpA (Turin, Italy), Federation of Migros Cooperatives (Zurich, Switzerland), and so on helped capsule&#x2019;s success, this triggering a series of legal battles with Nestl&#x00E9; that finally settled in 2003 (<xref ref-type="bibr" rid="ref43">House of Switzerland, 2017</xref>). As the popularity of Nespresso<sup>&#x00AE;</sup> coffee capsules increased, and the patents deposited by Nestl&#x00E8; SA and Monodor SA started to expire around 2012, several competitor brands entered the market.</p>
<p>As early as 1990, Green Mountain Coffee Roasters (now trading as Keurig Dr Pepper) launched Keurig<sup>&#x00AE;</sup> K-cups (<xref ref-type="fig" rid="F5">Figure 5A</xref>) in North America. In 1998, seven coffee roasters and machine manufacturers founded the non-profit Consortium for the Development and the Protection of the ESE Standard (<ext-link ext-link-type="uri" xlink:href="https://eseconsortium.com/consorzio">https://eseconsortium.com/consorzio</ext-link>; accessed: 22 May 2025) to encourage wide adoption of this open design. The investment needed to adapt coffee capsules machines to coffee pods (named as &#x201C;pads&#x201D; in the United States, the United Kingdom, and the EU) was limited because the pressure of extraction water had to be just lowered to avoid bursting of paper filter, as in the case of coffee pad machines developed by D&#x0113;longhi SpA (Treviso, Italy), Krups (SEB Developpement SpA, Ecully, France), and Philips SpA (Milan, Italy; Senseo<sup>&#x00AE;</sup> coffee maker, <ext-link ext-link-type="uri" xlink:href="https://www.philips.it/c-p/HD7810_60/macchina-da-caffe-a-cialde">https://www.philips.it/c-p/HD7810_60/macchina-da-caffe-a-cialde</ext-link>; accessed: 22 May 2025). Thus, since 2001, several coffee makers associated with the above-mentioned consortium have launched this format, filled with about 7 g of ground coffee, whereas a capsule approximately contains 5 g of ground coffee. A coffee pod consists of two basic elements, that is, the <italic>inner capsule</italic> or <italic>cup</italic>, which is generally made of aluminum, plastic, or bioplastic, and the <italic>aluminum film</italic> to assure hermetic sealing and a barrier effect against light, humidity, and oxygen to maintain fragrance and freshness of coffee. On the contrary, coffee pads refer to prefixed doses of RGC packed in paper filters, which must be stored in protective foil pouches (<xref ref-type="fig" rid="F5">Figure 5C</xref>).</p>
<p>The coffee market currently features approximately 400 competitor capsule brands, despite growing concerns about sustainability. With a recycling rate for spent coffee capsules below 5% (<xref ref-type="bibr" rid="ref36">Grant, 2020</xref>), the local government in Hamburg, Germany, in 2016, banned use of coffee capsules in all government organizations and offices. In response to this ban, Nestl&#x00E9; Nespresso<sup>&#x00AE;</sup> SA (Vevey, Vaud) pursued a two-pronged approach. The company established more than 100,000 aluminum capsule recycling collection points across 70 countries (Nestl&#x00E9;, 2022) to boost recycling rates. Additionally, in October 2023, Nespresso<sup>&#x00AE;</sup> launched novel paper-based home-compostable pods (<xref ref-type="fig" rid="F5">Figure 5F</xref>) in France and Switzerland, the culmination of 3 years of research and development (<xref ref-type="bibr" rid="ref56">Ludmir, 2023</xref>). These new compostable capsules are composed of 82% paper pulp and are coated with a thin, protective compostable biopolymer film (Nestl&#x00E9;, 2022). This timely launch coincided with the European Commission&#x2019;s drafting of new packaging regulations, which could potentially lead to the disappearance of single-use capsules, made from standard aluminum and plastics, from store shelves.</p>
<p>Packaging recyclability was also on the agenda of other coffee players.</p>
<p>The 2015-joint development process between Flo SpA (Fontanellato, Parma, Italy) and Nature Works LLC (Plymouth, MN, USA) led to GEA (by Flo SpA) compostable PLA coffee capsules in 2018 (<xref ref-type="fig" rid="F5">Figure 5E</xref>), which were compatible with the Lavazza <italic>A Modo Mio</italic> system (<xref ref-type="bibr" rid="ref85">Sustainable Plastics, 2020</xref>). Similarly, in 2021, the NEXE Innovations Inc. (Surrey, Canada) introduced novel 100% compostable, plant-based pods compatible with Keurig&#x00AE; single-serve brewing systems (<xref ref-type="bibr" rid="ref37">Guglani, 2021</xref>).</p>
<p>As the latest attempt at easing the disposables of spent coffee pods in organic waste bins, it is worth citing novel coffee balls (CoffeeB) launched by Migros-Genossenschafts-Bund (Z&#x00FC;rich, CH) in 2022 (<xref ref-type="fig" rid="F5">Figure 5H</xref>). Each coffee ball containing 5.3&#x2013;5.9 g of ground and roasted coffee is coated with a thin protective biopolymer film to retain coffee aroma. In this way, by avoiding the generation of any aluminum or plastic capsule waste, spent coffee balls are easily recycled by composting under both home and industrial conditions (<ext-link ext-link-type="uri" xlink:href="https://www.migros.ch/it/content/coffeeb">https://www.migros.ch/it/content/coffeeb</ext-link>; accessed: 22 May 2025).</p>
<p>Such a final goal could be achieved by using reusable Keurig<sup>&#x00AE;</sup> K-cups (<xref ref-type="fig" rid="F5">Figure 5B</xref>) or rechargeable stainless steel coffee capsules (<xref ref-type="fig" rid="F5">Figure 5G</xref>). At the expense of a lower service degree related to the need of dosing ground coffee in each reusable cup, disposing of SCGs and cleaning the cup before its reuse would avoid any consumption of aluminum or plastic packaging material and associated waste disposal, and would make easier the disposal of SCGs in domestic organic waste bins. A simplified rechargeable system for stainless steel coffee capsules was also developed by a French brand CAPS&#x2019;ME (<ext-link ext-link-type="uri" xlink:href="https://www.capsme.fr/products/3-capsules-reutilisables-inox">https://www.capsme.fr/products/3-capsules-reutilisables-inox</ext-link>; accessed: 22 May 2025).</p>
</sec>
<sec id="S2_6">
<title>Energy consumption during coffee brewing</title>
<p>Each of the described coffee brewing systems exhibits distinct energy consumption characteristics. These yields vary depending on the factors such as the volume of coffee brewed and the system&#x2019;s operational duration, including its stand-by state.</p>
<p>When using a Moka pot, gas or electricity consumption can be determined as suggested by the Product Category Rules for Moka coffee preparation (EPD, 2019a). First, measure the volume of water added to Moka pot. Then, weigh Moka funnel (either empty or after its basket has been filled with ground coffee) with an analytical balance. Next, place the funnel in the boiler, assemble it into the coffee collecting chamber, and position Moka pot over an induction or gas-fired stove. After adjusting the stove to supply a power of 0.6 kW, turn on the heat until the coffee stops flowing from the spout, noting the coffee end time and energy consumed. Subsequently, measure the overall volume of coffee recovered (V<sub>c</sub>), along with the remaining mass of water in the boiler and SCG in the funnel, which are recovered as soon as Moka pot cools and is disassembled. Energy consumption by an electric hob can be monitored via a digital power meter, while that by a gas-fired stove can be estimated by multiplying the volume of gas consumed by its corresponding lower heating value (LHV [kJ L<sup>&#x2013;1</sup>]).</p>
<p>When using any espresso or single-serve coffee machine, energy consumption is determined according to standard EN 60661 (European Committee for Electrotechnical Standardization [CENELEC], 2014) and the Product Category Rules for espresso coffee preparation (EPD, 2019b). This involves performing five sequential brewing cycles over a period of 100 min. First, weigh the filter holder (either empty or filled with ground coffee) or the coffee pod/capsule. Then, switch on the coffee machine and continuously monitor its energy consumption from start of the brewing process using a power meter. The first brewing cycle begins 1 min after the machine is ready; record the start time and initial energy consumed. At the end of brewing, measure the volume of the coffee collected in a cup, along with the mass of machine&#x2019;s filter holder and exhausted pod/capsule to assess the amount of SCG. The second brewing cycle starts 1 min after completion of the first cycle, registering the initial time and energy consumed. Each cycle produces two 40-mL cups of coffee, either in parallel (for espresso machines) or in sequence (for pod/capsule machines), repeating post-brewing measurements (volume and SCG). Energy consumption is continuously monitored for 30 min, reactivating the machine if needed, and registering the total time and energy consumed. The third brewing cycle is then performed by following the same steps as that of the second cycle. Finally, energy consumption is continuously monitored for 100 min, reactivating the machine as necessary, and recording the final time and total energy consumed. The electricity consumed to brew a single 40-mL cup of coffee is then estimated as the overall energy consumed over the 100-min test divided by the number of coffee cups prepared (i.e., five cups of coffee).</p>
<p>The research conducted by <xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>. (2021)</xref> investigated various coffee brewing parameters across different coffee makers. Their study aimed to quantify the following:</p>
<p><list list-type="bullet">
<list-item><p>Amount of ground coffee used in each brewing cycle (m<sub>GC</sub>) and moisture content (x<sub>WGC</sub>) of ground coffee used per brewing cycle.</p></list-item>
<list-item><p>Number of coffee cups brewed (n<sub>cc</sub>) and the overall volume (V<sub>c</sub>) of coffee prepared.</p></list-item>
<list-item><p>Amount of SCGs (m<sub>SCG</sub>) and moisture content (x<sub>WSGC</sub>) of SCG.</p></list-item>
<list-item><p>Specific energy consumed per single coffee cup (E<sub>cc</sub> [Wh/cup]).</p></list-item>
<list-item><p>Coffee cup preparation time (t<sub>c</sub> [s]).</p></list-item>
</list></p>
<p>Key findings of their replicated brewing tests are summarized in <xref ref-type="table" rid="T2">Table 2</xref>, where statistically significant differences observed across various parameters are indicated by superscript lowercase letters based on the Tukey test.</p>
<table-wrap id="T2" orientation="portrait" position="float">
<label>Table 2.</label><caption><p>Main results with their statistical significance of three replicated coffee brewing tests carried out by Cibelli <italic>et al.</italic> (2021) using different coffee formats and makers.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Coffee maker</th>
<th align="center">m<sub>GC</sub>/cycle(g)</th>
<th align="center">x<sub>WGC</sub>(% w/w)</th>
<th align="center">n<sub>cc</sub>(&#x2013;)</th>
<th align="center">V<sub>c</sub>(mL)</th>
<th align="center">m<sub>SCG</sub>(g)</th>
<th align="center">x<sub>WSCG</sub>(% w/w)</th>
<th align="center">E<sub>cc</sub>(Wh/cup)</th>
<th align="center">t<sub>c</sub>(s)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Induction Moka pot</td>
<td align="center">16.01&#x00B1;0.01</td>
<td align="center">0.68&#x00B1;0.12<sup>a</sup></td>
<td align="center">3</td>
<td align="center">119&#x00B1;1<sup>a</sup></td>
<td align="center">32.8&#x00B1;0.5<sup>a</sup></td>
<td align="center">61.0&#x00B1;0.1<sup>a</sup></td>
<td align="center">6.8&#x00B1;0.2</td>
<td align="center">88&#x00B1;2</td>
</tr>
<tr>
<td align="left">LPG-heated Moka pot</td>
<td align="center">16.01&#x00B1;0.01</td>
<td align="center">0.68&#x00B1;0.12<sup>a</sup></td>
<td align="center">3</td>
<td align="center">118&#x00B1;1<sup>a</sup></td>
<td align="center">34.1&#x00B1;2.3<sup>a</sup></td>
<td align="center">60.6&#x00B1;0.3<sup>a</sup></td>
<td align="center">18.3&#x00B1;1.2</td>
<td align="center">62&#x00B1;1</td>
</tr>
<tr>
<td align="left">Espresso coffee machine</td>
<td align="center">9.00&#x00B1;0.03</td>
<td align="center">0.68&#x00B1;0.12<sup>a</sup></td>
<td align="center">5</td>
<td align="center">200&#x00B1;2<sup>b</sup></td>
<td align="center">19.6&#x00B1;0.5<sup>b*</sup></td>
<td align="center">62.6&#x00B1;1.3<sup>a</sup></td>
<td align="center">15.9&#x00B1;0.4</td>
<td align="center">19&#x00B1;3</td>
</tr>
<tr>
<td align="left">Pod coffee machine</td>
<td align="center">7.23&#x00B1;0.02</td>
<td align="center">0.56&#x00B1;0.21<sup>a</sup></td>
<td align="center">5</td>
<td align="center">200&#x00B1;2<sup>b</sup></td>
<td align="center">13.7&#x00B1;0.8<sup>c</sup></td>
<td align="center">56.6&#x00B1;2.9<sup>a,b</sup></td>
<td align="center">12.0&#x00B1;0.6</td>
<td align="center">30&#x00B1;5</td>
</tr>
<tr>
<td align="left">Capsule coffee machine</td>
<td align="center">5.75&#x00B1;0.07</td>
<td align="center">0.54&#x00B1;0.22<sup>a</sup></td>
<td align="center">5</td>
<td align="center">200&#x00B1;2<sup>b</sup></td>
<td align="center">14.0&#x00B1;0.5<sup>c</sup></td>
<td align="center">62.6&#x00B1;1.3<sup>a</sup></td>
<td align="center">8.5&#x00B1;0.2</td>
<td align="center">25&#x00B1;4</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF2-1"><p>Notes: m<sub>GC</sub>: amount of ground coffee used in each brewing cycle; x<sub>WGC</sub>: moisture content of ground coffee used in each brewing cycle; n<sub>cc</sub>: number of coffee cups brewed; V<sub>c</sub>: the overall volume of coffee prepared; m<sub>SCG</sub>: amount of spent ground coffee; x<sub>WSGC</sub>: moisture content of spent ground coffee; E<sub>cc</sub>: specific energy consumed per single coffee cup; t<sub>c</sub>: coffee cup preparation time; LPG: liquefied petroleum gas.</p></fn>
<fn id="TF2-2"><label>*</label><p>It includes paper filter.</p></fn>
<fn id="TF2-3"><p>Different lowercase superscript letters indicate statistically significant difference among the column mean values of each parameter at <italic>p</italic> = 0.05, based on Tukey test.</p></fn></table-wrap-foot>
</table-wrap>
<p>For induction- and LPG-heated Moka pots, approximately 16 g of ground coffee was used per cycle, which aligned with 14&#x2013;19-g range recommended by the Moka coffee disciplinary (<xref ref-type="bibr" rid="ref19">Comitato Italiano del Caff&#x00E8;, 2020</xref>) for 3-cup Moka pot.</p>
<p>When considering the coffee dose per single cup, the amount in coffee pods (7.23 g) and espresso filters (9.00 g) was in 7&#x2013;9-g range recommended by the Espresso coffee disciplinary (<xref ref-type="bibr" rid="ref18">Comitato Italiano del Caff&#x00E8;, 2018</xref>), while the amount RCG in coffee capsules (5.75 g) was notably lower.</p>
<p>The moisture content of ground coffee (x<sub>WGC</sub>) was remarkably consistent across all formats, averaging about 0.62% w/w, indicating that the format did not significantly influence this parameter.</p>
<p>The amount (m<sub>SCG</sub>) of SCG approximately doubled the initial amount of coffee powder used. For example, Moka pots starting with about 16 g of coffee produced approximately 33&#x2013;34 g of SCGs. The moisture content of SCGs varied slightly, ranging from 56.6% to 62.6% (w/w), with no clear trend tied with the type of coffee maker.</p>
<p>Energy consumption per cup showed significant differences. The LPG-heated Moka pot had the highest energy consumption at 18.3 Wh/cup, followed by the espresso coffee machine at 15.9 Wh/cup. In contrast, the induction Moka pot proved considerably more energy-efficient, using energy only 6.8 Wh/cup, underscoring the benefits of induction heating. Capsule and pod coffee machines also demonstrated relatively low energy consumption at 8.5 Wh/cup and 12.0 Wh/cup, respectively.</p>
<p>Coffee cup preparation time (t<sub>c</sub>) also showed wide differences. Moka pots had the longest preparation time, with induction and LPG-heated versions taking 88 s and 62 s, respectively, for three cups of coffee. The espresso coffee machine offered the fastest preparation at just 19 s, while capsule and pod machines also provided quick brewing time at 25 s and 30 s, respectively.</p>
<p>Further insights into energy consumption arrived from other studies. <xref ref-type="bibr" rid="ref11">Brommer <italic>et al</italic>. (2011)</xref> reported that efficient pod or capsule machines with auto power-down function consumed approximately 39 Wh per 125-mL cup (~0.31 Wh/mL). Comparing this to the E<sub>cc</sub> data shown in <xref ref-type="table" rid="T2">Table 2</xref>, this value was lower than that of the LPG-heated Moka pot (0.46 Wh/mL) and espresso coffee machine (0.40 Wh/mL) in Cibelli <italic>et al</italic>.&#x2019;s (2021) study. It was practically coincident with the pod coffee machine (0.30 Wh/mL) but higher than the capsule coffee maker (0.21 Wh/mL) and induction Moka pot (0.17 Wh/mL). <xref ref-type="bibr" rid="ref11">Brommer <italic>et al</italic>. (2011)</xref> also noted that inefficient appliances without auto power-down functions could significantly increase energy expenditure by up to 0.87 Wh/mL.</p>
<p>Other studies support these variations: <xref ref-type="bibr" rid="ref71">Phrommarat (2019)</xref> reported a higher specific energy consumption of 0.93 Wh/mL for an electric Moka pot, while energy consumption in different capsule coffee makers ranged from 0.20 Wh/mL (<xref ref-type="bibr" rid="ref71">Phrommarat, 2019</xref>) to 0.28 Wh/mL (<xref ref-type="bibr" rid="ref44">Humbert <italic>et al</italic>., 2009</xref>) and 0.32 Wh/mL (<xref ref-type="bibr" rid="ref22">Dubois <italic>et al</italic>., 2011</xref>). Notably, the energy consumed per single cup for induction Moka pot (6.8 Wh/cup) was found to be significantly lower than all single-serving coffee makers examined at a 95% confidence level (95% CL), highlighting its superior energy efficiency.</p>
</sec>
<sec id="S2_7">
<title>Environmental impact of green coffee production</title>
<p>Coffee cultivation&#x2019;s environmental impact has been a focus of extensive research, revealing significant issues such as deforestation, biodiversity loss, habitat fragmentation, and pollution from wastewater and processing residues (<xref ref-type="bibr" rid="ref71">Phrommarat, 2019</xref>).</p>
<p>Several LCAs have produced widely varying estimations of carbon footprint of coffee production, with values ranging from 3.7 kg to 15.8 kg carbon dioxide equivalent (CO<sub>2e</sub>)/kg of GCB (<xref ref-type="bibr" rid="ref8">Arzoumanidis <italic>et al</italic>., 2017</xref>; <xref ref-type="bibr" rid="ref17">Coltro <italic>et al</italic>., 2006</xref>; <xref ref-type="bibr" rid="ref21">Dom&#x00ED;nguez-Pati&#x00F1;o <italic>et al</italic>., 2014</xref>; <xref ref-type="bibr" rid="ref44">Humbert <italic>et al</italic>., 2009</xref>; <xref ref-type="bibr" rid="ref54">Killian <italic>et al</italic>., 2013</xref>; <xref ref-type="bibr" rid="ref69">PCF Pilotprojekt Deutschland, 2008</xref>). For instance, <xref ref-type="bibr" rid="ref69">PCF Pilotprojekt Deutschland (2008)</xref> attributed 55% of carbon footprint to cultivation and on-farm processing, and 30% carbon footprint to consumption, while <xref ref-type="bibr" rid="ref44">Humbert <italic>et al</italic>. (2009)</xref> similarly found that about half of the total environmental impact originated from the processes (such as cultivation, treatment, processing, packaging, and distribution) controlled by coffee producers and suppliers, with the rest attributed to consumers (use and post-consumer disposal).</p>
<p>Key findings of the recent studies are as follows:</p>
<p><list list-type="bullet">
<list-item><p><italic>Brazilian coffee production</italic>: <xref ref-type="bibr" rid="ref17">Coltro <italic>et al</italic>. (2006)</xref> highlighted substantial water, energy, and fertilizer inputs required for Brazilian coffee bean production.</p></list-item>
<list-item><p><italic>Central American Arabica carbon footprint</italic>: <xref ref-type="bibr" rid="ref6">Arellano and Hern&#x00E1;ndez (2023)</xref> reviewed Arabica coffee production in Central America, identifying application of nitrogen fertilizer as the primary emission factor, particularly in intensified unshaded plantations. The authors found that traditional polycultures had a lower carbon footprint (0.51 kg CO<sub>2e</sub>/kg cherry coffee) and higher carbon storage (53.6 MT/ha), compared to unshaded monocultures (0.64 kg CO<sub>2e</sub>/kg and 9.7 MT/ha, respectively). Shade trees are crucial for carbon conservation, with agroecosystems retaining about 28% of tropical forest&#x2019;s aboveground biomass carbon, while unshaded monocultures lost 95%.</p></list-item>
<list-item><p><italic>Vietnam coffee carbon footprint</italic>: <xref ref-type="bibr" rid="ref63">Nab and Maslin (2020)</xref> estimated the carbon footprint of conventional Arabica coffee production in Vietnam as 15.3 kg CO<sub>2e</sub>/kg of green coffee. However, the authors found that sustainable coffee production significantly reduced this by 77%, to 3.5 kg CO<sub>2e</sub>/kg, this being primarily attributed to decreased agrochemical inputs and exportation of coffee beans via cargo ship rather than freight flight.</p></list-item>
<list-item><p><italic>Indonesian coffee sustainability</italic>: <xref ref-type="bibr" rid="ref74">Rahmah <italic>et al</italic>. (2022)</xref> assessed Indonesian coffee systems, finding that organic fertilizing systems (OFS) offered superior environmental and economic benefits. In contrast, chemical fertilizing systems (CFS) had the highest environmental impact, lowest economic returns, and the highest energy consumption. While OFS increased energy use, chemical organic systems presented a viable energy-efficient alternative. The study identified fertilizer (especially NPK) and rice husk as key environmental hotspots.</p></list-item>
</list></p>
<p>Researchers consistently recommend several strategies to mitigate these impacts:</p>
<p><list list-type="bullet">
<list-item><p>Optimizing nitrogen application</p></list-item>
<list-item><p>Using low nitrification/denitrification potential fertilizers</p></list-item>
<list-item><p>Exploring mycorrhizal fungi or nitrogen-fixing bacteria</p></list-item>
<list-item><p>Incorporating functional trees (shade and/or nitrogen fixers)</p></list-item>
<list-item><p>Implementing soil conservation practices</p></list-item>
<list-item><p>Utilizing biofertilizers</p></list-item>
</list></p>
<p>Implementing these recommendations through proper certification schemes could lead to even greater environmental benefits required for coffee cultivation.</p>
<p>Based on the production of various GCB varieties (Arabica and Robusta) at the farm gate (FG), cultivated in different countries under diverse agricultural conditions (see <xref ref-type="table" rid="T1">Table 1</xref>), <xref ref-type="table" rid="T3">Table 3</xref> presents 16 environmental impact categories of the PEF standard method (<xref ref-type="bibr" rid="ref29">European Commission, 2021</xref>) estimated using the LCA SimaPro Craft 10.2.0.0 software.</p>
<table-wrap id="T3" orientation="portrait" position="float">
<label>Table 3.</label><caption><p>Environmental profile for 1 kg of green Arabica or Robusta coffee beans at farm gate.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left" colspan="2">Coffee variety</th>
<th align="center">Arabica</th>
<th align="center">Arabica</th>
<th align="center">Arabica</th>
<th align="center">Arabica</th>
<th align="center">Robusta</th>
<th align="center">Robusta</th>
<th align="center">Robusta</th>
<th align="center">Robusta</th>
</tr>
<tr>
<th align="left">Country</th>
<th align="center"></th>
<th align="center">BR</th>
<th align="center">CO</th>
<th align="center">HR</th>
<th align="center">IN</th>
<th align="center">VN</th>
<th align="center">IN</th>
<th align="center">ID</th>
<th align="center">BR</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left"><bold>IC</bold></td>
<td align="center"><bold>Unit</bold></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">CC</td>
<td align="center">kg CO<sub>2e</sub></td>
<td align="center">4.91</td>
<td align="center">6.56</td>
<td align="center">10.20</td>
<td align="center">17.7</td>
<td align="center">6.64</td>
<td align="center">8.40</td>
<td align="center">18.1</td>
<td align="center">2.79</td>
</tr>
<tr>
<td align="left">OD</td>
<td align="center">kg CFC<sub>11e</sub></td>
<td align="center">3.6&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">3.1&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">6.6&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">1.7&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">3.2&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">7.5&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">8.1&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">2.6&#x00D7;10<sup>&#x2013;8</sup></td>
</tr>
<tr>
<td align="left">IR</td>
<td align="center">kBq U<sub>e</sub><sup>235</sup></td>
<td align="center">1.6&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">1.3&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">7.8&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">2.2&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">4.6&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">9.3&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">1.1&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">3.2&#x00D7;10<sup>&#x2013;2</sup></td>
</tr>
<tr>
<td align="left">PhOF</td>
<td align="center">kg NMVOC<sub>e</sub></td>
<td align="center">2.8&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">4.1&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">3.6&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">9.9&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">2.1&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">4.6&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">5.6&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">1.4&#x00D7;10<sup>&#x2013;2</sup></td>
</tr>
<tr>
<td align="left">PM</td>
<td align="center">Disease inc.</td>
<td align="center">7.75&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">9.4&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">1.8&#x00D7;10<sup>&#x2013;6</sup></td>
<td align="center">6.3&#x00D7;10<sup>&#x2013;6</sup></td>
<td align="center">4.6&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">2.9&#x00D7;10<sup>&#x2013;6</sup></td>
<td align="center">3.0&#x00D7;10<sup>&#x2013;6</sup></td>
<td align="center">3.6&#x00D7;10<sup>&#x2013;7</sup></td>
</tr>
<tr>
<td align="left">AC</td>
<td align="center">mol H<sub>e</sub><sup>+</sup></td>
<td align="center">1.0&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">1.3&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">2.2&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">9.0&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">4.5&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">4.2&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">3.8&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">4.5&#x00D7;10<sup>&#x2013;2</sup></td>
</tr>
<tr>
<td align="left">FWE</td>
<td align="center">kg P<sub>e</sub></td>
<td align="center">1.7&#x00D7;10<sup>&#x2013;3</sup></td>
<td align="center">3.2&#x00D7;10<sup>&#x2013;3</sup></td>
<td align="center">1.8&#x00D7;10<sup>&#x2013;3</sup></td>
<td align="center">3.7&#x00D7;10<sup>&#x2013;3</sup></td>
<td align="center">8.6&#x00D7;10<sup>&#x2013;4</sup></td>
<td align="center">1.7&#x00D7;10<sup>&#x2013;3</sup></td>
<td align="center">2.9&#x00D7;10<sup>&#x2013;3</sup></td>
<td align="center">8.3&#x00D7;10<sup>&#x2013;4</sup></td>
</tr>
<tr>
<td align="left">ME</td>
<td align="center">kg N<sub>e</sub></td>
<td align="center">3.5&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">1.7&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">1.1&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">1.7&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">3.1&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">7.8&#x00D7;10<sup>&#x2013;2</sup></td>
<td align="center">1.9&#x00D7;10<sup>&#x2013;1</sup></td>
<td align="center">1.8&#x00D7;10<sup>&#x2013;2</sup></td>
</tr>
<tr>
<td align="left">TE</td>
<td align="center">mol N<sub>e</sub></td>
<td align="center">0.41</td>
<td align="center">0.54</td>
<td align="center">0.96</td>
<td align="center">4.0</td>
<td align="center">0.19</td>
<td align="center">1.87</td>
<td align="center">1.67</td>
<td align="center">0.18</td>
</tr>
<tr>
<td align="left">FWET</td>
<td align="center">CTU<sub>e</sub></td>
<td align="center">840</td>
<td align="center">599</td>
<td align="center">311</td>
<td align="center">489</td>
<td align="center">180</td>
<td align="center">230</td>
<td align="center">418</td>
<td align="center">127</td>
</tr>
<tr>
<td align="left">C-HT</td>
<td align="center">CTU<sub>h</sub></td>
<td align="center">1.9&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">3.8&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">2.4&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">4.8&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">1.6&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">2.2&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">4.2&#x00D7;10<sup>&#x2013;8</sup></td>
<td align="center">8.0&#x00D7;10<sup>&#x2013;9</sup></td>
</tr>
<tr>
<td align="left">NC-HT</td>
<td align="center">CTU<sub>h</sub></td>
<td align="center">4.9&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">2.6&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">3.4&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">1.9&#x00D7;10<sup>&#x2013;6</sup></td>
<td align="center">5.1&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">8.7&#x00D7;10<sup>&#x2013;7</sup></td>
<td align="center">1.8&#x00D7;10<sup>&#x2013;6</sup></td>
<td align="center">4.7&#x00D7;10<sup>&#x2013;7</sup></td>
</tr>
<tr>
<td align="left">LU</td>
<td align="center">Pt</td>
<td align="center">442</td>
<td align="center">1160</td>
<td align="center">592</td>
<td align="center">961</td>
<td align="center">305</td>
<td align="center">416</td>
<td align="center">742</td>
<td align="center">157</td>
</tr>
<tr>
<td align="left">WU</td>
<td align="center">m<sup>3</sup>depriv.</td>
<td align="center">2.96</td>
<td align="center">2.14</td>
<td align="center">2.47</td>
<td align="center">20.8</td>
<td align="center">12.7</td>
<td align="center">8.29</td>
<td align="center">4.72</td>
<td align="center">0.63</td>
</tr>
<tr>
<td align="left">RUF</td>
<td align="center">MJ</td>
<td align="center">41.9</td>
<td align="center">51.6</td>
<td align="center">38.4</td>
<td align="center">127</td>
<td align="center">22.0</td>
<td align="center">57.6</td>
<td align="center">60.0</td>
<td align="center">18.7</td>
</tr>
<tr>
<td align="left">RUMM</td>
<td align="center">kg Sb<sub>e</sub></td>
<td align="center">8.6&#x00D7;10<sup>&#x2013;5</sup></td>
<td align="center">6.3&#x00D7;10<sup>&#x2013;5</sup></td>
<td align="center">2.5&#x00D7;10<sup>&#x2013;5</sup></td>
<td align="center">9.9&#x00D7;10<sup>&#x2013;5</sup></td>
<td align="center">2.4&#x00D7;10<sup>&#x2013;5</sup></td>
<td align="center">4.4&#x00D7;10<sup>&#x2013;5</sup></td>
<td align="center">4.7&#x00D7;10<sup>&#x2013;5</sup></td>
<td align="center">1.6&#x00D7;10<sup>&#x2013;5</sup></td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF3-1"><p>Notes: Product environmental footprint (PEF) method&#x2019;s 16 impact categories (IC) for selected growing regions (Brazil, BR; Colombia, CO; Honduras, HR; India, IN; Indonesia, ID; and Vietnam, VN). AC: acidification (mol H<sup>+</sup><sub>e</sub>); CC: climate change (kg CO<sub>2e</sub>); CFC<sub>11e</sub>): trichlorofluoromethane (expressed as equivalent); C-HT: human toxicity, cancer (CTU<sub>e</sub>); CTU<sub>e</sub>: Comparative Toxic Unit for freshwater ecosystems (expressed as equivalent); CTU<sub>h</sub>: Comparative Toxic Unit for human (expressed as equivalent); FWE: freshwater eutrophication [kg P<sub>e</sub>]; FWET: ecotoxicity, freshwater [CTU<sub>e</sub>]; IR: ionizing radiation [kBq<sup>235</sup>U<sub>e</sub>]; LU: land use [Pt]; ME: marine eutrophication [kg N<sub>e</sub>]; NC-HT: human toxicity, non-cancer (CTU<sub>e</sub>); NMVOC<sub>e</sub>: non-methane volatile organic compounds (expressed as equivalent); OD: ozone depletion (kg CFC<sub>11e</sub>); PhOF: photochemical ozone formation (kg NMVOC<sub>e</sub>); PM: particulate matter (disease inc.); RUF: resource use fossils [MJ]; RUMM: resource use minerals and metals [kg Sb<sub>e</sub>]; TE: terrestrial eutrophication (mol N<sub>e</sub>); and WU: water use (m<sup>3</sup> deprived).</p></fn></table-wrap-foot>
</table-wrap>
<p>Environmental impact data for GCBs, as observed in <xref ref-type="table" rid="T3">Table 3</xref>, revealed considerable diversity based on coffee variety (Arabica and Robusta) and the country of origin (Brazil, Vietnam, India, Indonesia, Colombia, and Honduras). Generally, Arabica coffee exhibits a higher PEF across various categories, compared to Robusta.</p>
<p>For climate change (CC [kg CO<sub>2e</sub>]) impacts, Arabica typically has higher scores, reaching approximately 18 kg CO<sub>2e</sub>/kg in India, while Brazil&#x2019;s Robusta stands out for its very low emissions of 2.8 kg CO<sub>2e</sub>/kg. In terms of ozone depletion (OD [kg CFC<sub>11e</sub>]), while overall potential is relatively low, it can vary up to 14-fold, with Brazil showing both extremes depending on the variety. Arabica coffee also generally shows a higher impact than Robusta for ionizing radiation, photochemical ozone formation (PhOF [kg NMVOC<sub>e</sub>]), and particulate matter (PM) formation, particularly in case of India, whereas Brazil&#x2019;s Robusta consistently presents the lowest impact in these fields.</p>
<p>Eutrophication and acidification (AC) are significant environmental impacts of coffee production, stemming from excessive nutrient and acid deposition across freshwater, marine, and terrestrial ecosystems. Across all categories for both impacts, Arabica coffee consistently demonstrates a higher potential than Robusta. For eutrophication, Brazil generally represents the lowest impact source, while India and Southeast Asian origins (specifically Indonesia for marine eutrophication) tend to have the highest values. Similarly, Arabica is considerably more acidifying, with Arabica from India showing the highest acidification potential (0.90 mol H<sub>e</sub><sup>+</sup>), a more than 20-fold difference compared to Robusta in Brazil (0.045 mol H<sub>e</sub><sup>+</sup>). These trends indicate that cultivation practices, including fertilizer use and runoff management, associated with different coffee varieties and regions, significantly influence their PEF regarding nutrient pollution and acidification.</p>
<p>Regarding toxicity, Arabica from Brazil shows an unusually high impact for freshwater ecotoxicity (840 CTU<sub>e</sub>), significantly exceeding Robusta from the same region (127 CTU<sub>e</sub>), suggesting that local agrochemical use could be a factor.</p>
<p>For human toxicity, both cancer (C-HT)- and non-cancer (NC-HT)-related impacts are generally higher for Arabica, compared to Robusta. While the cancer toxicity footprint is minor, it is not negligible, with Robusta consistently showing lower values (e.g., Robusta in Brazil at 8.0&#x00D7;10<sup>-9</sup> CTU<sub>h</sub>, compared to Arabica in India at 4.8&#x00D7;10<sup>-8</sup> CTU<sub>h</sub>). Arabica demonstrates higher non-cancer toxicity (e.g., Arabica in India at 1.90&#x00D7;10<sup>-6</sup> CTU<sub>h</sub>, compared to Robusta in Brazil at 4.7&#x00D7;10<sup>-7</sup> CTU<sub>h</sub>), indicating a more pronounced human toxicity footprint for Arabica cultivation in these regions.</p>
<p>Land use requirements are considerably higher for Arabica coffee, with Arabica from Colombia exhibiting the highest land use impact (1,160 Pt) and Robusta from Brazil the lowest (157 Pt), highlighting differing cultivation needs and efficiency.</p>
<p>Water use efficiency also varies significantly, with Brazil&#x2019;s Robusta being vastly more efficient; Arabica from India shows the highest water consumption (20.8 m<sup>3</sup> deprived), contrasting sharply with Robusta from Brazil (0.63 m<sup>3</sup> deprived).</p>
<p>Fossil resource consumption is notably higher for Arabica, with Arabica from India demanding more than six times more fossil energy (127 MJ), compared to Robusta from Brazil (18.7 MJ). Similarly, Arabica from India also has the highest mineral and metal resource intensity (9.9&#x00D7;10<sup>-5</sup> kg Sb<sub>e</sub>), making it the most resource-intensive in this category, while Robusta from Brazil again demonstrates the lowest impact (1.6&#x00D7;10<sup>-5</sup> kg Sb<sub>e</sub>).</p>
<p>After normalizing impact category scores and weighing them to reflect their perceived importance, the overall PEF score, expressed in micro-points per kilogram (&#x00B5;Pt/kg), represents the combined environmental impact across all categories. As shown in <xref ref-type="table" rid="T4">Table 4</xref>, Arabica coffee consistently demonstrates a higher PEF across almost all categories, compared to Robusta, with India (Arabica) showing the highest impacts and Brazil (Robusta) consistently presenting the lowest, making Robusta from Brazil the most environment-sustainable choice.</p>
<table-wrap id="T4" orientation="portrait" position="float">
<label>Table 4.</label><caption><p>Sustainability ranking of 1 kg of green Arabica and Robusta coffee beans at farm gate for a few selected growing regions according to the overall PEF score.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Rank</th>
<th align="left" colspan="2">Coffee variety and origin</th>
<th align="left">Overall environmental impact</th>
<th align="center">PEF (&#x03BC;Pt/kg)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">1</td>
<td align="left">Robusta</td>
<td align="left">Brazil</td>
<td align="left">Lowest impact across almost all categories</td>
<td align="center">459</td>
</tr>
<tr>
<td align="left">2</td>
<td align="left">Robusta</td>
<td align="left">Vietnam</td>
<td align="left">Low land, toxicity, and water impact</td>
<td align="center">764</td>
</tr>
<tr>
<td align="left">3</td>
<td align="left">Arabica</td>
<td align="left">Brazil</td>
<td align="left">Balanced, moderate impact overall</td>
<td align="center">1,167</td>
</tr>
<tr>
<td align="left">4</td>
<td align="left">Arabica</td>
<td align="left">Colombia</td>
<td align="left">High land and ecotoxicity burden</td>
<td align="center">1,495</td>
</tr>
<tr>
<td align="left">5</td>
<td align="left">Arabica</td>
<td align="left">Honduras</td>
<td align="left">Moderate impact, especially water and land</td>
<td align="center">1,575</td>
</tr>
<tr>
<td align="left">6</td>
<td align="left">Robusta</td>
<td align="left">India</td>
<td align="left">Higher ionizing radiation and eutrophication</td>
<td align="center">2,196</td>
</tr>
<tr>
<td align="left">7</td>
<td align="left">Robusta</td>
<td align="left">Indonesia</td>
<td align="left">High in almost all environmental categories</td>
<td align="center">2,828</td>
</tr>
<tr>
<td align="left">8</td>
<td align="left">Arabica</td>
<td align="left">India</td>
<td align="left">Highest impact across nearly all categories</td>
<td align="center">4,744</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF4-1"><p>Notes: PEF: product environmental footprint.</p></fn></table-wrap-foot>
</table-wrap>
</sec>
<sec id="S2_8">
<title>Environmental impact of coffee consumption</title>
<p>The environmental impacts of coffee consumption account for a significant portion of the total environmental impact, ranging from 30% to 50% (<xref ref-type="bibr" rid="ref44">Humbert <italic>et al</italic>., 2009</xref>; <xref ref-type="bibr" rid="ref69">PCF Pilotprojekt Deutschland, 2008</xref>), with these figures depending on specific coffee preparation methods and types used (<xref ref-type="bibr" rid="ref13">B&#x00FC;sser and Jungbluth, 2009</xref>).</p>
<p>Concerning the coffee preparation methods used commonly, in Italy Moka pot is the predominant method for preparing coffee at home, typically using ground coffee. Globally, a diverse array of coffee machines exists apart from Moka pot (see Section 2.5). The country-wise market share of these brewers varies significantly. For instance, electric drip-filter coffee machines maintained a market share of 55% in the United States (<xref ref-type="bibr" rid="ref55">Kraeutler <italic>et al</italic>., 2015</xref>) and 62% in Germany (<xref ref-type="bibr" rid="ref11">Brommer <italic>et al</italic>., 2011</xref>). In these drip brewers, the brewed coffee is stored in a continuously heated reservoir. A notable drawback of many of these machines is their energy inefficiency, as they often lack auto-power down features, leading to up to three-fourths of their total electricity consumption occurring in a standby mode to keep the beverage hot (<xref ref-type="bibr" rid="ref12">Bush <italic>et al</italic>., 2009</xref>). In contrast, single-serve coffee makers are designed to force a precise volume of hot water through pre-packaged coffee dispensers, such as pods and capsules. These machines compress and heat water to a pressure ranging from 3 bar to 19 bar and temperature ranging from 93 &#x00B0;C to 95 &#x00B0;C, with power consumption typically ranging from 400 W to 1,500 W.</p>
<p><xref ref-type="bibr" rid="ref11">Brommer <italic>et al</italic>. (2011)</xref> estimated the business-to-consumer GHG emissions associated with the preparation of 2,000 cups of coffee (125 mL each), these being averagely consumed in German families on a year basis. The agriculture phase was responsible for 55.4% of the overall GHG emissions, followed by the consumer and post-consumer phases (36%), coffee roasting, packaging, and distribution (6.6%), and overseas transportation (1.9%).</p>
<p><xref ref-type="bibr" rid="ref38">Hassard <italic>et al</italic>. (2014)</xref> assessed the carbon footprint and energy consumption of different coffee products in Japan, showing that most GHGs were released from coffee cultivation and production, while processing and preparation involved higher consumption of energy.</p>
<p><xref ref-type="bibr" rid="ref42">Hicks (2017)</xref> conducted a comparative LCA in the United States, concluding that coffee pods were the most environment-friendly option between drip filter, French press, and pod coffee machines.</p>
<p>An LCA commissioned to Quantis-Canada by the Packaging Consortium concluded that an 8-oz (236.6 mL) cup of coffee prepared using single-serve coffee systems exhibited a superior environmental performance compared to drip-brewed systems in North America (<xref ref-type="bibr" rid="ref14">Chayer and Kicak, 2015</xref>). This was primarily attributed to the accurate dosage of ground coffee (reducing waste) and the potential for energy-saving machines with longer service lifespan. The authors found that reduction in ground coffee and electricity consumption offset the increased packaging waste generated by single-serve systems.</p>
<p><xref ref-type="bibr" rid="ref71">Phrommarat (2019)</xref>, conducting a cradle-to-grave assessment of organically farmed Arabica coffee in Thailand, found Moka pot (heated on an electric plate) to be particularly energy-intensive. This energy demand led to damage of non-renewable resources directly related to the consumption of electricity from fossil sources and to human health. This conclusion strongly suggests that, within the context of Thailand&#x2019;s electricity grid at the time of the study, which probably relied significantly on fossil fuels, the Moka pot&#x2019;s energy consumption translated directly into substantial environmental burdens. The high proportion of nonrenewable sources in the electricity mix would amplify the impact of any energy-intensive appliance.</p>
<p>Conversely, <xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>. (2021)</xref>, in a study on Italian coffee consumption, specifically assessed the carbon footprint of a 40-mL cup prepared in a three-cup Moka pot heated by either an induction- or a gas-fired stove. They reported emissions of 45&#x2013;57-g CO<sub>2e</sub> and 47&#x2013;59-g CO<sub>2e</sub> per cup, respectively. Crucially, their comparison to single-serve machines (espresso, pod, and capsule) showed that preparing coffee with a pod or capsule machine resulted in extra emissions of 12.6&#x2013;27.6-g CO<sub>2e</sub>, compared to an induction Moka pot. This finding implies that, within the Italian energy context, Moka pot, particularly when using electricity (induction) from a grid that has a more favorable mix of renewable and nonrenewable sources, compared to Thailand, or gas, presents a relatively lower carbon-emitting option, compared to the combined impact of single-serve systems (including their packaging).</p>
<p>While both <xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>. (2021)</xref> and <xref ref-type="bibr" rid="ref71">Phrommarat (2019)</xref> assessed the environmental impact of coffee preparation using a Moka pot, their conclusions, although apparently divergent, are largely influenced by the distinct energy mixes of their respective study regions&#x2014;Thailand and Italy. The differing conclusions highlight that the environmental performance of an appliance is not solely inherent to the appliance itself but is significantly shaped by the energy infrastructure of the region where it is used. In case electricity grids rely heavily on fossil fuels, any energy-intensive brewing method naturally shows a higher environmental burden related to resource depletion and emissions. Conversely, in regions with a cleaner energy mix, the same appliance could appear more favorable, especially compared to the alternatives that carry additional burdens of packaging or other life cycle stages.</p>
<p>A recent report conducted by <xref ref-type="bibr" rid="ref24">Eneroth <italic>et al</italic>. (2022)</xref>, intended for Swedish consumers, detailed the environmental impacts of coffee, tea, and cocoa, specifically quantifying climate impact, land use, biodiversity, and water use. For coffee, the climate impact of roasted ground coffee on the Swedish market was 4.0 kg CO<sub>2e</sub>/kg powder, while instant coffee powder had a higher impact at 11.5 kg CO<sub>2e</sub>/kg. When considering prepared beverages, the total climate impact per liter, including energy for brewing, was estimated at 0.25 kg CO<sub>2e</sub> for brewed coffee and 0.16 kg CO<sub>2e</sub> for instant coffee. Notably, less GCBs are needed to produce the same amount of ready-to-drink instant coffee, compared to brewed coffee. Instant black coffee per cup registered 24-g CO<sub>2e</sub>, and brewed black coffee showed 38-g CO<sub>2e</sub>. The report highlighted that adding milk to coffee substantially increases its climate impact. Although the existing literature often attributes a significant portion of coffee&#x2019;s total climate impact to the consumer stage due to machine&#x2019;s electricity use, <xref ref-type="bibr" rid="ref24">Eneroth <italic>et al</italic>. (2022)</xref> observed that with the Nordic region&#x2019;s low-carbon energy mix, contributions from brewing and heating water and milk were minor. Another crucial factor at the consumer stage is the waste of prepared coffee; this wastage contributes to climate impact through additional production costs and electricity consumed in preparation, although the latter&#x2019;s contribution was calculated as small. The report concluded that household coffee waste is substantial and reducing it could significantly decrease the environmental impact of Swedish hot drink consumption.</p>
<p>It is important to note that direct comparisons across various coffee LCA studies are often challenging because of significant differences in methodologies. These disparities include variations in coffee varieties (e.g., Arabica vs. Robusta), farming practices (conventional and organic), cultivation locations, beverage volumes (ranging from 40 mL to 237 mL), and brewing methods (using roasted coffee beans, ground coffee, or coffee packed in pods and capsules made from different materials). Furthermore, the specific coffee brewing method adopted by the consumer and the energy efficiency of the used appliance have a considerable effect on the environmental impact of the use phase.</p>
</sec>
<sec id="S2_9">
<title>Environmental impact of coffee packaging</title>
<p>Early research done by <xref ref-type="bibr" rid="ref20">De Monte <italic>et al</italic>. (2005)</xref> established foundational insights into the environmental impact of various coffee packaging formats through an LCA. Their study compared metallic cans, glass jars, and poly-laminated bags, analyzing the entire life cycle from raw material extraction to disposal. While poly-laminated bags offered a lighter alternative for small packages, their poor recyclability meant that metallic cans and glass jars were generally preferred in case material recycling was prioritized due to their established infrastructure and higher recovery proportions. Lighter weight and lower transport emissions of poly-laminated bags were often offset by a higher environmental impact at the end-of-life stage because of the inherent difficulty in recycling multi-layered materials.</p>
<p>Continuing this line of inquiry, <xref ref-type="bibr" rid="ref40">Heller&#x2019;s (2017)</xref> report further synthesized findings from various LCA studies on coffee consumption. Heller identified packaging as a critical contributor to coffee&#x2019;s overall PEF, particularly during the consumer use phase. His analysis highlighted that the following:</p>
<p><list list-type="bullet">
<list-item><p><italic>Single-serve coffee formats</italic> (e.g., pods/capsules) generally have a higher environmental impact per serving than bulk or traditionally brewed coffee. This is primarily due to the material and energy-intensive production of the capsules, which are often made from mixed materials (plastic, aluminum, etc.), difficult to recycle.</p></list-item>
<list-item><p><italic>The material weight and type of packaging</italic> are substantial drivers of environmental impact. While coffee cultivation accounts for a large portion of the overall footprint, packaging, especially for smaller portion sizes, can disproportionately contribute to the issues such as resource depletion, waste generation, and climate change per cup.</p></list-item>
<list-item><p>Studies indicate that the <italic>environmental burden from packaging</italic>, particularly for single-serve systems, often exceeds the impacts of the disposal of traditional ground coffee, even when considering brewing energy. The energy consumed by some single-serve machines can also be higher compared to conventional brewing methods.</p></list-item>
<list-item><p>The <italic>end-of-life management of packaging</italic> is a major factor. If single-serve capsules are not effectively recycled (often because of material complexity or lack of accessible infrastructure), their environmental impact from landfilling or incineration increases significantly.</p></list-item>
<list-item><p>Conversely, <italic>bulk coffee</italic> or <italic>coffee sold in larger and more easily recyclable packaging</italic> (e.g., recyclable bags or tins for ground/whole beans) tends to have a lower PEF associated with packaging per serving. The reusability of brewing equipment for traditional coffee further reduces the overall impact.</p></list-item>
</list></p>
<p><xref ref-type="bibr" rid="ref40">Heller&#x2019;s (2017)</xref> report concluded that while cultivation and on-farm processing are significant hotspots for coffee, packaging formats, especially single-serve capsules, impose a disproportionately high environmental burden per serving, compared to traditional coffee formats. This is primarily due to material intensity, recycling difficulties, and associated energy consumption.</p>
<p>More recently, <xref ref-type="bibr" rid="ref58">Marinello <italic>et al</italic>. (2021)</xref> provided a comprehensive review specifically on the environmental impacts of coffee capsules, focusing on recovery and management techniques. This review corroborated and expanded upon <xref ref-type="bibr" rid="ref40">Heller&#x2019;s (2017)</xref> findings regarding the challenges of complex capsule materials.</p>
<p><xref ref-type="bibr" rid="ref58">Marinello <italic>et al</italic>. (2021)</xref> highlighted significant difficulties with polylaminate materials (e.g., plastics and aluminum foil) commonly found in popular coffee capsules. Their multi-layered composition makes them difficult to manage and recycle through traditional methods. In contrast, the review noted encouraging aspects in the recovery of single-material plastics (such as PP) and metals (such as aluminum), as capsules predominantly made from these materials offer better potential for recycling than multi-layered polylaminates.</p>
<p>Although <xref ref-type="bibr" rid="ref58">Marinello <italic>et al</italic>. (2021)</xref> did not provide a quantified ranking from a single primary LCA study, they synthesized insights from various studies to infer an environmental impact ranking for coffee capsules:</p>
<p><list list-type="bullet">
<list-item><p>Capsules made from single and more easily recyclable materials (e.g., aluminum or specific plastics, such as PP) generally present a lower environmental impact. This is particularly true for waste management and resource depletion, assuming effective recycling infrastructure and strong consumer participation. However, challenges often arise due to their small size, residual ground coffee, and consumer confusion regarding recycling protocols.</p></list-item>
<list-item><p>Conversely, capsules made from complex polylaminates tend to have a higher environmental impact. This is primarily due to the difficulty in managing and recycling them. Their multi-layered composition hinders material separation for recycling, frequently leading to incineration or landfilling, which contributes to increased waste generation and resource depletion. Currently, recovery techniques for these materials are often inefficient or even nonexistent for widespread implementation.</p></list-item>
</list></p>
<p>Overall, <xref ref-type="bibr" rid="ref58">Marinello <italic>et al</italic>. (2021)</xref> emphasized that, despite the growth fueled by coffee capsule convenience, the environmental consequences, especially regarding packaging waste management, remain a critical area for ongoing research and improvement in recovery techniques. The &#x201C;encouraging aspects&#x201D; mentioned specifically refer to the development of methods for recovering materials, indicating that the current widespread disposal of capsules (especially polylaminates) poses a major environmental concern.</p>
<p>These studies collectively underscore that while coffee cultivation is a primary environmental consideration, packaging, particularly single-serve formats and multi-layered materials, contributes disproportionately to the overall environmental burden at the consumer use phase. Strategies to reduce coffee&#x2019;s PEF should, therefore, strongly consider shifts toward more sustainable packaging solutions and promote traditional brewing methods to mitigate impacts from the consumer use phase.</p>
<p>The main problem with small coffee portions is the high ratio between the mass of the overall packaging materials and the ground coffee. While GCBs are generally packed in 1,000-kg flexible PE supersacks weighing approximately 3 kg each, they are transported by truck from the farm gate to the nearest harbor. From there, they are dispatched by cargo to a nearby harbor in the processing country, and then by truck to the roasting and grinding plant. At plant, RGC powder of an appropriate size is mixed before being packaged in various formats to be commercially available in supermarkets or online. As an example, to illustrate different packaging material-to-ground coffee ratios, diverse formats as shown in <xref ref-type="table" rid="T5">Table 5</xref>, all considered primary packaging units, are examined. Thus, based on the available information and comparisons to similar products, such data provide informed estimates of the single-serving portions of coffee available on the market.</p>
<table-wrap id="T5" orientation="portrait" position="float">
<label>Table 5.</label><caption><p>Mass of packaging material and ground coffee for various primary single-serving formats.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Format</th>
<th align="left">Description</th>
<th align="left">Main items</th>
<th align="center">Item mass (g)</th>
<th align="left">Source/comments</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">F1</td>
<td align="left">250-g coffee flexible multilayer bag</td>
<td align="left">RGC<break/>PE (0.735)-Al (0.143)-PP (0.122) bag</td>
<td align="center">250.0<break/>7.86&#x00B1;0.20</td>
<td align="left"><xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref></td>
</tr>
<tr>
<td align="left">F2</td>
<td align="left">Coffee pods</td>
<td align="left">RGC<break/>Paper filter<break/>PE-Al-PET pouch</td>
<td align="center">7.23&#x00B1;0.02<break/>0.180&#x00B1;0.002<break/>1.51&#x00B1;0.01</td>
<td align="left"><xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref></td>
</tr>
<tr>
<td align="left">F3</td>
<td align="left" rowspan="5">Coffee capsules</td>
<td align="left">RGC<break/>Al capsule (AIC)<break/>Upper Al lid<break/>Abaca-based filter<break/>Nitrogen fill</td>
<td align="center">~5.5<break/>1.0<break/>0.25<break/>~0.28<break/>0.43</td>
<td align="left">OnWin, n.d.a</td>
</tr>
<tr>
<td align="left">F4</td>
<td align="left">RGC<break/>PP capsule<break/>Upper Al lid<break/>Paper-based filter<break/>Nitrogen fill</td>
<td align="center">~5.5<break/>3.0<break/>0.25<break/>~0.28<break/>0.43</td>
<td align="left">AFPAK, n.d.</td>
</tr>
<tr>
<td align="left">F5</td>
<td align="left">RGC<break/>PE-Al-PET capsule <break/>Upper Al lid<break/>Nitrogen fill</td>
<td align="center">5.75&#x00B1;0.07<break/>1.05&#x00B1;0.02<break/>0.110&#x00B1;0.002<break/>0.43</td>
<td align="left"><xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref></td>
</tr>
<tr>
<td align="left">F6</td>
<td align="left">RGC<break/>PBS/PLA capsule<break/>PLA-based lid<break/>PLA-based filter<break/>Nitrogen fill</td>
<td align="center">~5.5<break/>~2.6<break/>~0.3<break/>~0.3<break/>0.43</td>
<td align="left">OnWin, n.d.b</td>
</tr>
<tr>
<td align="left">F7</td>
<td align="left">RGC<break/>Paper-based capsule <break/>Upper paper-based lid<break/>PLA-based filter<break/>Nitrogen fill</td>
<td align="center">~5.5<break/>~2.6<break/>~0.3<break/>~0.3<break/>0.43</td>
<td align="left"><bold>1</bold></td>
</tr>
<tr>
<td align="left">F8</td>
<td align="left">Coffee balls</td>
<td align="left">RGC<break/>Biopolymer film coating</td>
<td align="center">5.6 (5.3-5.9)<break/>~0.3</td>
<td align="left"><bold>2</bold></td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF5-1"><p>Notes: <sup>1</sup>Nespresso<sup>&#x00AE;</sup> has not disclosed exact mass breakdown of paper-based capsules (<ext-link ext-link-type="uri" xlink:href="https://nestle-nespresso.com/nespresso-unveils-new-range-home-compostable-coffee-capsules?utm_source=chatgpt.com">https://nestle-nespresso.com/nespresso-unveils-new-range-home-compostable-coffee-capsules?utm_source=chatgpt.com</ext-link>; accessed: 10 June 2025). Therefore, these estimates are based on comparable compostable capsules.</p></fn>
<fn id="TF5-2"><label>2</label><p>CoffeeB did not disclose the specific biopolymer or the mass of the coating film used. Therefore, an average coffee ball with a 15-mm radius was assumed. This ball was presumed to be coated with an aqueous solution of Arabic gum (33.33% w/w concentration, 1,125-kg/m<sup>3</sup> density), forming a 282-mm wet film. This film was then dried to a 99% (w/w) solid content.</p></fn>
<fn id="TF5-3"><p>RGC: roasted and ground coffee; PBS: poly-(butylene succinate); F3: Al capsule; F4: PP capsule; F5: multilayer PE-Al-PET capsule; F6: PBS/PLA capsule; F7: paper-based capsule; F8: coffee balls.</p></fn></table-wrap-foot>
</table-wrap>
<p>The secondary packaging differs depending on the format.</p>
<p>For F1 (250-g flexible multilayer bag), the secondary packaging is a carton (CA), sealed with a 7-g sticky tape strip and labeled with a 2-g paper tag. In contrast, for F2&#x2013;F8, the secondary packaging consists of the following two components:</p>
<p><list list-type="bullet">
<list-item><p>Item A is typically a self-sealing corrugated paperboard box (CB) designed to hold either 20 pods or 10 capsules.</p></list-item>
<list-item><p>Item B is a cardboard master box (MB) sealed with sticky tape and paper-labeled in the same manner as the F1 carton (CA).</p></list-item>
</list></p>
<p>Finally, the tertiary packaging consists of a 14-kg European Pallet Association (EPAL) wood pallet (1,200-mm length [L] &#x00D7; 800-mm width [W] &#x00D7; 144-mm height [H]), which is 99.8% reusable. This pallet is used to assemble multiple cartons or master boxes per layer. These layers are then secured with a stretched PE film and labeled with two paper tags, each weighing 3.11 g.</p>
<p>As an example, <xref ref-type="fig" rid="F6">Figure 6</xref> shows the block diagram of packaging processes for some of the coffee formats (F1&#x2013;F3) listed in <xref ref-type="table" rid="T5">Table 5</xref>. Specifically, the formats are F1 (RGC in poly-laminated bags, as shown in <xref ref-type="fig" rid="F6">Figure 6A</xref>), F2 (coffee pads, as shown in <xref ref-type="fig" rid="F6">Figure 6B</xref>), and F3 (coffee aluminum capsules; see <xref ref-type="fig" rid="F6">Figure 6C</xref>).</p>
<fig id="F6" orientation="portrait" position="float">
<label>Figure 6.</label>
<caption><p>Schematic diagrams of packaging processes for ground coffee in (A) 250-g multilayer bags (F1); (B) 44-mm ESE pads (F2); and (C) aluminum capsules (F3).</p></caption>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g006.tif"/>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g006a.tif"/>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g006b.tif"/>
</fig>
<p>The packaging process for coffee capsules (F3) differs from that of coffee pads (F2) primarily because of their primary packaging. For capsules, this primary packaging (denoted as &#x201C;A&#x201D; in the diagram) can be made from a variety of materials, including aluminum, PP, poly-laminated materials, PLA-based composites, or paper-based composites. Additionally, capsules require a nitrogen fill to enhance the freshness and extend the shelf-life of coffee serving.</p>
<p><xref ref-type="table" rid="T6">Table 6</xref> provides comprehensive details about the primary, secondary, and tertiary packages of various coffee formats, allowing for a clear illustration of the packaging material-to-ground coffee ratio (PM/RGC [kg/kg]) and, consequently, the waste implications associated with single-use coffee servings.</p>
<table-wrap id="T6" orientation="portrait" position="float">
<label>Table 6.</label><caption><p>Mass of any component of primary, secondary, and tertiary packages for roasted and ground coffee (RGC), as referred to the eight formats described in Table 5.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Packaging format</th>
<th align="center">F1</th>
<th align="center">F2</th>
<th align="center">F3</th>
<th align="center">F4</th>
<th align="center">F5</th>
<th align="center">F6</th>
<th align="center">F7</th>
<th align="center">F8</th>
<th align="center">Unit</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left"><italic>Primary packaging A</italic></td>
<td align="center"><italic>MLB</italic></td>
<td align="center"><italic>CPO</italic></td>
<td align="center"><italic>AlC</italic></td>
<td align="center"><italic>PPC</italic></td>
<td align="center"><italic>PAPC</italic></td>
<td align="center"><italic>CP</italic></td>
<td align="center"><italic>PC</italic></td>
<td align="center"><italic>CB</italic></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">RGC mass</td>
<td align="center">250</td>
<td align="center">7.23</td>
<td align="center">5.5</td>
<td align="center">5.5</td>
<td align="center">5.75</td>
<td align="center">5.5</td>
<td align="center">5.5</td>
<td align="center">5.6</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Vacuum pack mass</td>
<td align="center">7.86</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Upper lid</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">0.25</td>
<td align="center">0.25</td>
<td align="center">0.11</td>
<td align="center">0.3</td>
<td align="center">0.3</td>
<td align="center">&#x2013;</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Paper filter mass</td>
<td align="center">&#x2013;</td>
<td align="center">0.18</td>
<td align="center">0.28</td>
<td align="center">0.28</td>
<td align="center">&#x2013;</td>
<td align="center">0.3</td>
<td align="center">0.3</td>
<td align="center">&#x2013;</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Biopolymer film coating</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">0.3</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Nitrogen fill</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">0.43</td>
<td align="center">0.43</td>
<td align="center">0.43</td>
<td align="center">0.43</td>
<td align="center">0.43</td>
<td align="center">&#x2013;</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Capsule mass</td>
<td align="center">&#x2013;</td>
<td align="center"><italic>&#x2013;</italic></td>
<td align="center">1.00</td>
<td align="center">3.00</td>
<td align="center">1.05</td>
<td align="center">2.6</td>
<td align="center">2.6</td>
<td align="center"></td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Overall mass of primary package A</td>
<td align="center">257.86</td>
<td align="center">7.41</td>
<td align="center">7.46</td>
<td align="center">9.46</td>
<td align="center">7.34</td>
<td align="center">9.13</td>
<td align="center">9.13</td>
<td align="center">5.90</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left"><italic>Primary packaging B</italic></td>
<td align="center">&#x2013;</td>
<td align="center"><italic>Pouch</italic></td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center"><italic>&#x2013;</italic></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">Poly-laminated pouch mass</td>
<td align="center">&#x2013;</td>
<td align="center">1.51</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center"><italic>&#x2013;</italic></td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Overall mass of primary package B</td>
<td align="center">&#x2013;</td>
<td align="center">8.92</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center">&#x2013;</td>
<td align="center"><italic>&#x2013;</italic></td>
<td align="center">g</td>
</tr>
<tr>
<td align="left"><italic>Secondary packaging A</italic></td>
<td align="center">&#x2013;</td>
<td align="center"></td>
<td align="center"></td>
<td align="center"><italic>Sleeve pack</italic></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"><italic>Sleeve pack</italic></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">Dimensions</td>
<td align="center">&#x2013;</td>
<td align="center">L10&#x00D7;W10&#x00D7;H22</td>
<td align="center">L14&#x00D7;W7&#x00D7;H3</td>
<td align="center">L14 &#x00D7; W7 &#x00D7; H3</td>
<td align="center">L14&#x00D7;W10&#x00D7;H4</td>
<td align="center">cm</td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">No. of pods or capsules/box</td>
<td align="center">&#x2013;</td>
<td align="center">20</td>
<td align="center">10</td>
<td align="center">10</td>
<td align="center">10</td>
<td align="center">10</td>
<td align="center">10</td>
<td align="center">9</td>
<td align="center"><italic>-</italic></td>
</tr>
<tr>
<td align="left">Corrugated paperboard sleeve mass</td>
<td align="center">&#x2013;</td>
<td align="center">64.8</td>
<td align="center">12.59</td>
<td align="center">12.59</td>
<td align="center">12.59</td>
<td align="center">12.59</td>
<td align="center">12.59</td>
<td align="center">14.4</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Overall mass of secondary A package</td>
<td align="center">&#x2013;</td>
<td align="center">243.2</td>
<td align="center">87.2</td>
<td align="center">107.2</td>
<td align="center">86.0</td>
<td align="center">103.9</td>
<td align="center">103.9</td>
<td align="center">67.50</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left"><italic>Secondary packaging B</italic></td>
<td align="center"><italic>CA</italic></td>
<td align="center"><italic>MB</italic></td>
<td align="center"><italic>MB</italic></td>
<td align="center"><italic>MB</italic></td>
<td align="center"><italic>MB</italic></td>
<td align="center"><italic>MB</italic></td>
<td align="center"><italic>MB</italic></td>
<td align="center"><italic>MB</italic></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">Dimensions</td>
<td align="center">L40&#x00D7;W18&#x00D7;H15</td>
<td align="center">L80&#x00D7;W30&#x00D7;H45</td>
<td align="center">L40&#x00D7;W30&#x00D7;H45</td>
<td align="center">L40&#x00D7;W30&#x00D7;H45</td>
<td align="center">cm</td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">CA or MB mass</td>
<td align="center">318</td>
<td align="center">1,470</td>
<td align="center">870</td>
<td align="center">870</td>
<td align="center">870</td>
<td align="center">870</td>
<td align="center">870</td>
<td align="center">640</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">No. of pouches per CA/sleeves per MB</td>
<td align="center">20</td>
<td align="center">48</td>
<td align="center">156</td>
<td align="center">156</td>
<td align="center">156</td>
<td align="center">156</td>
<td align="center">156</td>
<td align="center">120</td>
<td align="center">-</td>
</tr>
<tr>
<td align="left">Sticky tape mass</td>
<td align="center">7</td>
<td align="center">7</td>
<td align="center">7</td>
<td align="center">7</td>
<td align="center">7</td>
<td align="center">7</td>
<td align="center">7</td>
<td align="center">7</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Paper label mass</td>
<td align="center">2</td>
<td align="center">2</td>
<td align="center">2</td>
<td align="center">2</td>
<td align="center">2</td>
<td align="center">2</td>
<td align="center">2</td>
<td align="center">2</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Overall mass of secondary packages</td>
<td align="center">5.475</td>
<td align="center">13.144</td>
<td align="center">14.472</td>
<td align="center">17.592</td>
<td align="center">14.284</td>
<td align="center">17.077</td>
<td align="center">17.077</td>
<td align="center">8.740</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left"><italic>Tertiary packaging</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"><italic>EWP</italic></td>
<td align="center"></td>
</tr>
<tr>
<td align="left">No. of CA or MBs per layer</td>
<td align="center">12</td>
<td align="center">4</td>
<td align="center">8</td>
<td align="center">8</td>
<td align="center">8</td>
<td align="center">8</td>
<td align="center">8</td>
<td align="center">8</td>
<td align="center">-</td>
</tr>
<tr>
<td align="left">No. of layers per pallet</td>
<td align="center">12</td>
<td align="center">4</td>
<td align="center">4</td>
<td align="center">4</td>
<td align="center">4</td>
<td align="center">4</td>
<td align="center">4</td>
<td align="center">4</td>
<td align="center">-</td>
</tr>
<tr>
<td align="left">PE film mass</td>
<td align="center">0.821</td>
<td align="center">0.912</td>
<td align="center">0.912</td>
<td align="center">0.912</td>
<td align="center">0.912</td>
<td align="center">0.912</td>
<td align="center">0.912</td>
<td align="center">0.912</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Pallet paper labels</td>
<td align="center">3.11</td>
<td align="center">3.11</td>
<td align="center">3.11</td>
<td align="center">3.11</td>
<td align="center">3.11</td>
<td align="center">3.11</td>
<td align="center">3.11</td>
<td align="center">3.11</td>
<td align="center">g</td>
</tr>
<tr>
<td align="left">Overall RGC mass</td>
<td align="center">720.0</td>
<td align="center">111.1</td>
<td align="center">274.6</td>
<td align="center">274.6</td>
<td align="center">287.0</td>
<td align="center">274.6</td>
<td align="center">274.6</td>
<td align="center">193.5</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Overall mass of tertiary package</td>
<td align="center">803.3</td>
<td align="center">225.2</td>
<td align="center">478.0</td>
<td align="center">577.9</td>
<td align="center">472.0</td>
<td align="center">561.4</td>
<td align="center">561.4</td>
<td align="center">294.6</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Packaging-to-RGC mass ratio</td>
<td align="center">0.116</td>
<td align="center">1.028</td>
<td align="center">0.741</td>
<td align="center">1.105</td>
<td align="center">0.644</td>
<td align="center">1.045</td>
<td align="center">1.045</td>
<td align="center">0.522</td>
<td align="center">kg kg<sup>-1</sup></td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF6-1"><p>Notes: AlC: AI capsule; CB: coffee balls; CP: PBS/PLA capsules; CPO: coffee pad; EWP: European Pallet Association (EPAL) wooden pallet; MB: cardboard master box; MLB: multi-layer bag; PAPC: PE-Al-PET capsule; PC: paper-based capsule; PPC: PP capsule.</p></fn></table-wrap-foot>
</table-wrap>
<p>While single-serve options, such as coffee balls and diverse capsules, offer convenience, they inherently utilize more packaging material relative to the coffee contained. For example, the coffee ball format (F8), designed for nine spherical coffee portions (<xref ref-type="fig" rid="F5">Figure 5H</xref>), has a packaging-to-RGC mass ratio (PM/RGC) of 0.522 kg of packaging/kg of RGC. The biopolymer film coating applied directly to coffee balls represents quite a lightweight primary packaging. This ratio means that for every kilogram of coffee, more than half a kilogram of packaging material is used.</p>
<p>Comparing this to other single-serve formats shown in <xref ref-type="table" rid="T6">Table 6</xref>, coffee pods (F2) show a significantly higher ratio of 1.028 kg/kg of RGC, indicating they use more than 1 kg of packaging for every kilogram of coffee. Diverse capsules (F3&#x2013;F7), each weighing from 1 g to 3 g, exhibit varied features. Their PM/RGC ratios range from 1.105 kg/kg in the case of PP capsules (F4) to 0.741 kg/kg in the case of Al Nespresso<sup>&#x00AE;</sup> Espresso capsules (F3), and down to 0.644 kg/kg in the case of poly-laminated capsules (F5). Among all these single-serve options, coffee balls (F8) at 0.522 kg/kg demonstrate the lowest PM/RGC mass ratio, indicating that they are the most material-efficient single-serve format presented in <xref ref-type="table" rid="T6">Table 6</xref>.</p>
<p>In stark contrast, a 250-g poly-laminated bag of ground coffee, a common format for use with Moka pots, espresso machines, and other traditional brewing systems, boasts a significantly lower PM/RGC ratio of approximately 0.12 kg/kg. This highlights a substantial difference in material efficiency: traditional bulk packaging requires nearly five times less packaging material per unit of coffee, compared to the coffee ball format which is significantly more efficient than all single-serve options.</p>
<p>This comparison underscores a fundamental trade-off: the convenience and portion control offered by single-serve coffee systems typically come at the cost of increased packaging material per serving. While innovations in materials and design, such as the molded cardboard for coffee balls, aim to minimize this footprint, they still face the challenge of providing individual protection and containment for small quantities of coffee, which inherently leads to a higher packaging-to-product ratio than larger, multi-serve formats. Consequently, the coffee ball format&#x2019;s lower PM/RGC ratio among single-serve options suggests a potentially more environment-friendly profile in terms of material consumption for this category. However, it is important to note that this analysis solely considers mass and does not encompass other environmental impacts, such as recyclability, end-of-life options, or energy consumption during coffee preparation.</p>
</sec>
<sec id="S2_10">
<title>Environmental impact of coffee&#x2019;s consumer use phase</title>
<p>The environmental impact of coffee&#x2019;s use phase primarily stems from the energy needed for brewing and washing reusable cups. In contrast, RGC itself typically has a minimal impact during storage, as it is kept at room temperature in airtight, vacuum-sealed, or inert gas-filled containers.</p>
<p>A key factor in this phase&#x2019;s PEF is the choice of coffee vessel: single-use or reusable.</p>
<p>Common reusable options include cups made from glass, porcelain, or earthenware. Mugs are another popular choice, usually larger, cylindrical containers with a handle, often made of ceramic or stoneware. For on-the-go coffee, travel mugs are used widely. These are generally reusable and come with a lid, as do insulated or thermal mugs, which are specifically designed to keep drinks hot or cold. Lids on these mugs often feature a drinking spout or a sip opening, while iced beverages commonly use lids with a straw aperture. Reusable cups and mugs typically have a lifespan of around 500 use cycles (<xref ref-type="bibr" rid="ref14">Chayer and Kicak, 2015</xref>).</p>
<p>For disposable options, paper or plastic cups are very common. While Styrofoam cups are also disposable, their use has declined due to environmental concerns (<xref ref-type="bibr" rid="ref61">Mindful Sip, 2024</xref>). A disposable cup might also include a cardboard sleeve to protect hands from heat. To help mix ingredients, such as sugar or milk powder, single-use cups often include a spoon or a stirring stick.</p>
<p>Brewing a cup of coffee, using the systems described in Section 2.5, primarily consumes electricity or natural gas from the national grid.</p>
<p>Washing reusable cups can be performed either manually (handwashing) or with a dishwasher. Handwashing typically uses about 0.5 L of 40 &#x00B0;C water per cup. Dishwashers, on the other hand, uses anywhere from 9.5 L (<xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>) to 18 L (<xref ref-type="bibr" rid="ref44">Humbert <italic>et al</italic>., 2009</xref>) of water per cycle. A dishwasher generally consumes 10 g of detergent per cycle, regardless of its loading capacity. This capacity can range from 40 ceramic mugs (300 g each; <xref ref-type="bibr" rid="ref44">Humbert <italic>et al</italic>., 2009</xref>) to 56 earthenware cups (120 g each; <xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>). Dishwasher&#x2019;s energy consumption also varies significantly, ranging from 1.05 kWh to 1.4 kWh per cycle. However, this can be as low as 0.8 kWh per cycle for an Energy Class A<sup>+++</sup> dishwasher running an &#x201C;express wash&#x201D; function, which cuts the running time by 50% (<xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>). These figures clearly show how the energy consumption for washing cups and mugs can differ greatly based on the dishwasher type and its settings, offering a range of possibilities for evaluating the overall energy efficiency and environmental impact.</p>
<p>While the energy used for brewing and washing reusable cups are key environmental factors in the coffee use phase, a comprehensive LCA of reusable coffee cups, as detailed by <xref ref-type="bibr" rid="ref4">Almeida <italic>et al</italic>. (2018)</xref>, provided deeper insight into their cradle-to-grave environmental impact when benchmarked against single-use and other reusable alternatives.</p>
<p>KeepCups, for example, are reusable coffee cups designed to replace single-use disposables. Created in Australia in 2007 by siblings Abigail and Jamie Forsyth, they aimed to reduce the environmental impact of single-use coffee cups, which often end up in landfills because of their mixed material construction (paper and plastic lining) making recycling difficult (<ext-link ext-link-type="uri" xlink:href="https://www.madesustained.nl/project/keepcup/">https://www.madesustained.nl/project/keepcup/</ext-link>; accessed: 5 June 2025). These cups were designed to encourage a shift in consumer behavior toward habitually reusing their own cups for takeaway beverages, having been tested for hundreds or even thousands of use cycles. They are made from various materials, including PP, tempered glass, and stainless steel, available in standard disposable cup sizes (e.g., 8, 12, and 16 oz), and feature interchangeable parts (such as a lid or band), allowing users to replace a single damaged component, rather than discarding the entire cup. They are also easily washed in dishwashers.</p>
<p><xref ref-type="bibr" rid="ref4">Almeida <italic>et al</italic>. (2018)</xref> highlighted several environmental benefits of such reusable cups:</p>
<p><list list-type="bullet">
<list-item><p>Reduced carbon footprint achievable after a relatively small number of uses (e.g., eight uses for a Thermal KeepCup vs. a paper cup, or four uses vs. a compostable cup). Over a year of light use (250 coffees/year), a thermal KeepCup can reduce its carbon footprint by 77&#x2013;87%, compared to disposables.</p></list-item>
<list-item><p>Reduced waste to landfill because these cups replace disposable cups.</p></list-item>
<list-item><p>Lower energy and water use (over its lifespan), this benefit being particularly pronounced with energy-efficient washing practices. The choice of electricity source for washing (grid vs. renewables) significantly influences these impacts.</p></list-item>
</list></p>
<p>In essence, the study conducted by <xref ref-type="bibr" rid="ref4">Almeida <italic>et al</italic>. (2018)</xref> reinforced that reusable cups, such as KeepCups, generally offer a more environment-friendly option than single-use alternatives. However, it also underscored that the use phase, particularly the washing process, remains the most significant environmental hotspot. This emphasizes the fundamental importance of influencing user behavior through education on energy-efficient washing practices, such as ensuring dishwashers are fully loaded.</p>
</sec>
<sec id="S2_11">
<title>Environmental impact of coffee waste disposal</title>
<p>The disposal phase of coffee consumption significantly contributes to its overall PEF, involving waste streams generated throughout green coffee processing, packaging, and post-consumer stages. Both upstream industrial processes and downstream consumer behaviors influence the fate of organic and packaging waste.</p>
<p>Waste management practices vary across countries. In Italy, for example, post-consumer organic and packaging wastes are managed according to national municipal solid waste (MSW) guidelines (<xref ref-type="bibr" rid="ref9">Aterini, 2025</xref>; <xref ref-type="bibr" rid="ref32">Evangelista <italic>et al</italic>., 2023</xref>; Italian Institute for Environmental Protection and Research [ISPRA], 2024; <xref ref-type="bibr" rid="ref68">Pavan, 2024</xref>; <xref ref-type="bibr" rid="ref70">Pergolizzi, 2024</xref>). <xref ref-type="table" rid="T7">Table 7</xref> summarizes the Italian waste management scenarios for 2022.</p>
<table-wrap id="T7" orientation="portrait" position="float">
<label>Table 7.</label><caption><p>The overall Italian waste management scenarios for packaging and organic and undifferentiated wastes in 2022.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Waste management scenarios</th> 
<th align="center">Landfill (%)</th>
<th align="center">Recycling (%)</th>
<th align="center">Incineration (%)</th>
<th align="left">References</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Organic waste</td>
<td align="center">21.9</td>
<td align="center">49.2</td>
<td align="center">28.9</td>
<td align="left"><xref ref-type="bibr" rid="ref9">Aterini, 2025</xref>; ISPRA, 2024</td>
</tr>
<tr>
<td align="left">Paper and cardboard waste</td>
<td align="center">13.0</td>
<td align="center">81.2</td>
<td align="center">5.8</td>
<td align="left"><xref ref-type="bibr" rid="ref32">Evangelista <italic>et al</italic>., 2023</xref></td>
</tr>
<tr>
<td align="left">Wood waste</td>
<td align="center">35.6</td>
<td align="center">62.7</td>
<td align="center">1.7</td>
<td align="left"><xref ref-type="bibr" rid="ref32">Evangelista <italic>et al</italic>., 2023</xref></td>
</tr>
<tr>
<td align="left">Plastic waste</td>
<td align="center">10.6</td>
<td align="center">48.9</td>
<td align="center">40.5</td>
<td align="left"><xref ref-type="bibr" rid="ref32">Evangelista <italic>et al</italic>., 2023</xref></td>
</tr>
<tr>
<td align="left">Glass waste</td>
<td align="center">19.2</td>
<td align="center">80.8</td>
<td align="center">0.0</td>
<td align="left"><xref ref-type="bibr" rid="ref32">Evangelista <italic>et al</italic>., 2023</xref></td>
</tr>
<tr>
<td align="left">Aluminum waste</td>
<td align="center">22.2</td>
<td align="center">73.6</td>
<td align="center">4.2</td>
<td align="left"><xref ref-type="bibr" rid="ref32">Evangelista <italic>et al</italic>., 2023</xref></td>
</tr>
<tr>
<td align="left">Iron waste</td>
<td align="center">19.4</td>
<td align="center">80.6</td>
<td align="center">0.0</td>
<td align="left"><xref ref-type="bibr" rid="ref32">Evangelista <italic>et al</italic>., 2023</xref></td>
</tr>
<tr>
<td align="left">Undifferentiated waste</td>
<td align="center">49.4</td>
<td align="center">-</td>
<td align="center">50.6</td>
<td align="left"><xref ref-type="bibr" rid="ref68">Pavan, 2024</xref></td>
</tr>
</tbody>
</table></table-wrap>
<p>These data highlight high recycling proportions for paper and cardboard (81.2%), aluminum (73.6%), and wood (62.7%) as well as moderate recycling for plastics (48.9%). In 2022, 49.2% of organic waste was recycled (ISPRA, 2024), with 44% processed into compost and 5.2% treated through anaerobic digestion (<xref ref-type="bibr" rid="ref70">Pergolizzi, 2024</xref>); 21.9% was landfilled (<xref ref-type="bibr" rid="ref9">Aterini, 2025</xref>), and the remaining 28.9% was incinerated with energy recovery.</p>
<p>At the industrial scale, green coffee processing and packaging generate multiple waste streams, each managed differently:</p>
<p><list list-type="bullet">
<list-item><p><italic>Organic waste</italic>: Roasted ground coffee from broken bags, pods, or capsules.</p></list-item>
<list-item><p><italic>Plastic waste</italic>: PE supersacks, multilayer bags or pouches for coffee pods, and stretch films.</p></list-item>
<list-item><p><italic>Paper and cardboard waste</italic>: Rejected cartons, corrugated paperboard boxes, master boxes, and labels.</p></list-item>
<list-item><p><italic>Wood waste</italic>: Wooden pallets managed through repair and reuse or disposed as wood waste.</p></list-item>
</list></p>
<p><xref ref-type="table" rid="T8">Table 8</xref> summarizes the percentage of packaging materials discarded during green coffee transportation (TR) and packaging at the industrial scale as reported by <xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>. (2021)</xref>.</p>
<table-wrap id="T8" orientation="portrait" position="float">
<label>Table 8.</label><caption><p>Percentage of packaging materials discarded during the processing of green coffee beans (GCBs) and roasted and ground coffee (RGC) at an industrial scale as reported by Cibelli <italic>et al.</italic> (2021).</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Processing and packaging materials discarded</th>
<th align="center">Discarded fraction (%)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left" colspan="2"><italic>Primary packaging of GCBs</italic></td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;PE supersacks</td>
<td align="center">5.0</td>
</tr>
<tr>
<td align="left" colspan="2"><italic>Primary packaging of RGC</italic></td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Ground coffee waste</td>
<td align="center">0.3</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Poly-laminated bag waste</td>
<td align="center">1.5</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;PE foil per multilayer bags</td>
<td align="center">0.3</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Pad paper filter waste</td>
<td align="center">30.0</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Poly-laminated pouch waste</td>
<td align="center">0.64</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Capsule and paper- or PLA-based filter waste</td>
<td align="center">1.0</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Capsule lid waste</td>
<td align="center">1.0</td>
</tr>
<tr>
<td align="left" colspan="2"><italic>Secondary packaging of RGC</italic></td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Cardboard carton, box, or master box waste</td>
<td align="center">0.4</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Sticky tape waste</td>
<td align="center">0.2</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Paper label waste</td>
<td align="center">0.2</td>
</tr>
<tr>
<td align="left" colspan="2"><italic>Tertiary packaging of RGC</italic></td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;EPAL pallet waste</td>
<td align="center">0.2</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Stretch and shrink PE film waste</td>
<td align="center">0.2</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;Pallet adhesive label waste</td>
<td align="center">0.2</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF8-1"><p>Note: EPAL: European Pallet Association; PE: polyethylene.</p></fn></table-wrap-foot>
</table-wrap>
<p>Globally, waste treatment practices for coffee packaging and SCGs differ significantly. In Switzerland, aluminum, plastic, and bioplastic capsules along with SCGs are often incinerated without separation (<xref ref-type="bibr" rid="ref22">Dubois <italic>et al</italic>., 2011</xref>). In contrast, in the United States, most SCGs are landfilled or incinerated, with only 3.9% composted (<xref ref-type="bibr" rid="ref72">Quantis, 2015</xref>), contributing to substantial GHG emissions, particularly methane and CO<sub>2</sub>.</p>
<p>While numerous LCA studies consistently identify coffee production (cultivation, harvesting, and processing) as the principal contributor to coffee&#x2019;s environmental impact (<xref ref-type="bibr" rid="ref80">Sarmento dos Muchangos <italic>et al</italic>., 2025</xref>), waste management remains a relevant factor, especially for single-serve systems utilizing non-recyclable packaging.</p>
<p>The LCA conducted by <xref ref-type="bibr" rid="ref22">Dubois <italic>et al</italic>. (2011)</xref> for Nespresso<sup>&#x00AE;</sup> examined espresso prepared with various capsule types (Nespresso<sup>&#x00AE;</sup> Espresso Al, PP-Al-PE, PP-PET, and polylactate-starch). The main contributors to GHG emissions were in the following descending order: preparation stage, coffee production, packaging production, and disposal. Aluminum capsules showed the lowest GHG emissions, while bioplastic capsules disposed of in landfills resulted in the highest GHG emissions because of methane release.</p>
<p>More recent evaluations done by <xref ref-type="bibr" rid="ref73">Quantis (2024)</xref>, using aluminum capsules as the baseline (100%), revealed distinct Global Warming Potential (GWP) profiles for different European brewing systems:</p>
<p><list list-type="bullet">
<list-item><p>Paper-based Nespresso<sup>&#x00AE;</sup> capsules exhibited the lowest GWP, at ~90% of the aluminum capsule&#x2019;s impact.</p></list-item>
<list-item><p>Compostable coffee balls followed at ~105%.</p></list-item>
<list-item><p>Unportioned systems showed consistently higher GWP values: full automat (~120%), drip filter (~130%), and Moka (~135%), primarily because of higher coffee quantities per serving.</p></list-item>
</list></p>
<p>The earlier study conducted by <xref ref-type="bibr" rid="ref72">Quantis (2015)</xref> emphasized that consumer behaviors, such as over-preparation, freshness loss, and prolonged warming, further elevate the GHG impacts of unportioned systems. Even minimal over-preparation (2%) or freshness loss (3%) can make drip brewing more impactful than optimized capsule systems.</p>
<p>Beyond GWP, <xref ref-type="bibr" rid="ref73">Quantis (2024)</xref> assessed 16 environmental impact categories, finding that paper-based capsules generally outperformed aluminum across most indicators. However, regardless of the brewing system, coffee production consistently remained a dominant contributor to environmental impacts, with capsule manufacturing representing a secondary yet significant factor for portioned systems.</p>
<p>In summary, the environmental impact of disposal of coffee waste is strongly influenced by the following:</p>
<p><list list-type="bullet">
<list-item><p>The brewing system employed (portioned vs. unportioned)</p></list-item>
<list-item><p>The waste management infrastructure at national and municipal levels</p></list-item>
<list-item><p>Consumer behaviors affecting brewing efficiency and waste generation</p></list-item>
<list-item><p>The development and implementation of circular economy solutions for both packaging and SCGs.</p></list-item>
</list></p>
<p>Thus, reducing coffee&#x2019;s environmental burden requires a dual strategy:</p>
<p><list list-type="order">
<list-item><p>Optimizing brewing systems for portion control, efficiency, and reduced coffee waste.</p></list-item>
<list-item><p>Establishing robust circular management pathways for both packaging materials and SCGs.</p></list-item>
</list></p>
</sec>
<sec id="S2_12">
<title>Valorization of spent coffee grounds in circular bioeconomy</title>
<p>The food industry&#x2019;s growing interest in circular economy models to enhance product and service sustainability has intensified focus on recycling waste and residues. In this context, coffee processing by-products, which vary based on processing methods (wet, dry, roasting, and infusion), include coffee pulp, husks, silver husks, and notably SCGs. SCG constitutes the most abundant waste, accounting for 45% of residues from coffee beverage preparation (<xref ref-type="bibr" rid="ref62">Murthy and Naidu, 2012</xref>). Approximately 2 kg of wet SCGs are generated per kilogram of instant coffee, while 0.65 kg of SCGs result from 1 kg of green coffee (<xref ref-type="bibr" rid="ref51">Janissen and Huynh, 2018</xref>). This significant interest in coffee waste stems from coffee&#x2019;s global popularity as the second most traded product, cultivated in roughly 80 countries (<xref ref-type="bibr" rid="ref62">Murthy and Naidu, 2012</xref>).</p>
<p><xref ref-type="bibr" rid="ref34">Forcina <italic>et al</italic>. (2023)</xref> conducted a comparative LCA of various SCG reuse strategies, highlighting their environmental implications and associated recovery challenges. With an estimated 60 million MT of SCGs generated annually worldwide, its effective management and valorization through circular economy strategies are urgently needed. SCG is a versatile resource because of its rich composition of polysaccharides, lipids, proteins, and bioactive compounds, such as polyphenols and caffeine.</p>
<p>Potential valorization avenues for SCG, as explored in literature, include the following (<xref ref-type="bibr" rid="ref7">Arias <italic>et al</italic>., 2023</xref>; <xref ref-type="bibr" rid="ref34">Forcina <italic>et al</italic>., 2023</xref>; <xref ref-type="bibr" rid="ref39">Hejna, 2021</xref>):</p>
<p><list list-type="bullet">
<list-item><p><italic>Compost and fertilizers</italic>: SCG is rich in nitrogen and other nutrients, making it an excellent soil amendment to enhance fertility and promote plant growth. It can also be used as a substrate for mushroom cultivation.</p></list-item>
<list-item><p><italic>Biofuels and bioenergy</italic>: SCG can be converted into biodiesel, bioethanol, biogas, or bio-pellets, serving as a source of renewable energy to reduce dependence on fossil fuels.</p></list-item>
<list-item><p><italic>Building materials</italic>: SCG can be incorporated into construction materials, such as bricks, to enhance their sustainability and efficiency.</p></list-item>
<list-item><p><italic>Polymer applications</italic>: Coffee by-products, including SCG, offer significant potential in polymer chemistry and technology. They are used as fillers in polymer composites to enhance mechanical properties (e.g., stiffness and tensile strength), reduce material costs, and improve biodegradability. Furthermore, they can serve as a source for bio-based monomers/plasticizers (e.g., from SCG lipids) and as functional additives imparting properties such as protection from ultraviolet (UV) radiation.</p></list-item>
<list-item><p><italic>Food industry</italic>: SCG can be transformed into flour rich in dietary fiber and antioxidants, suitable for baking and other culinary applications.</p></list-item>
<list-item><p><italic>Cosmetics and skincare</italic>: The bioactive compounds and abrasive texture of SCG make it suitable for use in exfoliants, scrubs, and other skincare products.</p></list-item>
<list-item><p><italic>Adsorbents</italic>: SCG is used to remove heavy metals or other pollutants from water.</p></list-item>
<list-item><p><italic>Biochar production</italic>: Pyrolysis/gasification of SCG can produce bio-oil, syngas, and biochar, the latter improving soil quality, carbon sequestration, and water retention.</p></list-item>
</list></p>
<p>The environmental performance of SCG reuse strategies is a critical assessment component. Traditional disposal via landfilling is highly problematic, because SCG anaerobic decomposition leads to significant emissions of potent GHGs, such as CH<sub>4</sub> and CO<sub>2</sub>. Furthermore, harmful chemical substances such as caffeine, tannins, and polyphenols can leach into the environment, potentially impacting soil fertility and groundwater. Conversely, valorization strategies aim to mitigate these negative impacts. For example, biofuel production from SCG can reduce dependence on fossil fuels, thereby lowering associated GHG emissions, and composting SCG can enrich soil and reduce the need for synthetic fertilizers.</p>
<p>According to the LCA study done by <xref ref-type="bibr" rid="ref34">Forcina <italic>et al</italic>. (2023)</xref>, SCG landfilling exhibited the highest environmental burden across all categories, with a GWP of 0.15 kg CO<sub>2e</sub>/MT of SCG. Composting resulted in an approximate 84% reduction in GWP compared to landfilling (0.023 kg CO<sub>2e</sub>/MT), and an 18% decrease in emissions into air. Production of biodiesel yielded negative values across all categories. Notably, its GWP was -0.35 kg CO<sub>2e</sub>/MT, meaning it actively reduced the overall carbon footprint by displacing fossil fuels, although it yielded only 1% decrease in direct process emissions into air compared to landfill. Finally, partial incorporation of SCG in bricks appeared to be highly effective for reducing atmospheric pollutants, thanks to a remarkable 76% decrease in emissions into air compared to landfilling.</p>
<p><xref ref-type="bibr" rid="ref34">Forcina <italic>et al</italic>. (2023)</xref> unequivocally demonstrates that all valorization strategies for SCGs (composting, biodiesel production, and incorporation into bricks) offer substantial environmental advantages over traditional landfilling. Nevertheless, the success of these waste management alternatives is significantly influenced by transportation distance. Assuming a 100-km transportation distance for landfill disposal, <xref ref-type="bibr" rid="ref34">Forcina <italic>et al</italic>. (2023)</xref> estimated break-even distances, beyond which transport impacts negate environmental benefits: 150 km for biodiesel production, 500 km for composting, and 1,800 km for brick-production. Compared to average distances in the Italian scenario, composting (average 40 km) and brick production (average 460 km) proved environmentally beneficial, their real distance being less than their break-even points. On the contrary, biodiesel production in Italy would not explicit its environmental benefits because it is carried out in plants collecting raw materials from about 500-km distance, considerably higher than its 150-km break-even distance.</p>
<p>Despite the promising potential of SCG valorization, the practicalities of collecting and processing this waste present significant hurdles, particularly when considering sources beyond large-scale industrial operations:</p>
<p><list list-type="bullet">
<list-item><p><italic>Recovery from house bins</italic>: Collecting SCG from individual household bins is exceptionally difficult and inefficient. The small quantities generated per household, coupled with contamination from other waste streams, make large-scale collection impractical and economically unfeasible without dedicated and widespread separate collection systems. The moisture content in fresh SCG also adds to collection and storage challenges, as leads to growth of mold.</p></list-item>
<list-item><p><italic>Exhausted coffee capsules or pods</italic>: Coffee capsules and pods, while convenient for consumers, pose a distinct challenge. They are often made of mixed materials (plastic, aluminum, and foil) and still contain residual ground coffee. Separating SCGs from capsule material is a complex manual process, making SCGs difficult to recycle through standard municipal recycling streams. Specialized collection schemes, often managed by manufacturers, are required, but their effectiveness relies heavily on consumer participation, which is often low because of the added hassle. The very nature of convenience that drives their popularity works against effective post-consumer recovery.</p></list-item>
<list-item><p><italic>Collecting sufficient quantities for industrial-scale application</italic>: The fragmented and dispersed nature of SCG generation, especially from domestic and small commercial sources (e.g., cafes), makes it challenging to aggregate enough to feed industrial-scale valorization facilities. Industrial applications require a consistent and substantial feedstock supply to be economically viable. While large coffee-processing plants or instant coffee manufacturers generate significant volumes, establishing robust collection networks that can gather SCG from myriad smaller producers (households, offices, and small cafes) without incurring prohibitive logistical and economic costs remains a major barrier. The need for efficient collection and separation systems is paramount to unlock the full potential of SCG as a valuable resource.</p></list-item>
</list></p>
<p>While all reuse scenarios offer environmental benefits over landfilling, especially in terms of reducing the overall emissions, the practical applicability and true environmental advantage elicits a strategic, localized approach. This involves prioritizing collection and processing methods that minimize transport distances, alongside continued research and development into diverse valorization pathways to match regional needs and infrastructure. Investing in robust, localized collection systems, especially for decentralized sources such as households and cafes, is crucial to unlock fully the potential of SCG within a truly sustainable circular bioeconomy.</p>
</sec>
</sec>
<sec id="S3">
<title>Methodology</title>
<p>This work was based on the LCA procedure (International Organization for Standardization [ISO] 14040, 2006a, 14044, and 2006b).</p>
<sec id="S3_1">
<title>Goal and scope definition</title>
<p>The purpose of this study was to assess the environmental impact of a 40-mL cup of Moka or espresso coffee with no additional ingredients (e.g., sugar and milk) according to the guidelines of the Italian Coffee Committee (<xref ref-type="bibr" rid="ref18">Comitato Italiano del Caff&#x00E8;, 2018</xref>, 2020). Coffee brewing was carried out using the below-mentioned systems and the specific coffee formats (F1&#x2013;F8) outlined in <xref ref-type="table" rid="T6">Table 6</xref>:</p>
<p><list list-type="order">
<list-item><p>A three-cup Moka pot (cod. Linea-Moka-Induction-Oro: Bialetti Industrie SpA, Coccaglio, BS, Italy), heated by an induction stove.</p></list-item>
<list-item><p>An espresso coffee machine Gaggia Viva RI8433/11 (Gaggia SpA, Gaggio Montano, BO, Italy) having a nominal power of 1,025 W.</p></list-item>
<list-item><p>A pod coffee machine Did&#x00EC; Borbone Blue Pods (Didiesse Srl, Caivano, NA, Italy) having a nominal power of 450 W.</p></list-item>
<list-item><p>A capsule coffee machine Nespresso D40 Inissia Black (D&#x0113;Longhi Appliances Srl, Treviso, Italy) having a nominal power of 1,260 W.</p></list-item>
<list-item><p>A CoffeeB Horizon machine (<ext-link ext-link-type="uri" xlink:href="https://www.coffeeb.com/media/d8/32/18/1731324632/2024-10-17%20CoffeeB_Horizon_Manual_EN.pd">https://www.coffeeb.com/media/d8/32/18/1731324632/2024-10-17%20CoffeeB_Horizon_Manual_EN.pd</ext-link>; accessed: 15 June 2025) having a nominal power of 1,450 W.</p></list-item>
</list></p>
<p>Roasted and ground coffee, specifically in laminated bag packaging (F1), was utilized for brewing with (a) Moka pot, (b) espresso coffee machine, and (c) reusable stainless steel coffee capsules developed by CAPSME (<xref ref-type="fig" rid="F5">Figure 5G</xref>).</p>
<p>To assess the required number of individual coffee format units, their associated packaging and the total output of 40-mL Moka or espresso cups, a functional unit of 720-kg RGC was selected. This amount corresponds to the RGC packed in 250-g flexible multi-laminated bags, assembled on a single EPAL wood pallet (<xref ref-type="table" rid="T6">Table 6</xref>).</p>
<p>Owing to the varying environmental impacts of green coffee bean production&#x2014;depending on coffee variety, production location, agricultural practices, and processing of harvested coffee cherries (Section 2.2) as well as transportation and processing at the roaster plant&#x2014;the system boundary for this streamlined LCA study referred to a generic roasted coffee bean mix. It included the following processing steps, as illustrated in <xref ref-type="fig" rid="F7">Figure 7</xref>:</p>
<fig id="F7" orientation="portrait" position="float">
<label>Figure 7.</label>
<caption><p>System boundary of an LCA study carried out to assess the environmental impact of a 40-mL cup of Moka or espresso coffee using different brewing systems.</p></caption>
<graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="IJFS-37-436-g007.tif"/>
</fig>
<p><list list-type="order">
<list-item><p>Production of primary, secondary, and tertiary packaging materials.</p></list-item>
<list-item><p>Packaging ground coffee in different formats as described in <xref ref-type="table" rid="T6">Table 6</xref>.</p></list-item>
<list-item><p>Transport of the palletized product to the platforms of distribution centers (DCs) and then to the points of sale (PoS).</p></list-item>
<list-item><p>Consumer use of RGC using the above-mentioned brewing systems, powered by electricity drawn from the Italian low-voltage grid.</p></list-item>
<list-item><p>Transport of post-consumer wastes from consumers&#x2019; houses (CHs) to waste collection centers (WCCs).</p></list-item>
<list-item><p>End-of-life processes of SCGs.</p></list-item>
<list-item><p>End-of-life processes of packaging waste.</p></list-item>
</list></p>
<sec id="S3_1_1">
<title><italic>Exclusions from system boundaries</italic></title>
<p>Several elements from the system boundaries of this study were excluded:</p>
<p><list list-type="bullet">
<list-item><p>Production, cleaning, and disposal of capital goods (e.g., machinery and coffee machines), as detailed in Section 6.4.4 of the British Standards Institution (BSI, 2011).</p></list-item>
<list-item><p>Travel by personnel.</p></list-item>
<list-item><p>Transportation of consumers to and from PoS, as detailed in Section 6.5 of BSI (2011).</p></list-item>
</list></p>
</sec>
<sec id="S3_1_2">
<title><italic>Geographical, temporal, and technological boundaries</italic></title>
<p>Following the Publicly Available Specification (PAS) 2050, Section 7.2 of BSI (2011), the datasets reflected typical process configurations and the current technical and environmental standards of industrial-scale coffee roasters.</p>
</sec>
<sec id="S3_1_3">
<title><italic>Data used</italic></title>
<p>For primary data, information on by-product formation (specifically SCGs and packaging waste) was sourced from <xref ref-type="table" rid="T2">Tables 2</xref> and <xref ref-type="table" rid="T6">6</xref>.</p>
<p>Secondary data were obtained from the Ecoinvent v. 3.10 database, integrated into the LCA software SimaPro Craft 10.2.0.2 (Pr&#x00E9; Consultants, Amersfoort, NL).</p>
<p>In essence, this streamlined LCA aimed to evaluate the impact of various coffee brewing methods, independent of the origin of green coffee beans and its subsequent processing into RGC.</p>
</sec>
</sec>
<sec id="S3_2">
<title>Life cycle inventory analysis</title>
<sec id="S3_2_1">
<title><italic>Coffee packaging</italic></title>
<p>Roasted and ground coffee is packed into various formats (F1&#x2013;F8), as detailed in <xref ref-type="table" rid="T5">Table 5</xref>. This packaging process consumes approximately 0.00366 kWh of electricity per kg of ground coffee (<xref ref-type="bibr" rid="ref71">Phrommarat, 2019</xref>). All electricity for this operation is sourced from the Italian medium-voltage network.</p>
<p>The manufacturing of packaging material involves distinct processes for each type. Flexible laminated bags are produced by bonding plastic, foil, and another plastic layer together using extrusion coating/lamination, where molten polymer acts as an adhesive. After printing and slitting, this composite material undergoes bag-forming (heat sealing the edges), filling with coffee, and finally sealing and cutting.</p>
<p>For aluminum coffee capsules, the cup shape is achieved by pressing aluminum slugs or discs into a die with a punch; these are then trimmed and often lacquered. Multi-layer composite capsules (plastic/aluminum) have their bodies created through injection molding. PLA-based capsules are often co-extruded/laminated with other biopolymers to enhance barrier properties and are formed by injection molding. Paper-based capsules are made by molding/compressing paper pulp.</p>
<p>The lids for all capsule types are prepared through the lamination of either aluminum foils or biodegradable laminates, which are then die-cut. After assembly, all capsules are filled with coffee. They are then nitrogen-flushed to preserve freshness and subsequently heat-sealed. Finally, coffee balls are manufactured by compressing ground coffee into dense spheres. These spheres are then spray coated with a thin, protective, and plant-based layer and subsequently dried before being packaged.</p>
<p>Coffee paper filters, whether for single-use or reusable capsules (RC), are engineered for controlled porosity, high wet strength, and taste neutrality. Their creation starts with selecting raw materials, such as wood pulp or sustainable plant fibers, which undergo pulping to form fiber slurry. This pulp is then mechanically treated to enhance fiber properties, with additives, such as wet strength agents, often incorporated. Bleaching, if done, uses eco-friendly methods. The refined slurry is fed onto a mesh belt for sheet formation, followed by pressing to remove water and drying to solidify the paper. Many filters are then textured to boost filtration efficiency. Finally, large paper rolls are slit and cut into precise shapes, such as circular discs for coffee capsules, which are integrated during automated capsule filling or designed for reusable capsules. All details about the primary, secondary, and tertiary packages used are given in Environmental impact of coffee packaging..</p>
</sec>
<sec id="S3_2_2">
<title><italic>Transportation and distribution stage</italic></title>
<p>Complete transportation throughout the supply chain comprised Euro 5 road vehicles, as detailed in <xref ref-type="table" rid="T9">Table 9</xref>. This encompassed the transportation of the following:</p>
<table-wrap id="T9" orientation="portrait" position="float">
<label>Table 9.</label><caption><p>Logistics of input/output materials by EURO 5 road vehicles: transportation routes, vehicle types, load capacities, and distances for materials in the supply chain.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Input/output materials</th>
<th align="left">From</th> 
<th align="left">To</th>
<th align="center">Means of transport</th> 
<th align="center">Load capacity (MT)</th>
<th align="center">Distance (km)</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">Paper filters</td>
<td align="left">PFG</td>
<td align="left">FG</td>
<td align="center">Heavy rigid truck</td>
<td align="center">7.5&#x2013;16</td>
<td align="center">850</td>
</tr>
<tr>
<td align="left">Multilayer bags, pouches, sticky tape, and PE films</td>
<td align="left">PFG</td>
<td align="left">FG</td>
<td align="center">Heavy rigid truck</td>
<td align="center">7.5&#x2013;16</td>
<td align="center">300</td>
</tr>
<tr>
<td align="left">Cartons, pallet labels</td>
<td align="left">PFG</td>
<td align="left">FG</td>
<td align="center">Heavy rigid truck</td>
<td align="center">7.5&#x2013;16</td>
<td align="center">50</td>
</tr>
<tr>
<td align="left">Pallets</td>
<td align="left">EPMC</td>
<td align="left">FG</td>
<td align="center">Heavy rigid truck</td>
<td align="center">7.5&#x2013;16</td>
<td align="center">200</td>
</tr>
<tr>
<td align="left">Pallets (returned)</td>
<td align="left">DC</td>
<td align="left">EPMC</td>
<td align="center">Heavy rigid truck</td>
<td align="center">7.5&#x2013;16</td>
<td align="center">800</td>
</tr>
<tr>
<td align="left">Palletized coffee</td>
<td align="left">FG</td>
<td align="left">DC</td>
<td align="center">Articulated truck</td>
<td align="center">16&#x2013;32</td>
<td align="center">1,000</td>
</tr>
<tr>
<td align="left">Palletized coffee</td>
<td align="left">DC</td>
<td align="left">SoP</td>
<td align="center">Light-medium rigid truck</td>
<td align="center">3.5&#x2013;7.5</td>
<td align="center">50</td>
</tr>
<tr>
<td align="left">Organic and packaging wastes</td>
<td align="left">FG, CH</td>
<td align="left">WCC</td>
<td align="center">Heavy rigid truck</td>
<td align="center">7.5&#x2013;16</td>
<td align="center">50</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF9-1"><p>Notes: CH: consumer houses; DC: distribution center; EPMC: EPAL wood pallet managing center; FG: factory gate; PFG: packaging factory gate; PoS: point of sale; WCC: waste collection center.</p></fn></table-wrap-foot>
</table-wrap>
<p><list list-type="bullet">
<list-item><p>Raw packaging materials (e.g., granulates, slugs, and pulp) from their production sites (PS) to the packaging material factory gate (PFG), covering a constant distance of 250 km.</p></list-item>
<list-item><p>Packaging materials from PFG to the main coffee factory gate (FG).</p></list-item>
<list-item><p>Final palletized products from FG to DCs and PoS.</p></list-item>
<list-item><p>EPAL wood pallets between the Euro pallet managings center (EPMC), FG, and DCs.</p></list-item>
<list-item><p>Processing waste from FG and post-consumer organic and packaging wastes from consumer houses to WCCs.</p></list-item>
</list></p>
<p>Logistics data were partially sourced from a typical Italian coffee processing plant (<xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>) and partly from the Product Category Rules for Moka coffee and espresso preparation (EPD, 2019a, 2019b).</p>
</sec>
<sec id="S3_2_3">
<title><italic>Consumer phase</italic></title>
<p>All coffee formats are stored at room temperature. To prepare a 40-mL cup of coffee, the energy requirements were determined as indicated in the category rules for Moka and espresso coffees (EPD, 2019a, 2019b) and detailed in <xref ref-type="table" rid="T2">Table 2</xref>. Notably, the specific energy consumption per coffee cup, as measured for PE-Al-PET capsules (Format F5) and shown in <xref ref-type="table" rid="T2">Table 2</xref>, was assumed to be consistent with that associated with the use of other Nespresso<sup>&#x00AE;</sup>-compatible capsules, such as formats F3, F4, F6, and F7 as well as coffee balls (F8). Electricity energy (EE) was the only energy resource used, which was withdrawn from the Italian low-voltage grid.</p>
<p>For reusable stainless steel capsules, which are designed for more than 1,000 uses because of their high durability, a specialized twisting device precisely fills each capsule with 4.2&#x2013;5.5 g of ground coffee. This achieves an average fill of 5.2 g while minimizing coffee waste to just 0.1 g per charge. Each capsule includes a silicone gasket and a paper filter, both weighing approximately 0.3 g. Both paper filter and SCGs are suitable for disposal in organic waste stream. For Moka pot and espresso coffee machine preparation, filling of Moka funnel or espresso machine portafilter resulted in a coffee waste of 3% and 2% of ground coffee charge, respectively. In contrast, no coffee waste was assumed for coffee capsules or coffee pods.</p>
<p>To avoid the burden of disposable paper or plastic cups, the beverage was consumed from 120-g earthenware cups. However, to highlight the effect of the different coffee formats used, their washing was not considered to avoid confounding environmental impacts with varying energy classes, load capacities, and washing period of used dishwashers.</p>
</sec>
<sec id="S3_2_4">
<title><italic>Management of coffee processing and packaging waste</italic></title>
<p>As detailed in Environmental impact of coffee waste disposal, all wastage from RGC packaging (based on discarded percentages shown in <xref ref-type="table" rid="T8">Table 8</xref>) and the post-consumer phase was collected through a differentiated method. These wastes were then disposed of according to Italy&#x2019;s 2022 municipal solid waste management settings, as outlined in <xref ref-type="table" rid="T7">Table 7</xref>.</p>
<p>Notably, SCGs were collected as organic waste. This included SCGs separated from Moka funnels, espresso machine portafilters, reusable capsules as well as those contained within the exhausted coffee pads, PLA- or paper-based capsules, and coffee balls. The mass of this organic waste amounted to 2.14 &#x00B1; 0.2 times the mass of original ground coffee, regardless of the coffee format used (<xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>). Conversely, Al, PE-Al-PET, and PP capsules were not separated from their SCGs and were disposed of in the undifferentiated fraction of municipal solid waste.</p>
</sec>
</sec>
<sec id="S3_3">
<title>Environmental impact assessment</title>
<p>Environmental impact of the chosen functional unit was estimated using the standard PEF methodology (<xref ref-type="bibr" rid="ref28">European Commission, 2018</xref>), which is embedded in the SimaPro software (PR&#x00E9; Consultants, Amersfoort, NL). Following a cut-off system model (Ecoinvent, 2024), the producer is held responsible for waste disposal, and no credit is received for the provision of recyclable materials. Therefore, all potential CO<sub>2</sub> credits from the recycling of both renewable and nonrenewable materials were excluded.</p>
<p>The PEF method accounts for 16 impact categories, with their reference substances indicated in parentheses: &#x201C;climate change&#x201D; (CC: kg CO<sub>2e</sub>); &#x201C;ozone depletion&#x201D; (OD: kg CFC-11<sub>e</sub>); &#x201C;ionizing radiation-human health&#x201D; (IR: kBq <sup>235</sup>U<sub>e</sub>); &#x201C;photochemical ozone formation&#x201D; (PhOF: kg NMVOC<sub>e</sub>); &#x201C;particulate matter (PM: disease inc.);&#x201D; &#x201C;human toxicity, non-cancer&#x201D; (NC-HT: CTU<sub>h</sub>); &#x201C;human toxicity, cancer&#x201D; (C-HT: CTU<sub>h</sub>); &#x201C;acidification&#x201D; (AC: mol H<sup>+</sup><sub>e</sub>); &#x201C;freshwater eutrophication&#x201D; (FWE: kg P<sub>e</sub>); &#x201C;marine eutrophication&#x201D; (ME: kg N<sub>e</sub>); &#x201C;terrestrial eutrophication&#x201D; (TE [mol N<sub>e</sub>]); &#x201C;freshwater eco-toxicity&#x201D; (FWET: CTU<sub>e</sub>); &#x201C;land use&#x201D; (LU: Pt); &#x201C;water scarcity&#x201D; (WU: m<sup>3</sup> depriv.); &#x201C;resource use fossils&#x201D; (RUF; MJ); and &#x201C;resource use-mineral and metals&#x201D; (RUMM [kg Sb<sub>e</sub>]).</p>
<p>This methodology consolidates these environmental impacts into a single point value. This is achieved by normalizing each impact category against its corresponding global impact, as recommended by <xref ref-type="bibr" rid="ref79">Sala <italic>et al</italic>. (2017)</xref>. The normalized scores are then weighed according to <xref ref-type="bibr" rid="ref78">Sala <italic>et al</italic>. (2018)</xref> and are summed to yield the overall weighed score (PEF).</p>
</sec>
<sec id="S3_4">
<title>Sensitivity analysis</title>
<p>To address uncertainties in SCG and packaging waste proportions and resource consumption within the brewing process, a sensitivity analysis was conducted using Monte Carlo simulations. Triangular and/or normal probability distributions were assigned to relevant parameters in the LCA model. Employing the SimaPro software, 2,000 iterations were performed, generating random variables within these defined uncertainty ranges. This process recalculated impact categories and the overall score, resulting in a probability distribution of potential outcomes that comprehensively assess the study&#x2019;s inherent uncertainty. Tukey&#x2019;s Honestly Significant Difference (HSD) test (<italic>p</italic> &#x003C; 0.05) was subsequently applied to evaluate the statistical significance of differences observed among parameters.</p>
</sec>
</sec>
<sec id="S4">
<title>Results and Discussion</title>
<sec id="S4_1">
<title>Waste mass balances and packaging material discards for diverse coffee formats</title>
<p><xref ref-type="table" rid="T10">Table 10</xref> provides a detailed mass balance of waste generated when a net amount of 720 kg of RGC is packed for eight different coffee packaging formats, designated F1&#x2013;F8. This analysis incorporates the proportions of raw material and packaging materials discarded at industrial roaster scale, as detailed in <xref ref-type="table" rid="T8">Table 8</xref>. All wastage and material discards are presented in kg, as indicated in the &#x201C;Unit&#x201D; column.</p>
<table-wrap id="T10" orientation="portrait" position="float">
<label>Table 10.</label><caption><p>Waste mass balances and packaging material discards for the eight coffee packaging formats described in Table 5 when packing a net amount of 720 kg of roasted and ground coffee (RGC).</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Coffee formats Parameter</th>
<th align="center">F1</th>
<th align="center">F2</th>
<th align="center">F3</th>
<th align="center">F4</th>
<th align="center">F5</th>
<th align="center">F6</th>
<th align="center">F7</th>
<th align="center">F8</th>
<th align="center">Unit</th>
</tr>
</thead>
<tbody valign="top">
<tr>
<td align="left">RGC</td>
<td align="center">722.16</td>
<td align="center">722.16</td>
<td align="center">722.16</td>
<td align="center">722.16</td>
<td align="center">722.16</td>
<td align="center">722.16</td>
<td align="center">722.16</td>
<td align="center">722.16</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Wood waste</td>
<td align="center">0.03</td>
<td align="center">0.18</td>
<td align="center">0.07</td>
<td align="center">0.07</td>
<td align="center">0.07</td>
<td align="center">0.07</td>
<td align="center">0.07</td>
<td align="center">0.10</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Paper and cardboard waste</td>
<td align="center">46.2</td>
<td align="center">482.8</td>
<td align="center">239.3</td>
<td align="center">239.4</td>
<td align="center">228.7</td>
<td align="center">239.4</td>
<td align="center">242.8</td>
<td align="center">283.4</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Plastic waste</td>
<td align="center">5.1</td>
<td align="center">6.7</td>
<td align="center">3.0</td>
<td align="center">6.9</td>
<td align="center">2.9</td>
<td align="center">3.0</td>
<td align="center">3.0</td>
<td align="center">4.2</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Bag or capsule waste</td>
<td align="center">23.0</td>
<td align="center">151.3</td>
<td align="center">200.3</td>
<td align="center">462.1</td>
<td align="center">146.6</td>
<td align="center">343.8</td>
<td align="center">340.4</td>
<td align="center">0.0</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">SCGs</td>
<td align="center">1,538.8</td>
<td align="center">1,538.8</td>
<td align="center">1,538.8</td>
<td align="center">1,538.8</td>
<td align="center">1,538.8</td>
<td align="center">1,538.8</td>
<td align="center">1,538.8</td>
<td align="center">1,538.8</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Organic waste</td>
<td align="center">2.16</td>
<td align="center">2.16</td>
<td align="center">2.16</td>
<td align="center">2.16</td>
<td align="center">2.16</td>
<td align="center">2.16</td>
<td align="center">2.16</td>
<td align="center">2.16</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Compostable waste</td>
<td align="center">0.00</td>
<td align="center">17.93</td>
<td align="center">0.00</td>
<td align="center">0.00</td>
<td align="center">0.00</td>
<td align="center">78.9</td>
<td align="center">78.9</td>
<td align="center">38.8</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Aluminum waste</td>
<td align="center">0.00</td>
<td align="center">0.00</td>
<td align="center">1.64</td>
<td align="center">0.33</td>
<td align="center">0.14</td>
<td align="center">0.00</td>
<td align="center">0.00</td>
<td align="center">0.0</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">N2Emissions to Air</td>
<td align="center">0.00</td>
<td align="center">0.00</td>
<td align="center">56.3</td>
<td align="center">56.3</td>
<td align="center">53.8</td>
<td align="center">56.3</td>
<td align="center">56.3</td>
<td align="center">0.0</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Overall wastes formed</td>
<td align="center">1,615.3</td>
<td align="center">2,199.9</td>
<td align="center">1,985.3</td>
<td align="center">2,249.8</td>
<td align="center">1,919.2</td>
<td align="center">2,206.2</td>
<td align="center">2,206.2</td>
<td align="center">1,867.5</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Overall packaging wastes formed</td>
<td align="center">74.3</td>
<td align="center">658.9</td>
<td align="center">444.3</td>
<td align="center">708.8</td>
<td align="center">378.3</td>
<td align="center">665.2</td>
<td align="center">665.2</td>
<td align="center">326.6</td>
<td align="center">kg</td>
</tr>
<tr>
<td align="left">Packaging materials&#x2013;RGC ratio</td>
<td align="center">0.103</td>
<td align="center">0.915</td>
<td align="center">0.617</td>
<td align="center">0.984</td>
<td align="center">0.525</td>
<td align="center">0.924</td>
<td align="center">0.924</td>
<td align="center">0.454</td>
<td align="center">kg/kg</td>
</tr>
</tbody>
</table></table-wrap>
<p>Consistently, SCGs represent the largest single waste component across all formats, contributing approximately 1,538.8 kg, which translates to about 2.1 kg/kg of RGC.</p>
<p>Regarding packaging of waste components, paper and cardboard waste represents a major contribution, particularly for most capsule and pad formats. Coffee pads (F2) lead significantly with 482.8 kg, followed by coffee balls (F8) at 283.4 kg. Various capsule formats (F3, F4, F5, F6, and F7) show contributions ranging from 228.7 kg to 239.4 kg. In contrast, coffee flexible multilayer bags (F1) generate a significantly lower amount at 46.2 kg.</p>
<p>Regarding plastic waste, coffee PP capsules (F4) afforded rise to the highest amount at 6.9 kg, followed closely by coffee pads (F2) at 6.7 kg. Coffee balls (F8) contributed 4.2 kg of plastic waste. Other capsule types, such as F3, F5, F6, and F7, generate notably lower plastic waste, typically around 2.9&#x2013;3.0 kg. Coffee flexible multilayer bags (F1) were responsible for 5.1 kg of plastic waste.</p>
<p>The &#x201C;Bag or Capsule waste&#x201D; category specifically reflects the mass of primary packaging unit discarded. Coffee PP capsules (F4) show the highest contribution at 462.1 kg, followed by PBS/PLA (F6) at 343.8 kg and paper-based (F7) capsules at 340.4 kg. Other capsule types, such as F3 (200.3 kg) and F5 (146.6 kg), also showed substantial contributions, as do pads (F2) at 151.3 kg. Interestingly, coffee balls (F8) have no contribution to this category, as their primary packaging waste is classified as compostable waste. Even in this category, coffee flexible multilayer bags (F1) have a significantly lower amount at 23.0 kg.</p>
<p>Aluminum waste primarily derives from Al capsules (F3) at 1.64 kg, while formats incorporating aluminum lids, such as F4 (0.33 kg) and F5 (0.14 kg), report smaller amounts of aluminum waste. Formats F1, F2, and F8 generate no aluminum waste in this context.</p>
<p>Regarding the compostable waste category, PBS/PLA (F6) and paper-based (F7) capsules show a significant amount of compostable waste at 78.9 kg each. They are followed by coffee balls (F8) at 38.8 kg and coffee pads (F2) at 17.9 kg, which is attributable to their paper filter and biopolymer film coating, respectively.</p>
<p>Small amounts of wood waste (ranging from 0.03 kg to 0.18 kg) and organic waste (2.16 kg for all formats) are also reported, although they are minor contributors compared to other categories.</p>
<p>Nitrogen (N<sub>2</sub>) emissions to air are noted for several capsule types (F3&#x2013;F7), ranging from 53.8 kg to 56.3 kg, indicating emissions associated with their use phase.</p>
<p>When considering the &#x201C;overall packaging wastes formed,&#x201D; the total weight of packaging materials discarded per 720 kg of RGC is maximum in the case of coffee PP capsules (F4) at 708.8 kg. This is followed by PBS/PLA (F6) and paper-based capsules (F7), both at 665.2 kg, and coffee pads (F2) at 658.9 kg. Aluminum (F3) and PE-Al-PET (F5) capsules contribute 444.3 kg and 378.3 kg of packaging waste, respectively. Coffee balls (F8) have a lower amount of waste at 326.6 kg, although the lowest overall packaging waste, at just 74.3 kg, is associated with coffee flexible multilayer bags (F1).</p>
<p>In conclusion, the following key observations are pointed out:</p>
<p><list list-type="bullet">
<list-item><p>Single-serve formats (pads and capsules) generally generate substantially more packaging waste per kg of RGC, compared to flexible multilayer bags (F1) and coffee balls (F8).</p></list-item>
<list-item><p>Coffee flexible multilayer bags (F1) consistently demonstrate the lowest environmental burden from packaging waste across all metrics as shown in Table10.</p></list-item>
<list-item><p>Coffee PP capsules (F4) resulted in the highest packaging materials&#x2013;RGC ratio (0.984 kg/kg), followed by compostable capsules (F6 and F7) at 0.924 kg/kg each, and coffee pads (F2) at 0.915 kg/kg.</p></list-item>
<list-item><p>High figures for &#x201C;bag or capsule waste&#x201D; for most capsule/pad formats confirm that the discarded primary packaging units account for a substantial portion of their overall waste mass.</p></list-item>
<list-item><p>The presence of compostable waste in F2 and F6&#x2013;F8 formats indicates a shift toward more sustainable material choices in these formats, although these still exhibit higher overall packaging waste compared to flexible bag (F1).</p></list-item>
</list></p>
</sec>
<sec id="S4_2">
<title>Environmental profile for diverse coffee formats and brewing systems</title>
<p>To remove the variability associated with coffee variety, cultivation, and initial processing, the same RGC was used across all formats and brewing systems examined here to primarily attribute any differences in PEF scores and impact category contributions to the following:</p>
<p><list list-type="bullet">
<list-item><p>Production, transport, and end-of-life of packaging materials (i.e., bags, pads, and capsules).</p></list-item>
<list-item><p>Use-phase energy of the brewing machines used (e.g., Moka pot, espresso, and pad/capsule machine).</p></list-item>
<list-item><p>Energy and water consumed during the actual brewing of a single cup.</p></list-item>
<list-item><p>Easiness/difficulty to separate and dispose of SCGs and packaging.</p></list-item>
</list></p>
<p><xref ref-type="table" rid="T11">Table 11</xref> presents normalized and weighed impact categories (expressed in mPt) according to the PEF standard method, along with the overall weighed PEF score, for eight coffee formats (F1&#x2013;F8) described in <xref ref-type="table" rid="T5">Table 5</xref> across various brewing systems, when referring to a functional unit of 720 kg of packed RGC. The brewing systems included Moka pot, espresso machine, pad/capsule coffee machines, and reusable capsules for a typical capsule coffee machine.</p>
<table-wrap id="T11" orientation="portrait" position="float">
<label>Table 11.</label><caption><p>Normalized and weighed impact categories (IC) and the overall weighed score (PEF) according to the PEF standard method for various coffee formats (F1&#x2013;F8) described in Table 5 and associated brewing systems, as referred to a functional unit of 720-kg of packed roasted and ground coffee (RGC).</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">&#x00A0;&#x00A0;Coffeeformat</th>
<th align="center"></th>
<th align="center"></th>
<th colspan="2" align="center">F1 MLB</th>
<th align="center"></th>
<th align="center"></th>
<th colspan="2" align="center">F2 CPO</th>
<th colspan="2" align="center">F3 AlC</th>
<th colspan="2" align="center">F4 PPC</th>
<th colspan="2" align="center">F5 PAPC</th>
<th colspan="2" align="center">F6 CP</th>
<th colspan="2" align="center">F7 PC</th>
<th colspan="2" align="center">F8 CB</th>
</tr>
<tr>
<th align="left">&#x00A0;&#x00A0;Brew. system</th>
<th colspan="2" align="center">MP</th>
<th colspan="2" align="center">ECM</th>
<th colspan="2" align="center">RC</th>
<th colspan="2" align="center">PCM</th>
<th align="center"></th>
<th align="center"></th>
<th align="center"></th>
<th align="center"></th>
<th colspan="2" align="center">CCM</th>
<th align="center"></th>
<th align="center"></th>
<th align="center"></th>
<th align="center"></th>
<th colspan="2" align="center">CBM</th>
</tr>
<tr>
<th align="left">&#x00A0;&#x00A0;IC (mPt)</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
<th align="center">M&#x00B1;SD</th>
<th align="center">%</th>
</tr></thead>
<tbody valign="top">
<tr>
<td align="left">&#x00A0;&#x00A0;CC</td>
<td align="center">26.5&#x00B1;0.5</td>
<td align="center"><bold>32.0</bold></td>
<td align="center">30.8&#x00B1;0.2</td>
<td align="center"><bold>32.3</bold></td>
<td align="center">31.4&#x00B1;1.3</td>
<td align="center"><bold>31.8</bold></td>
<td align="center">74.8&#x00B1;2.4</td>
<td align="center"><bold>26.0</bold></td>
<td align="center">117.1&#x00B1;1.4</td>
<td align="center"><bold>41.4</bold></td>
<td align="center">148.8&#x00B1;1.5</td>
<td align="center"><bold>40.9</bold></td>
<td align="center">111.3&#x00B1;0.7</td>
<td align="center"><bold>46.5</bold></td>
<td align="center">110.3&#x00B1;1.5</td>
<td align="center"><bold>34.8</bold></td>
<td align="center">95.7&#x00B1;1.0</td>
<td align="center"><bold>35.9</bold></td>
<td align="center">85.8&#x00B1;1.6</td>
<td align="center"><bold>39.8</bold></td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;OD</td>
<td align="center">0.0&#x00B1;0.0</td>
<td align="center">0.0</td>
<td align="center">0.0&#x00B1;0.0</td>
<td align="center">0.0</td>
<td align="center">0.0&#x00B1;0.0</td>
<td align="center">0.0</td>
<td align="center">0.4&#x00B1;0.1</td>
<td align="center">0.1</td>
<td align="center">0.0&#x00B1;0.0</td>
<td align="center">0.0</td>
<td align="center">0.0&#x00B1;0.0</td>
<td align="center">0.0</td>
<td align="center">0.3&#x00B1;0.0</td>
<td align="center">0.1</td>
<td align="center">0.1&#x00B1;0.0</td>
<td align="center">0.0</td>
<td align="center">0.0&#x00B1;0.0</td>
<td align="center">0.0</td>
<td align="center">0.1&#x00B1;0.0</td>
<td align="center">0.0</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;IR</td>
<td align="center">0.7&#x00B1;0.0</td>
<td align="center">0.9</td>
<td align="center">0.9&#x00B1;0.0</td>
<td align="center">1.0</td>
<td align="center">0.9&#x00B1;0.0</td>
<td align="center">0.9</td>
<td align="center">2.1&#x00B1;0.0</td>
<td align="center">0.7</td>
<td align="center">1.3&#x00B1;0.0</td>
<td align="center">0.5</td>
<td align="center">3.5&#x00B1;0.0</td>
<td align="center">1.0</td>
<td align="center">1.8&#x00B1;0.0</td>
<td align="center">0.8</td>
<td align="center">4.2&#x00B1;0.1</td>
<td align="center">1.3</td>
<td align="center">2.4&#x00B1;0.0</td>
<td align="center">0.9</td>
<td align="center">1.3&#x00B1;0.0</td>
<td align="center">0.6</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;PhOF</td>
<td align="center">3.3&#x00B1;0.0</td>
<td align="center">4.0</td>
<td align="center">3.8&#x00B1;0.0</td>
<td align="center">4.0</td>
<td align="center">3.9&#x00B1;0.1</td>
<td align="center">4.0</td>
<td align="center">9.8&#x00B1;0.4</td>
<td align="center">3.4</td>
<td align="center">8.8&#x00B1;0.1</td>
<td align="center">3.1</td>
<td align="center">11.9&#x00B1;0.1</td>
<td align="center">3.3</td>
<td align="center">7.9&#x00B1;0.0</td>
<td align="center">3.3</td>
<td align="center">12.1&#x00B1;0.2</td>
<td align="center">3.8</td>
<td align="center">9.6&#x00B1;0.1</td>
<td align="center">3.6</td>
<td align="center">17.3&#x00B1;0.5</td>
<td align="center">8.0</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;PM</td>
<td align="center">6.0&#x00B1;0.1</td>
<td align="center">7.3</td>
<td align="center">6.5&#x00B1;0.0</td>
<td align="center">6.9</td>
<td align="center">6.8&#x00B1;0.2</td>
<td align="center">6.9</td>
<td align="center">24.1&#x00B1;2.8</td>
<td align="center">8.3</td>
<td align="center">14.9&#x00B1;0.1</td>
<td align="center">5.3</td>
<td align="center">20.2&#x00B1;0.1</td>
<td align="center">5.6</td>
<td align="center">12.4&#x00B1;0.1</td>
<td align="center">5.2</td>
<td align="center">20.8&#x00B1;0.3</td>
<td align="center">6.6</td>
<td align="center">18.3&#x00B1;0.2</td>
<td align="center">6.8</td>
<td align="center">12.7&#x00B1;0.2</td>
<td align="center">5.9</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;AC</td>
<td align="center">4.7&#x00B1;0.1</td>
<td align="center">5.6</td>
<td align="center">5.4&#x00B1;0.0</td>
<td align="center">5.7</td>
<td align="center">5.6&#x00B1;0.3</td>
<td align="center">5.7</td>
<td align="center">14.3&#x00B1;2.4</td>
<td align="center">5.0</td>
<td align="center">8.7&#x00B1;0.1</td>
<td align="center">3.1</td>
<td align="center">12.8&#x00B1;0.1</td>
<td align="center">3.5</td>
<td align="center">6.9&#x00B1;0.0</td>
<td align="center">2.9</td>
<td align="center">15.1&#x00B1;0.3</td>
<td align="center">4.8</td>
<td align="center">11.0&#x00B1;0.2</td>
<td align="center">4.1</td>
<td align="center">7.6&#x00B1;0.1</td>
<td align="center">3.5</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;FWE</td>
<td align="center">2.8&#x00B1;0.1</td>
<td align="center">3.4</td>
<td align="center">3.4&#x00B1;0.0</td>
<td align="center">3.6</td>
<td align="center">4.1&#x00B1;0.2</td>
<td align="center">4.1</td>
<td align="center">21.8&#x00B1;8.6</td>
<td align="center">7.6</td>
<td align="center">11.4&#x00B1;0.1</td>
<td align="center">4.0</td>
<td align="center">17.1&#x00B1;0.2</td>
<td align="center">4.7</td>
<td align="center">5.1&#x00B1;0.0</td>
<td align="center">2.1</td>
<td align="center">13.4&#x00B1;0.4</td>
<td align="center">4.2</td>
<td align="center">16.5&#x00B1;0.5</td>
<td align="center">6.2</td>
<td align="center">3.9&#x00B1;0.1</td>
<td align="center">1.8</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;ME</td>
<td align="center">1.8&#x00B1;0.0</td>
<td align="center">2.2</td>
<td align="center">2.0&#x00B1;0.0</td>
<td align="center">2.1</td>
<td align="center">2.1&#x00B1;0.1</td>
<td align="center">2.1</td>
<td align="center">8.5&#x00B1;1.8</td>
<td align="center">3.0</td>
<td align="center">7.3&#x00B1;0.1</td>
<td align="center">2.6</td>
<td align="center">8.5&#x00B1;0.1</td>
<td align="center">2.3</td>
<td align="center">5.5&#x00B1;0.0</td>
<td align="center">2.3</td>
<td align="center">8.4&#x00B1;0.1</td>
<td align="center">2.7</td>
<td align="center">7.6&#x00B1;0.1</td>
<td align="center">2.9</td>
<td align="center">6.3&#x00B1;0.1</td>
<td align="center">2.9</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;TE</td>
<td align="center">2.7&#x00B1;0.1</td>
<td align="center">3.3</td>
<td align="center">3.0&#x00B1;0.0</td>
<td align="center">3.2</td>
<td align="center">3.2&#x00B1;0.1</td>
<td align="center">3.2</td>
<td align="center">9.1&#x00B1;2.0</td>
<td align="center">3.1</td>
<td align="center">5.2&#x00B1;0.0</td>
<td align="center">1.8</td>
<td align="center">6.8&#x00B1;0.0</td>
<td align="center">1.9</td>
<td align="center">3.4&#x00B1;0.0</td>
<td align="center">1.4</td>
<td align="center">7.7&#x00B1;0.2</td>
<td align="center">2.4</td>
<td align="center">6.4&#x00B1;0.1</td>
<td align="center">2.4</td>
<td align="center">4.3&#x00B1;0.1</td>
<td align="center">2.0</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;FWET</td>
<td align="center">3.6&#x00B1;0.1</td>
<td align="center">4.3</td>
<td align="center">3.9&#x00B1;0.0</td>
<td align="center">4.1</td>
<td align="center">4.1&#x00B1;0.2</td>
<td align="center">4.1</td>
<td align="center">9.4&#x00B1;2.4</td>
<td align="center">3.3</td>
<td align="center">7.0&#x00B1;0.1</td>
<td align="center">2.5</td>
<td align="center">7.7&#x00B1;0.1</td>
<td align="center">2.1</td>
<td align="center">4.9&#x00B1;0.0</td>
<td align="center">2.1</td>
<td align="center">11.3&#x00B1;0.2</td>
<td align="center">3.6</td>
<td align="center">8.8&#x00B1;0.1</td>
<td align="center">3.3</td>
<td align="center">6.7&#x00B1;0.1</td>
<td align="center">3.1</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;C-HT</td>
<td align="center">0.4&#x00B1;0.0</td>
<td align="center">0.5</td>
<td align="center">0.5&#x00B1;0.0</td>
<td align="center">0.5</td>
<td align="center">0.5&#x00B1;0.0</td>
<td align="center">0.5</td>
<td align="center">0.5&#x00B1;1.8</td>
<td align="center">0.2</td>
<td align="center">0.8&#x00B1;0.0</td>
<td align="center">0.3</td>
<td align="center">1.0&#x00B1;0.0</td>
<td align="center">0.3</td>
<td align="center">0.9&#x00B1;0.0</td>
<td align="center">0.4</td>
<td align="center">1.4&#x00B1;0.0</td>
<td align="center">0.4</td>
<td align="center">1.1&#x00B1;0.0</td>
<td align="center">0.4</td>
<td align="center">0.8&#x00B1;0.0</td>
<td align="center">0.4</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;NC-HT</td>
<td align="center">1.5&#x00B1;0.0</td>
<td align="center">1.8</td>
<td align="center">1.8&#x00B1;0.0</td>
<td align="center">1.8</td>
<td align="center">1.8&#x00B1;0.1</td>
<td align="center">1.8</td>
<td align="center">&#x2013;0.9&#x00B1;48.2</td>
<td align="center">&#x2013;0.3</td>
<td align="center">3.0&#x00B1;0.1</td>
<td align="center">1.1</td>
<td align="center">3.1&#x00B1;0.1</td>
<td align="center">0.9</td>
<td align="center">3.7&#x00B1;0.0</td>
<td align="center">1.5</td>
<td align="center">4.8&#x00B1;0.1</td>
<td align="center">1.5</td>
<td align="center">3.8&#x00B1;0.1</td>
<td align="center">1.4</td>
<td align="center">2.9&#x00B1;0.0</td>
<td align="center">1.4</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;LU</td>
<td align="center">0.5&#x00B1;0.0</td>
<td align="center">0.6</td>
<td align="center">0.5&#x00B1;0.0</td>
<td align="center">0.6</td>
<td align="center">0.9&#x00B1;0.0</td>
<td align="center">0.9</td>
<td align="center">2.8&#x00B1;0.6</td>
<td align="center">1.0</td>
<td align="center">1.6&#x00B1;0.0</td>
<td align="center">0.6</td>
<td align="center">2.5&#x00B1;0.0</td>
<td align="center">0.7</td>
<td align="center">1.2&#x00B1;0.0</td>
<td align="center">0.5</td>
<td align="center">2.7&#x00B1;0.1</td>
<td align="center">0.8</td>
<td align="center">7.6&#x00B1;0.3</td>
<td align="center">2.9</td>
<td align="center">1.1&#x00B1;0.0</td>
<td align="center">0.5</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;WU</td>
<td align="center">7.9&#x00B1;0.1</td>
<td align="center">9.5</td>
<td align="center">7.7&#x00B1;0.1</td>
<td align="center">8.1</td>
<td align="center">8.6&#x00B1;0.3</td>
<td align="center">8.8</td>
<td align="center">54.8&#x00B1;6.3</td>
<td align="center"><italic>19.0</italic></td>
<td align="center">60.2&#x00B1;1.2</td>
<td align="center"><italic>21.3</italic></td>
<td align="center">35.7&#x00B1;0.2</td>
<td align="center">9.8</td>
<td align="center">29.5&#x00B1;0.2</td>
<td align="center">12.3</td>
<td align="center">30.4&#x00B1;0.3</td>
<td align="center">9.6</td>
<td align="center">31.0&#x00B1;0.3</td>
<td align="center">11.6</td>
<td align="center">29.2&#x00B1;0.6</td>
<td align="center"><italic>13.6</italic></td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;RUF</td>
<td align="center">14.5&#x00B1;0.2</td>
<td align="center"><italic>17.6</italic></td>
<td align="center">17.3&#x00B1;0.1</td>
<td align="center"><italic>18.1</italic></td>
<td align="center">17.3&#x00B1;0.6</td>
<td align="center"><italic>17.6</italic></td>
<td align="center">45.3&#x00B1;0.8</td>
<td align="center">15.7</td>
<td align="center">27.7&#x00B1;0.3</td>
<td align="center">9.8</td>
<td align="center">70.3&#x00B1;0.7</td>
<td align="center"><italic>19.3</italic></td>
<td align="center">35.0&#x00B1;0.2</td>
<td align="center"><italic>14.6</italic></td>
<td align="center">56.6&#x00B1;1.4</td>
<td align="center"><italic>17.9</italic></td>
<td align="center">36.3&#x00B1;0.5</td>
<td align="center"><italic>13.6</italic></td>
<td align="center">26.7&#x00B1;0.3</td>
<td align="center">12.4</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;RUMM</td>
<td align="center">5.9&#x00B1;0.1</td>
<td align="center">7.1</td>
<td align="center">7.7&#x00B1;0.1</td>
<td align="center">8.1</td>
<td align="center">7.6&#x00B1;0.4</td>
<td align="center">7.7</td>
<td align="center">11.5&#x00B1;0.6</td>
<td align="center">4.0</td>
<td align="center">8.2&#x00B1;0.2</td>
<td align="center">2.9</td>
<td align="center">13.5&#x00B1;0.2</td>
<td align="center">3.7</td>
<td align="center">9.3&#x00B1;0.1</td>
<td align="center">3.9</td>
<td align="center">17.3&#x00B1;0.4</td>
<td align="center">5.5</td>
<td align="center">10.6&#x00B1;0.2</td>
<td align="center">4.0</td>
<td align="center">8.7&#x00B1;0.2</td>
<td align="center">4.0</td>
</tr>
<tr>
<td align="left">&#x00A0;&#x00A0;<bold>PEF</bold></td>
<td align="center"><bold>83</bold>&#x00B1;<bold>1</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>95</bold>&#x00B1;<bold>1</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>99</bold>&#x00B1;<bold>4</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>288</bold>&#x00B1;<bold>58</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>283</bold>&#x00B1;<bold>3</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>363&#x00B1;3</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>239</bold>&#x00B1;<bold>1</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>317</bold>&#x00B1;<bold>6</bold></td>
<td align="center">100.0</td>
<td align="center"><bold>267</bold>&#x00B1;4</td>
<td align="center">100.0</td>
<td align="center"><bold>215&#x00B1;3</bold></td>
<td align="center">100.0</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF11-1"><p>Notes: <italic>Coffee formats</italic>: AlC: Al capsules; CB: coffee balls; CP: PBS/PLA capsules; CPO: coffee pads; MLB: multi-layer bags; PAPC: PE-Al-PET capsules; PC: paper-based capsules; PP: polypropylene; PPC: PP capsules.</p></fn>
<fn id="TF11-2"><p><italic>Brewing systems</italic>: CBM: coffee ball machine; CCM: capsule coffee machine; ECM: espresso coffee machine; MP: Moka pot; PCM: pad coffee machine; RC: reusable capsules.</p></fn></table-wrap-foot>
</table-wrap>
<p>Foremost, from the analysis of PEF scores, it was clear that F1 (multi-layer bags) brewed with Moka pot had the lowest environmental impact with a score of 83 mPt. This was probably due to the simplicity of the brewing device, lower use-phase energy consumption per cup, compared to automated machines (<xref ref-type="table" rid="T2">Table 2</xref>), and the packaging format (multi-layer bags), which, while not zero-waste, was less resource-intensive than single-serve capsules. Espresso machine exhibited a slightly higher impact (95 mPt), staying very close to Moka pot. This might be attributed to the higher use-phase energy consumption per cup of espresso machine and higher ground coffee used per single brewing cycle (<xref ref-type="table" rid="T2">Table 2</xref>).</p>
<p>Use of reusable capsules filled with ground coffee packed in multi-laminated bags (F1) displayed a slightly higher impact (99 mPt) than Moka pot and espresso machine. This could be due to the higher use-phase energy consumption per cup of a typical capsule machine (<xref ref-type="table" rid="T2">Table 2</xref>), which might have higher standby power or operational energy than a Moka pot, as well as the use of paper filters that are disposed of in organic waste together with SCGs. In this study, the energy associated with cleaning reusable capsules, as well as the manufacturing impact of reusable capsule themselves over their lifetime of more than 1,000 reuses, were disregarded. Although user cleaning practices were ignored in all the brewing systems examined here, it is critical to note that capsule&#x2019;s actual lifespan in consumer hands could alter the environmental profile of reusable capsules.</p>
<p>Thus, the traditional brewing methods (Moka pot and espresso machine) using ground coffee from multi-layer bags (F1) consistently show significantly lower environmental impacts, compared to all capsule- and pad-based systems. Moreover, formats F2&#x2013;F8 generally show significantly higher environmental impacts, compared to format F1 with traditional brewing methods. The primary reasons for this higher impact are typically as follows:</p>
<p><list list-type="bullet">
<list-item><p><italic>Packaging material production</italic>: The resources and energy required to produce individual pads/capsules (aluminum, PP, PE-Al-PET, PBS/PLA, paper-based, and coffee balls).</p></list-item>
<list-item><p><italic>End-of-life impact</italic>: Disposal of single-use capsules/pads, especially those that cannot be easily separated from SCGs (e.g., Al, PP, and PE-Al-PET capsules) and thus are difficult to recycle. This also underscores that the effectiveness of the existing waste management and recycling infrastructure plays a critical role in realizing the theoretical environmental benefits of various materials.</p></list-item>
<list-item><p><italic>Energy consumption of pad</italic>/<italic>capsule machines</italic>, which often have higher standby power consumption and may be less energy-efficient per cup compared to Moka pots (<xref ref-type="table" rid="T2">Table 2</xref>).</p></list-item>
</list></p>
<p>It is also worth noting that format F5 (i.e., PE-Al-PET capsules) emerged as the one with the &#x201C;best&#x201D; environmental performance among single-serve options. Its PEF score was 239 mPt, despite being considerably higher than F1 traditional methods. This was probably due to its lower capsule mass with respect to other PP (F4) or compostable (F6 and F7) capsules and the absence of a paper-based filter, which was generally used in the other capsules (F3&#x2013;F4 and F6&#x2013;F7). This suggests that these design choices effectively mitigate some material-related impacts, allowing other factors, such as machine energy, to dominate.</p>
<p>In spite of the Quantis report (<xref ref-type="bibr" rid="ref22">Dubois <italic>et al</italic>., 2011</xref>), Al capsules (F3) exhibited a greater environmental impact (283 mPt) than that of multi-laminated ones (F5) (239 mPt), probably because of their greater aluminum content. In fact, both were disposed of as undifferentiated waste, the SCGs and paper-based filters being generally unseparated from capsules and lids.</p>
<p>The recent paper-based capsules (F7) showed a lower PEF (267 mPt), compared to aluminum capsules, probably because paper is biodegradable/compostable and does not need to be separated from SCGs. This finding aligns with the Quantis&#x2019; (2024) report.</p>
<p>Other compostable PBS/PLA capsules (F6) exhibited a higher impact (317 mPt) than PE-Al-PET and paper-based capsules, thus highlighting that &#x201C;bio-base&#x201D; does not automatically mean low impact, as processing and end-of-life pathways for these materials are still resource-intensive. This demonstrates a common challenge in sustainable design, where attempts to mitigate one environmental problem (e.g., material waste through bio-based plastics) can shift burdens to other impact categories, such as CC or RUF, because of energy-intensive production processes.</p>
<p>Despite being a better option than most capsules, coffee pads (F2) still register a substantial environmental impact (288 mPt). This is largely due to the necessity of protective multilayer pouches, which contribute to undifferentiated waste, and the energy consumed by pad machine during use. Variability, quantified by a coefficient of variation (i.e., standard deviation-to-mean ratio) of approximately 20%, was observed, which is linked to the high discard fraction of paper filter in industrial settings (<xref ref-type="bibr" rid="ref16">Cibelli <italic>et al</italic>., 2021</xref>).</p>
<p>Surprisingly, coffee balls (F8) emerged as the best-performing single-serve option, even surpassing F5 by a small margin. This indicates that their compostable nature and lower material requirements contribute to a significantly reduced PEF, compared to traditional plastic or aluminum capsules, as well as novel compostable capsules.</p>
<p>In conclusion, among the single-serve options, coffee balls (F8) and PE-Al-PET capsules (F5) appeared to be better choices, although they still had a higher impact than Moka Pot or espresso machine with the coffee format F1.</p>
<p>Given the standardization of RGC, climate change (CC) and fossil resource use (RUF) were key categories, reflecting energy consumption and material intensity, and proved prominent in differentiating the formats examined.</p>
<p>In the case of multi-layer bags (F1) used with Moka pot, espresso machine, and capsule machine with reusable capsules, climate change and RUF were the dominant factors, representing approximately 32% and 17% of the overall weighed score (PEF), respectively. The primary factor (climate change) was mainly driven by the use-phase energy consumed during brewing and the production/end-of-life of multi-layer bags, while the secondary one (RUF) reflected the fossil resources used for bag production, as well as the paper filters used with reusable capsules, and energy generation.</p>
<p>For coffee pads (F2), climate change, water use (WU), and RUF represented as much as 26%, 19%, and 15.7% of PEF, respectively. The significant contribution of WU was attributable to water consumption for producing coffee pads (e.g., paper or non-woven materials). The packaging (pads and their protective pouches) and pad machine energy demands are also primary drivers for the overall impact.</p>
<p>For aluminum capsules (F3), climate change and WU were the main factors, contributing 41.4% and 21.3% of PEF, respectively. This was unequivocally linked to the manufacturing of aluminum capsules and their associated production processes (e.g., bauxite extraction for aluminum).</p>
<p>For PP capsules (F4), climate change was still the top contributor (40.9% of PEF), but RUF remained very high (19.3%). This highlighted that the production of PP capsules was highly dependent on fossil resources, and the energy for their manufacturing, combined with the machine&#x2019;s use-phase energy, drove the impact of climate change.</p>
<p>For multi-laminated capsules (F5), climate change and RUF represented 46.5% and 14.6% of PEF, respectively. This high contribution of climate change was strongly linked to the use-phase energy consumption of capsule machine and the manufacturing processes of PE-Al-PET multi-layer capsule, despite its potentially lower mass. RUF reflected plastic components and energy.</p>
<p>For PBS/PLA capsules (F6), climate change and RUF were the highest contributors (34.8% vs. 17.9%) because of the energy and resources used in their production processes. Moreover, WU stood out as the third factor (9.6%), probably because of the raw material cultivation or processing of bioplastics. Similarly, for paper-based capsules (F7), climate change led the impact (35.9% of PEF), with RUF (13.6%) and WU (11.6%) also having significant impact. The impact here was primarily from the energy used in the poly-lactate and pulp&#x2013;paper manufacturing process for capsules and the use-phase energy consumption of capsule machine. Their compostable nature minimized some material impacts but shifted the focus to manufacturing energy.</p>
<p>Finally, for coffee balls (F8), climate change was the largest contributor (39.8% of PEF), followed by WU (13.6%) and RUF (12.4%). The greater contribution of WU, compared to RUF, could stem from water demands in the biopolymer production process for coffee balls, while the reduced and simpler packaging material lowered RUF.</p>
<p>In essence, by standardizing the coffee&#x2019;s upstream impact, the analysis clearly highlights that the choice of packaging material (especially its production energy and resource intensity) and energy consumption during the brewing phase are the primary determinants of PEF differences between coffee formats and brewing systems. For formats such as F1 (multi-layer bags) and F8 (coffee balls), where the packaging is either relatively simple or minimized, climate change is the primary driver (e.g., 32.0% for Moka pot (F1), and 39.8% for F8). This suggests that for these systems, the use-phase energy consumed by the brewing machine is the most significant differentiating factor, combined with the basic impact of packaging material production.</p>
</sec>
<sec id="S4_3">
<title>Granular environmental footprint: per-cup analysis of waste and key impacts</title>
<p>As indicated by the overall PEF scores in <xref ref-type="table" rid="T11">Table 11</xref>, traditional coffee preparation methods generally offer substantial environmental advantages. To provide a more granular and actionable understanding of these differences&#x2014;particularly concerning waste generation and specific environmental burdens&#x2014;a detailed per-cup analysis was conducted. This approach directly quantifies the environmental performance of each coffee format at the individual consumption level, aligning with stringent waste reduction and circularity objectives, such as those outlined in regulations like the PPWR.</p>
<p><xref ref-type="table" rid="T12">Table 12</xref> presents the specific mass of organic waste (SCGs) and packaging waste generated per single coffee cup for each of the eight examined formats. Furthermore, it details the per-cup contributions to the most significant environmental impact categories, including climate change, RUF, and WU, along the overall PEF.</p>
<table-wrap id="T12" orientation="portrait" position="float">
<label>Table 12.</label><caption><p>Specific mass of organic waste (SCGs and ground coffee waste) and packaging waste impacting environmental impact categories (CC, RUF, RUMM, and WU), and the overall weighed score (PEF) associated with the preparation of a single cup of coffee using different coffee formats and brewing systems.</p></caption>
<table frame="border" rules="groups">
<thead valign="top">
<tr>
<th align="left">Coffee format</th>
<th colspan="3" align="center">F1 MLB</th>
<th align="center">F2 CPO</th>
<th align="center">F3 AlC</th>
<th align="center">F4 PPC</th>
<th align="center">F5 PAPC</th>
<th align="center">F6 CC</th>
<th align="center">F7 PC</th>
<th align="center">F8 CB</th>
<th align="center">Unit</th>
</tr>
<tr>
<th align="left">Brewing system</th>
<th align="center">MP</th>
<th align="center">ECM</th>
<th align="center">RC</th>
<th align="center">PCM</th>
<th align="center"></th>
<th align="center"></th>
<th align="center">CCM</th>
<th align="center"></th>
<th align="center"></th>
<th align="center">CBM</th>
<th align="center"></th>
</tr></thead>
<tbody valign="top">
<tr>
<td align="left">RGC</td>
<td align="center">5.34</td>
<td align="center">9.00</td>
<td align="center">5.2</td>
<td align="center">7.23</td>
<td align="center">5.50</td>
<td align="center">5.50</td>
<td align="center">5.75</td>
<td align="center">5.50</td>
<td align="center">5.50</td>
<td align="center">5.60</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Wood waste</td>
<td align="center">0.0002</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">0.002</td>
<td align="center">0.001</td>
<td align="center">0.001</td>
<td align="center">0.001</td>
<td align="center">0.001</td>
<td align="center">0.001</td>
<td align="center">0.001</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Paper and cardboard waste</td>
<td align="center">0.343</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">4.849</td>
<td align="center">1.828</td>
<td align="center">1.829</td>
<td align="center">1.826</td>
<td align="center">1.829</td>
<td align="center">1.855</td>
<td align="center">2.204</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Plastic waste</td>
<td align="center">0.038</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">0.067</td>
<td align="center">0.023</td>
<td align="center">0.053</td>
<td align="center">0.023</td>
<td align="center">0.023</td>
<td align="center">0.023</td>
<td align="center">0.033</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Bag/capsule waste</td>
<td align="center">0.170</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">1.520</td>
<td align="center">1.530</td>
<td align="center">3.530</td>
<td align="center">1.171</td>
<td align="center">2.626</td>
<td align="center">2.600</td>
<td align="center">0.000</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Organic waste</td>
<td align="center">11.42</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">15.47</td>
<td align="center">11.77</td>
<td align="center">11.77</td>
<td align="center">12.31</td>
<td align="center">11.77</td>
<td align="center">11.77</td>
<td align="center">11.99</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Compostable waste</td>
<td align="center">-</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">-</td>
<td align="center">-</td>
<td align="center">-</td>
<td align="center">-</td>
<td align="center">0.603</td>
<td align="center">0.603</td>
<td align="center">0.302</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Aluminum waste</td>
<td align="center">0.000</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">0.000</td>
<td align="center">0.013</td>
<td align="center">0.003</td>
<td align="center">0.001</td>
<td align="center">0.000</td>
<td align="center">0.000</td>
<td align="center">0.000</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">Overall waste formed</td>
<td align="center">11.97</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">22.09</td>
<td align="center">15.17</td>
<td align="center">17.19</td>
<td align="center">15.33</td>
<td align="center">16.85</td>
<td align="center">16.853</td>
<td align="center">14.525</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">PM/RGC</td>
<td align="center">0.551</td>
<td align="center"></td>
<td align="center"></td>
<td align="center">6.617</td>
<td align="center">3.394</td>
<td align="center">5.415</td>
<td align="center">3.021</td>
<td align="center">5.081</td>
<td align="center">5.081</td>
<td align="center">2.540</td>
<td align="center">g/cup</td>
</tr>
<tr>
<td align="left">CC<sub>cup</sub></td>
<td align="center">8.2&#x00B1;0.1</td>
<td align="center">13.8&#x00B1;0.1</td>
<td align="center">8.1&#x00B1;0.3</td>
<td align="center">27&#x00B1;1</td>
<td align="center">32.1&#x00B1;0.4</td>
<td align="center">40.8&#x00B1;0.4</td>
<td align="center">31.9&#x00B1;0.2</td>
<td align="center">30.2&#x00B1;0.4</td>
<td align="center">26.2&#x00B1;0.3</td>
<td align="center">23.9&#x00B1;0.4</td>
<td align="center">kg CO<sub>2e</sub>/cup</td>
</tr>
<tr>
<td align="left">RUF<sub>cup</sub></td>
<td align="center">100&#x00B1;1</td>
<td align="center">169&#x00B1;1</td>
<td align="center">98&#x00B1;4</td>
<td align="center">355&#x00B1;7</td>
<td align="center">165&#x00B1;2</td>
<td align="center">419&#x00B1;4</td>
<td align="center">218&#x00B1;1</td>
<td align="center">338&#x00B1;8</td>
<td align="center">217&#x00B1;3</td>
<td align="center">162&#x00B1;2</td>
<td align="center">kJ/cup</td>
</tr>
<tr>
<td align="left">WU<sub>cup</sub></td>
<td align="center">7.7&#x00B1;0.1</td>
<td align="center">13.0&#x00B1;0.1</td>
<td align="center">8.4&#x00B1;0.3</td>
<td align="center">74&#x00B1;9</td>
<td align="center">62&#x00B1;1</td>
<td align="center">36.7&#x00B1;0.2</td>
<td align="center">31.7&#x00B1;0.2</td>
<td align="center">31.3&#x00B1;0.3</td>
<td align="center">31.9&#x00B1;0.3</td>
<td align="center">31&#x00B1;1</td>
<td align="center">L depriv./cup</td>
</tr>
<tr>
<td align="left">PEF<sub>cup</sub></td>
<td align="center">613&#x00B1;10</td>
<td align="center">1,191&#x00B1;9</td>
<td align="center">713&#x00B1;29</td>
<td align="center">2,895&#x00B1;581</td>
<td align="center">2,162&#x00B1;23</td>
<td align="center">2,777&#x00B1;23</td>
<td align="center">1,910&#x00B1;10</td>
<td align="center">2,419&#x00B1;42</td>
<td align="center">2,038&#x00B1;27</td>
<td align="center">1,675&#x00B1;25</td>
<td align="center">nPt/cup</td>
</tr>
</tbody>
</table>
<table-wrap-foot>
<fn id="TF12-1"><p>AlC: AI capsule; CB: coffee balls; CBM: coffee ball machine; CC: PBS/PLA capsules; CCcup: climate change per single coffee cup (kg CO2e/cup); CCM: coffee capsule machine; CPO: coffee pad; ECM: espresso coffee machine; MLB: multi-layer bags; MP: Moka pot; PAPC: PE-Al-PET capsule; PC: paper-based capsule; PCM: pad coffee machine; PEFcup: product environmental footprint per single coffee cup (nPt/cup); PPC: PP capsule; RC: reusable capsules; RUFcup: fossil resource use per single coffee cup (kJ/cup); WUcup: water use per single coffee cup (L depriv./cup).</p></fn></table-wrap-foot>
</table-wrap>
<p>Spent coffee grounds consistently constituted the largest waste component across all coffee formats and brewing methods, irrespective of coffee waste during filling for Moka pot, espresso coffee machine, and reusable capsules. Their amount ranged from 11.4 g/cup for multi-layer bags (F1) brewed with a Moka pot to 15.5 g/cup for coffee pads (F2).</p>
<p>Analysis of packaging waste revealed significant differences. While multi-layer bags with a Moka pot exhibited very low values for paper/cardboard (0.34 g/cup) and plastic waste (0.038 g/cup), all other capsule and pad systems (F2&#x2013;F7), and even coffee balls (F8), showed substantially higher amounts, ranging from 1.83 g/cup to 4.85 g/cup for paper/cardboard, and from 0.023 g/cup to 0.067 g/cup for plastic.</p>
<p>Bag/capsule waste was nil for coffee balls (F8), reflecting their innovative design, but was present for F1 at a low of 0.17 g/cup. All capsule formats, specifically PE-Al-PET capsules (F5) and PP capsules (F4), contributed significantly, with bag/capsule waste ranging from 1.17 g/cup to 3.53 g/cup. This waste was typically disposed of in undifferentiated stream for formats such as Al capsules (F3), PP capsules (F4), and PE-Al-PET capsules (F5), or the organic stream for PSB/PLA capsules (F6) and paper-based capsules (F7). Compostable waste included the lids and filters for PSB/PLA capsules (F6) and paper-based capsules (F7), or the biopolymer coating for coffee balls (F8). Finally, aluminum waste was primarily associated with Al capsules (F3) and their lids (0.013 g/cup), with smaller amounts attributed to Al lids discarded from PP capsules (F4) and PE-Al-PET capsules (F5) (0.003 g/cup).</p>
<p>Overall, the total waste formed was minimal for multi-layer bags (F1) at approximately 12 g/cup. This value increased to 14.5 g/cup for coffee balls (F8) and reached a maximum of 22.1 g/cup for coffee pads (F2), largely driven by their associated packaging.</p>
<p>The GHG emissions per single coffee cup varied significantly. The lowest emissions were observed when using multi-layer bags with a Moka pot (8.2 g CO<sub>2e</sub>/cup). This increased to approximately 24 g CO<sub>2e</sub>/cup for coffee balls (F8) with CBM. Different capsule formats (F3&#x2013;F7) exhibited higher emissions, ranging from 26 g CO<sub>2e</sub>/cup to 41 g CO<sub>2e</sub>/cup, with maximum emission attributed to PP capsules. Similar trends were observed for specific fossil resource use (RUF<sub>cup</sub>) and water use per single coffee cup (WU<sub>cup</sub>). These categories ranged from 100 kJ/cup and 7.7 L deprived/cup for multi-layer bags with a Moka pot to 162 kJ/cup and 31 L deprived/cup for coffee balls (F8), reaching up to 419 kJ/cup for PP capsules (F4) and 75 L deprived/cup for coffee pads (F2).</p>
<p>Finally, the overall weighed score per single coffee cup (PEF<sub>cup</sub>) provided a holistic view of environmental impact. Multi-layer bags (F1) with a Mokapot (613&#x00B1;10 nPt/cup) and coffee balls (1,675&#x00B1;25nPt/cup) demonstrated the best overall environmental performance. All capsule and pad systems, particularly coffee pads (2,895&#x00B1;581 nPt/cup) and PP capsules (2,777&#x00B1;23 nPt/cup), showed significantly higher PEF scores, indicating a greater overall environmental burden. This was largely attributable to the substantial amount of single-use packaging materials (plastic, aluminum, and paper/cardboard) and the energy and resources consumed in their production and disposal. Notably, PP capsules and coffee pads exhibited particularly high fossil resource use and the overall weighed scores.</p>
<p>In conclusion, for those prioritizing environmental sustainability in their coffee choices, selecting ground coffee (such as those used with MLB in a Moka pot) or innovative coffee balls offers a significantly more environment-friendly alternative, compared to various coffee capsule and pad systems. <xref ref-type="table" rid="T12">Table 12</xref> allows for a direct comparison of tangible impacts associated with a single serving of coffee, offering crucial insights for both consumers seeking more sustainable choices and industry stakeholders aiming for environmentally optimized product design.</p>
</sec>
<sec id="S4_4">
<title>Limitations of the Study</title>
<p>While this study provides valuable insights into the PEF of various coffee formats, it is important to acknowledge certain limitations that delineate its scope and inform the interpretation of its findings:</p>
<p><list list-type="bullet">
<list-item><p><italic>Trade-off between environmental impact and consumer convenience</italic>: The observed superior environmental performance of traditional brewing systems, such as Moka pots and espresso machines utilizing ground coffee from multilayer bags, or even reusable capsules, often comes at the expense of increased consumer effort. These methods typically demand more active engagement from the consumer, involving steps such as precise filling of portafilter or reusable capsule with ground coffee, and the manual disposal of SCGs into organic waste stream. In contrast, single-serving systems, despite their higher PEF, offer unparalleled convenience, a factor that significantly contributes to their rapidly increasing market share. This highlights a key challenge in promoting sustainable consumption&#x2014;effectively balancing environmental responsibility with prevailing consumer preferences for ease of use.</p></list-item>
<list-item><p><italic>Impact of a single RGC variety</italic>: The choice to utilize a single RGC variety inherently influences the impact associated with coffee waste generated during the filling of portafilters for Moka pots, espresso machines, and reusable capsules. Different grind sizes or variations in coffee density could potentially alter the quantity or characteristics of this specific waste stream.</p></list-item>
<list-item><p><italic>Variability in energy consumption</italic>: Specific energy consumption per cup can be significantly influenced by consumer behavior. Examples include the promptness with which a user switches off an electric stove used to heat a Moka pot, or inherent variations in machine efficiency and individual usage patterns for electric brewing systems. These behavioral aspects introduce a degree of variability not fully captured.</p></list-item>
<list-item><p><italic>Dependency on national electricity grids</italic>: The environmental impact associated with electricity consumption for brewing is directly tied to the specific energy mix of the national electricity grid where the coffee is prepared. This study utilized the Italian electricity mix; consequently, regional or national variations in energy sources could alter the overall environmental profile of consumption phase.</p></list-item>
<list-item><p><italic>Scope of the streamlined LCA</italic>: This study employed a streamlined LCA methodology, focusing specifically on the use and post-consumer phases of coffee consumption. While this targeted scope was deliberately chosen to align with the PPWR&#x2019;s emphasis on packaging and end-of-life considerations, a comprehensive cradle-to-grave LCA would provide a more holistic understanding by including the upstream agricultural, processing, and transportation phases of coffee production and packaging manufacturing.</p></list-item>
</list></p>
</sec>
</sec>
<sec id="S5">
<title>Conclusion and the Future Outlook</title>
<p>This study successfully characterized the fundamentals of coffee production and consumption, along with their associated environmental impacts, through a streamlined LCA focusing on the use and post-consumer phases of various coffee formats. This targeted assessment was motivated by the PPWR&#x2019;s emphasis on waste reduction and circularity, the escalating environmental burden of single-serve coffee packaging, and the imperative for consistent environmental impact comparisons.</p>
<p>This investigation across eight distinct coffee formats&#x2014;flexible multilayer bags, pads, and several capsule types (Al, PP, PE-Al-PET, polylactate, and paper), along with innovative coffee balls&#x2014;and their associated brewing systems (Moka pot, espresso machine, pad/capsule machines, and reusable capsules) yielded significant insights. Employing a functional unit of 720 kg of RGC, the streamlined LCA, assessed with the EU&#x2019;s PEF methodology, unequivocally demonstrated that traditional brewing systems utilizing ground coffee from multilayer bags were by far less impactful than coffee balls and all single-serving capsules.</p>
<p>This finding, consistently supported by the normalized and weighed impact categories and the overall weighed PEF score (<xref ref-type="table" rid="T11">Table 11</xref>), underscores the substantial environmental benefits of traditional coffee preparation. For instance, multilayer bags with a Moka pot yielded a PEF score of 613&#x00B1;10 nPt/cup, significantly lower than coffee balls (1,675&#x00B1;25 nPt/cup) and dramatically less than coffee pads (2,895&#x00B1;581 nPt/cup) and PP capsules (2,777&#x00B1;23 nPt/cup).</p>
<p>To provide more granular and actionable insights, <xref ref-type="table" rid="T12">Table 12</xref> meticulously details the specific organic and packaging waste per single coffee cup, beside quantifying associated climate change (carbon footprint), fossil resource use, and water use impacts. This direct quantification per serving powerfully illustrates the disproportionate environmental burden, particularly from single-serve systems. For example, the overall waste formed for multilayer bags was about 12 g/cup, rising to 14.5 g/cup for coffee balls, but reaching 22.1 g/cup for coffee pads. Similarly, GHG emissions ranged from 8.2 g CO<sub>2e</sub>/cup for multilayer bags to 24 g CO<sub>2e</sub>/cup for coffee balls, and between 26 g CO<sub>2e</sub>/cup and 41 g CO<sub>2e</sub>/cup for various capsules, with PP capsules being the highest GHG discharger. This granular data directly support the PPWR&#x2019;s focus on minimization of packaging waste, making results highly tangible for policymakers and consumers.</p>
<p>Despite the acknowledged limitations and inherent convenience factor offered by single-serve systems, this study effectively identifies crucial environmental hotspots within the coffee consumption life cycle, consistently highlighting the disproportionate impact of single-serve coffee formats.</p>
<p>The findings provide a strong evidence-based foundation for recommendations aimed at aligning coffee consumption practices and product design with the EU&#x2019;s evolving regulatory framework, thereby promoting more sustainable choices for both consumers and the industry. Moving forward, continued research focusing on innovative packaging materials, strategies for consumer behavior change, and optimized recycling infrastructure are crucial in further mitigating the environmental footprint of coffee consumption, ultimately aiming to bridge the gap between environmental responsibility and consumer convenience.</p></sec>
</body>
<back>
<ack>
<title>Acknowledgements</title>
<p>None.</p></ack>
<sec id="S6">
<title>Author Contributions</title>
<p>Both authors contributed equally to this article.</p>
</sec>
<sec id="S7">
<title>Competing Interests</title>
<p>The authors had no relevant financial interests to disclose.</p>
</sec>
<sec id="S8" sec-type="COI-statement">
<title>Conflicts of Interest</title>
<p>The authors declare no conflicts of interest.</p>
</sec>
<sec id="S9" sec-type="financial-disclosure">
<title>Funding</title>
<p>This research was supported by the <italic>Consorzio Universitario di Economia Industriale e Manageriale</italic> (CUEIM), Verona, Italy, in the research project entitled &#x201C;Innovation in the world of single-portion coffee &#x2013; coffee PADS,&#x201D; special grant POR CALABRIA FESR-FSE 2014-2020.</p>
</sec>
<ref-list>
<ref id="ref1"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>AFPAK</collab></person-group>. n.d. <article-title>Empty Nespresso capsules for Nespresso machines</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.afpkg.com/empty-nespresso-capsules/">https://www.afpkg.com/empty-nespresso-capsules/</ext-link> (Accessed on: 10 June 2025).</mixed-citation></ref>
<ref id="ref2"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Agenzia Giornalistica Italia (AGI)</collab></person-group>. <year>2016</year>. <article-title>Italiani popolo della moka, 97% non rinuncia al caff&#x00E8;</article-title>. <ext-link ext-link-type="uri" xlink:href="http://www.agi.it/lifestyle/italiani_popolo_della_moka_97_non_rinuncia_al_caff-1125142/news/2016-09-30/">www.agi.it/lifestyle/italiani_popolo_della_moka_97_non_rinuncia_al_caff-1125142/news/2016-09-30/</ext-link> (Accessed on: 27 May 2025).</mixed-citation></ref>
<ref id="ref3"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Ahmed</surname>, <given-names>Md. W</given-names></string-name>., <string-name><surname>Haque</surname>, <given-names>Md. A-</given-names></string-name>., <string-name><surname>Mohibbullah</surname>, <given-names>Md</given-names></string-name>., <string-name><surname>Islam Khan</surname>, <given-names>Md. S</given-names></string-name>., <string-name><surname>Islam</surname>, <given-names>M.A</given-names></string-name>., <string-name><surname>Tarek Mondal</surname>, <given-names>Md. H</given-names></string-name>., and <string-name><surname>Ahmmed</surname>, <given-names>R</given-names></string-name></person-group>. <year>2022</year>. <article-title>A review on active packaging for quality and safety of foods: current trends, applications, prospects and challenges</article-title>. <source>Food Pack Shelf Life</source>. <volume>33</volume>:<fpage>100913</fpage>. <pub-id pub-id-type="doi">10.1016/j.fpsl.2022.100913</pub-id></mixed-citation></ref>
<ref id="ref4"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Almeida</surname> <given-names>J</given-names></string-name>., <string-name><surname>Le Pellec</surname> <given-names>M</given-names></string-name>., and <string-name><surname>Bengtsson</surname> <given-names>J</given-names></string-name></person-group>. <year>2018</year>. <article-title>Reusable coffee cups life cycle assessment and benchmark</article-title>. <source>Technical report</source>. <ext-link ext-link-type="uri" xlink:href="https://www.researchgate.net/publication/328600555_Reusable_coffee_cups_life_cycle_assessment_and_benchmark">https://www.researchgate.net/publication/328600555_Reusable_coffee_cups_life_cycle_assessment_and_benchmark</ext-link> (Accessed on: 27 May 2025).</mixed-citation></ref>
<ref id="ref5"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Andrews</surname> <given-names>J</given-names></string-name></person-group>. <year>2022</year>. <article-title>WMF &#x2013; a brief history of coffee machines</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.linkedin.com/pulse/wmf-brief-history-coffee-machines-jonathan-ison/">https://www.linkedin.com/pulse/wmf-brief-history-coffee-machines-jonathan-ison/</ext-link> (Accessed on: 6 July 2025).</mixed-citation></ref>
<ref id="ref6"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Arellano</surname> <given-names>C</given-names></string-name>., and <string-name><surname>Hern&#x00E1;ndez</surname> <given-names>C</given-names></string-name></person-group>. <year>2023</year>. <article-title>Carbon footprint and carbon storing capacity of Arabica coffee plantations of Central America: a review</article-title>. <source>Coffee Sci</source>. <volume>18</volume>:<fpage>e182072</fpage>. <pub-id pub-id-type="doi">10.25186/.v18i.2072</pub-id></mixed-citation></ref>
<ref id="ref7"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Arias</surname> <given-names>A</given-names></string-name>., <string-name><surname>Ioannidou</surname> <given-names>M</given-names></string-name>., <string-name><surname>Giannakis</surname> <given-names>N</given-names></string-name>., <string-name><surname>Feijoo</surname> <given-names>G</given-names></string-name>., <string-name><surname>Moreira</surname> <given-names>M.T</given-names></string-name>., and <string-name><surname>Koutinas</surname> <given-names>A</given-names></string-name></person-group>. <year>2023</year>. <article-title>Review of potential and prospective strategies for the valorization of coffee grounds within the framework of a sustainable and circular bioeconomy</article-title>. <source>Ind Crops Prod</source>. <volume>205</volume>:<fpage>117504</fpage>. <pub-id pub-id-type="doi">10.1016/j.indcrop.2023.117504</pub-id></mixed-citation></ref>
<ref id="ref8"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Arzoumanidis</surname> <given-names>I</given-names></string-name>., <string-name><surname>Salomone</surname> <given-names>R</given-names></string-name>., <string-name><surname>Petti</surname> <given-names>L</given-names></string-name>., <string-name><surname>Mondello</surname> <given-names>G</given-names></string-name>., and <string-name><surname>Raggi</surname> <given-names>A</given-names></string-name></person-group>. <year>2017</year>. <article-title>Is there a simplified LCA tool suitable for the agri-food industry? An assessment of selected tools</article-title>. <source>J Clean Prod</source>. <volume>149</volume>:<fpage>406</fpage>&#x2013;<lpage>425</lpage>.</mixed-citation></ref>
<ref id="ref9"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Aterini</surname> <given-names>L</given-names></string-name></person-group>. <year>2025</year>. <article-title>Rifiuti organici, oltre il 70% degli impianti italiani di gestione lavora in perdita economica</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.greenreport.it/news/green-economy/4711-rifiuti-organici-oltre-il-70-degli-impianti-italiani-di-gestione-lavora-in-perdita-economica">https://www.greenreport.it/news/green-economy/4711-rifiuti-organici-oltre-il-70-degli-impianti-italiani-di-gestione-lavora-in-perdita-economica</ext-link> (Accessed on: 8 June 2025).</mixed-citation></ref>
<ref id="ref10"><mixed-citation publication-type="book"><person-group person-group-type="author"><collab>British Standards Institution (BSI)</collab></person-group>. <year>2011</year>. <article-title>Specification for the assessment of the life cycle greenhouse gas emissions of goods and services</article-title>, <source>PAS</source> <volume>2050</volume>:<fpage>2011</fpage>. <publisher-name>BSI</publisher-name>, <publisher-loc>London</publisher-loc>.</mixed-citation></ref>
<ref id="ref11"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Brommer</surname> <given-names>E</given-names></string-name>., <string-name><surname>Stratmann</surname> <given-names>B</given-names></string-name>., and <string-name><surname>Quack</surname> <given-names>D</given-names></string-name></person-group>. <year>2011</year>. <article-title>Environmental impacts of different methods of coffee preparation</article-title>. <source>Int J Consumer Stud</source>. <volume>35</volume>:<fpage>212</fpage>&#x2013;<lpage>220</lpage>.</mixed-citation></ref>
<ref id="ref12"><mixed-citation publication-type="other"><person-group person-group-type="author"><string-name><surname>Bush</surname> <given-names>E</given-names></string-name>., <string-name><surname>Josephy</surname> <given-names>B</given-names></string-name>., <string-name><surname>Heutling</surname> <given-names>S</given-names></string-name>., and <string-name><surname>Grie&#x00DF;hammer</surname> <given-names>R</given-names></string-name></person-group>. <year>2009</year>. <article-title>Strategies to Enhance Energy Efficiency of Coffee Machines</article-title>. <publisher-name>Topten International Group TIG</publisher-name>, <publisher-loc>Paris, France</publisher-loc>.</mixed-citation></ref>
<ref id="ref13"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>B&#x00FC;sser</surname> <given-names>S</given-names></string-name>., and <string-name><surname>Jungbluth</surname> <given-names>N</given-names></string-name></person-group>. <year>2009</year>. <article-title>The role of flexible packaging in the life cycle of coffee and butter</article-title>. <source>Int J Life Cycle Assess</source>. <volume>14</volume>(<supplement>Suppl 1</supplement>):<fpage>S80</fpage>&#x2013;<lpage>S91</lpage>.</mixed-citation></ref>
<ref id="ref14"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Chayer</surname> <given-names>J.-A</given-names></string-name>., and <string-name><surname>Kicak</surname> <given-names>K</given-names></string-name></person-group>. <year>2015</year>. <article-title>Life cycle assessment of coffee consumption: comparison of single-serve coffee and bulk coffee brewing</article-title>. <source>Final Report</source>. <publisher-name>Quantis&#x00A9;</publisher-name>, <publisher-loc>Lausanne, CH</publisher-loc>. <ext-link ext-link-type="uri" xlink:href="https://studylib.net/doc/8894288/life-cycle-assessment-of-coffee-consumption--comparison-of">https://studylib.net/doc/8894288/life-cycle-assessment-of-coffee-consumption--comparison-of</ext-link> (Accessed on: 11 July 2025).</mixed-citation></ref>
<ref id="ref15"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Ch&#x00E9;ron-Bessou</surname> <given-names>C</given-names></string-name>., <string-name><surname>Acosta-Alba</surname> <given-names>I</given-names></string-name>., <string-name><surname>Boissy</surname> <given-names>J</given-names></string-name>., <string-name><surname>Payen</surname> <given-names>S</given-names></string-name>., <string-name><surname>Rigal</surname> <given-names>C</given-names></string-name>., <string-name><surname>Setiawan</surname> <given-names>A.A.Rf</given-names></string-name>., <string-name><surname>Sevenster</surname> <given-names>M</given-names></string-name>., <string-name><surname>Tran</surname> <given-names>T</given-names></string-name>., and <string-name><surname>Azapagic</surname> <given-names>A</given-names></string-name></person-group>. <year>2024</year>. <article-title>Unravelling life cycle impacts of coffee: why do results differ so much among studies?</article-title> <source>Sustain Prod Consum</source>. <volume>47</volume>:<fpage>251</fpage>&#x2013;<lpage>266</lpage>. <pub-id pub-id-type="doi">10.1016/j.spc.2024.04.005</pub-id></mixed-citation></ref>
<ref id="ref16"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Cibelli</surname> <given-names>M</given-names></string-name>., <string-name><surname>Cimini</surname> <given-names>A</given-names></string-name>., <string-name><surname>Cerchiara</surname> <given-names>G</given-names></string-name>., and <string-name><surname>Moresi</surname> <given-names>M</given-names></string-name></person-group>. <year>2021</year>. <article-title>Carbon footprint of different methods of coffee preparation</article-title>. <source>Sustain Prod Consum</source>. <volume>27</volume>:<fpage>1614</fpage>&#x2013;<lpage>1625</lpage>. <pub-id pub-id-type="doi">10.1016/j.spc.2021.04.004</pub-id></mixed-citation></ref>
<ref id="ref17"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Coltro</surname> <given-names>L</given-names></string-name>., <string-name><surname>Mourad</surname> <given-names>A.L</given-names></string-name>., <string-name><surname>Oliveira</surname> <given-names>P.A.P.L.V</given-names></string-name>., <string-name><surname>Baddini</surname> <given-names>J.P.O.A</given-names></string-name>., and <string-name><surname>Kletecke</surname> <given-names>R.M</given-names></string-name></person-group>. <year>2006</year>. <article-title>Environmental profile of Brazilian green coffee</article-title>. <source>Int J Life Cycle Assess</source>. <volume>11</volume>(<issue>1</issue>):<fpage>16</fpage>&#x2013;<lpage>21</lpage>. <pub-id pub-id-type="doi">10.1065/lca2006.01.230</pub-id></mixed-citation></ref>
<ref id="ref18"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Comitato Italiano del Caff&#x00E8;</collab></person-group>. <year>2018</year>. <article-title>Disciplinare caff&#x00E8; espresso 2018</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.espressoitalianotradizionale.it/wp-content/uploads/2018/05/Disciplinare-Caff%C3%A8-Espresso-Italiano-Tradizionale-2018-def.pdf">https://www.espressoitalianotradizionale.it/wp-content/uploads/2018/05/Disciplinare-Caff%C3%A8-Espresso-Italiano-Tradizionale-2018-def.pdf</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref19"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Comitato Italiano del Caff&#x00E8;</collab></person-group>. <year>2020</year>. <article-title>Disciplinare del Caff&#x00E8; Moka 2020</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.comunicaffe.it/disciplinare-moka-parametri/">https://www.comunicaffe.it/disciplinare-moka-parametri/</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref20"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>De Monte</surname> <given-names>M</given-names></string-name>., <string-name><surname>Padoano</surname> <given-names>E</given-names></string-name>., and <string-name><surname>Pozzetto</surname> <given-names>D</given-names></string-name></person-group>. <year>2005</year>. <article-title>Alternative coffee packaging: an analysis from a life cycle point of view</article-title>. <source>J Food Eng</source>. <volume>66</volume>(<issue>4</issue>):<fpage>405</fpage>&#x2013;<lpage>411</lpage>. <pub-id pub-id-type="doi">10.1016/j.jfoodeng.2004.04.006</pub-id></mixed-citation></ref>
<ref id="ref21"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Dom&#x00ED;nguez-Pati&#x00F1;o</surname> <given-names>J</given-names></string-name>., <string-name><surname>Mart&#x00ED;nez</surname> <given-names>A</given-names></string-name>., <string-name><surname>Romero</surname> <given-names>R</given-names></string-name>., and <string-name><surname>Orozco</surname> <given-names>I</given-names></string-name></person-group>. <year>2014</year>. <article-title>Life cycle assessment on real time in a coffee machine</article-title>. <source>J Chem Chem Eng</source>. <volume>8</volume>:<fpage>1142</fpage>&#x2013;<lpage>1149</lpage>. <pub-id pub-id-type="doi">10.17265/1934-7375/2014.12.007</pub-id></mixed-citation></ref>
<ref id="ref22"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Dubois</surname> <given-names>C</given-names></string-name>., <string-name><surname>Humbert</surname> <given-names>S</given-names></string-name>., and <string-name><surname>Margni</surname> <given-names>M</given-names></string-name></person-group>. <year>2011</year>. <article-title>Comparative full life cycle assessment of B2C cup of espresso made using a packaging and distribution system from Nespresso Espresso and three generic products</article-title>. <source>Final report</source>. <publisher-name>Quantis Suisse</publisher-name>, <publisher-loc>Lausanne, Switzerland</publisher-loc>. <ext-link ext-link-type="uri" xlink:href="https://studylib.net/doc/8894294/comparative-full-life-cycle-assessment-of-b2c-cup-of">https://studylib.net/doc/8894294/comparative-full-life-cycle-assessment-of-b2c-cup-of</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref23"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>EcoInvent</collab></person-group>. <year>2024</year>. <article-title>Allocation cut-off by classification</article-title>. <ext-link ext-link-type="uri" xlink:href="https://support.ecoinvent.org/system-models#Allocation_classification">https://support.ecoinvent.org/system-models#Allocation_classification</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref24"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Eneroth</surname> <given-names>H</given-names></string-name>., <string-name><surname>Karlsson Potter</surname> <given-names>H</given-names></string-name>., and <string-name><surname>R&#x00F6;&#x00F6;s</surname> <given-names>E</given-names></string-name></person-group>. <year>2022</year>. <article-title>Environmental effects of coffee, tea and cocoa&#x2013;data collection for a consumer guide for plant-based foods</article-title>. <source>Report No. 122. Department of Energy and Technology, Swedish University of Agricultural Sciences, Uppsala, Sweden</source>. <pub-id pub-id-type="doi">10.54612/a.2n3m2d2pjl</pub-id>.</mixed-citation></ref>
<ref id="ref25"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Environmental Product Declarations<sup>&#x00AE;</sup> (EPD)</collab></person-group>. <year>2019a</year>. <article-title>Moka coffee product category classification: UN CPC 23912</article-title>. <source>Version 1.01</source>. <ext-link ext-link-type="uri" xlink:href="https://api.environdec.com/api/v1/EPDLibrary/Files/1458db8f-cff6-417f-8aca-a84f8be224bc/Data">https://api.environdec.com/api/v1/EPDLibrary/Files/1458db8f-cff6-417f-8aca-a84f8be224bc/Data</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref26"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Environmental Product Declarations<sup>&#x00AE;</sup> (EPD)</collab></person-group> <year>2019b</year>. <article-title>Espresso coffee product category classification: UN CPC 23912</article-title>. <source>Version 1.01</source>. <ext-link ext-link-type="uri" xlink:href="https://api.environdec.com/api/v1/EPDLibrary/Files/ab824bcd-b45a-43f1-8843-d97535ac67b8/Data">https://api.environdec.com/api/v1/EPDLibrary/Files/ab824bcd-b45a-43f1-8843-d97535ac67b8/Data</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref27"><mixed-citation publication-type="journal"><person-group person-group-type="author"><collab>European Coffee Federation</collab></person-group>. <year>2024</year>. <article-title>European coffee report 2023&#x2013;2024</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.ecf-coffee.org/wp-content/uploads/2024/07/European-Coffee-Report-2023-2024.pdf">https://www.ecf-coffee.org/wp-content/uploads/2024/07/European-Coffee-Report-2023-2024.pdf</ext-link> (Accessed on: 21 May 2025).</mixed-citation></ref>
<ref id="ref28"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>European Commission</collab></person-group>. <year>2018</year>. <article-title>Product Environmental Footprint Category 2 Rules Guidance 3</article-title>. <source>Version 6.3</source>. <ext-link ext-link-type="uri" xlink:href="https://eplca.jrc.ec.europa.eu/permalink/PEFCR_guidance_v6.3-2.pdf">https://eplca.jrc.ec.europa.eu/permalink/PEFCR_guidance_v6.3-2.pdf</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref29"><mixed-citation publication-type="journal"><person-group person-group-type="author"><collab>European Commission</collab></person-group>. <year>2021</year>. <article-title>Commission Recommendation (EU) 2021/2279 of 15 December 2021 on the use of environmental footprint methods to measure and communicate the life cycle environmental performance of products and organisations</article-title>. <source>Off J Eur Union</source>. <volume>L471</volume>/<issue>1</issue>:<fpage>1</fpage>&#x2013;<lpage>396</lpage>. <ext-link ext-link-type="uri" xlink:href="https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:32021H2279">https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:32021H2279</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref30"><mixed-citation publication-type="book"><person-group person-group-type="author"><collab>European Committee for Electrotechnical Standardization (CENELEC)</collab></person-group>. <year>2014</year>. <article-title>Methods for Measuring the Performance of Electric Household Coffee Makers</article-title>, <source>EN</source> <volume>60661</volume>:<fpage>2014-05</fpage>. <publisher-name>CENELEC</publisher-name>, <publisher-loc>Brussels, Belgium</publisher-loc>.</mixed-citation></ref>
<ref id="ref31"><mixed-citation publication-type="journal"><person-group person-group-type="author"><collab>European Union (EU)</collab></person-group>. <year>1994</year>. <article-title>European Parliament and Council Directive 94/62/EC of 20 December 1994 on packaging and packaging waste</article-title>. <source>Off J Eur Union L</source><volume>365</volume>:<fpage>10</fpage>&#x2013;<lpage>23</lpage>. <ext-link ext-link-type="uri" xlink:href="https://eur-lex.europa.eu/eli/dir/1994/62/oj/eng">https://eur-lex.europa.eu/eli/dir/1994/62/oj/eng</ext-link> (Accessed on: 12 May 2025).</mixed-citation></ref>
<ref id="ref32"><mixed-citation publication-type="book"><person-group person-group-type="author"><string-name><surname>Evangelista</surname> <given-names>R</given-names></string-name>., <string-name><surname>Mariotta</surname> <given-names>C</given-names></string-name>., <string-name><surname>Ricciardi</surname> <given-names>F</given-names></string-name>., and <string-name><surname>Tuscano</surname> <given-names>J</given-names></string-name></person-group>. <year>2023</year>. <article-title>Imballaggi e rifiuti di imballaggio</article-title>. <source>In Chapter 4: Rapporto Rifiuti Urbani. Edizione 2023. Rapporti 393/2023</source>. <publisher-name>ISPRA</publisher-name>, <publisher-loc>Rome</publisher-loc>, pp. <fpage>189</fpage>&#x2013;<lpage>219</lpage>. <ext-link ext-link-type="uri" xlink:href="https://www.isprambiente.gov.it/it/pubblicazioni/rapporti/rapporto-rifiuti-urbani-edizione-2023">https://www.isprambiente.gov.it/it/pubblicazioni/rapporti/rapporto-rifiuti-urbani-edizione-2023</ext-link> (Accessed on: 7 June 2025).</mixed-citation></ref>
<ref id="ref33"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Fisk</surname> <given-names>I.D</given-names></string-name>., <string-name><surname>Kettle</surname> <given-names>A</given-names></string-name>., <string-name><surname>Hofmeister</surname> <given-names>S</given-names></string-name>., <string-name><surname>Virdie</surname> <given-names>A</given-names></string-name>., and <string-name><surname>Silanes Kenny</surname> <given-names>J</given-names></string-name></person-group>. <year>2012</year>. <article-title>Discrimination of roast and ground coffee aroma</article-title>. <source>Flavour</source>. <volume>1</volume>:<fpage>14</fpage>. <pub-id pub-id-type="doi">10.1186/2044-7248-1-14</pub-id></mixed-citation></ref>
<ref id="ref34"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Forcina</surname> <given-names>A</given-names></string-name>., <string-name><surname>Petrillo</surname> <given-names>A</given-names></string-name>., <string-name><surname>Travaglioni</surname> <given-names>M</given-names></string-name>., <string-name><surname>di Chiara</surname> <given-names>S</given-names></string-name>., and <string-name><surname>De Felice</surname> <given-names>F</given-names></string-name></person-group>. <year>2023</year>. <article-title>A comparative life cycle assessment of different spent coffee ground reuse strategies and a sensitivity analysis for verifying the environmental convenience based on the location of sites</article-title>. <source>J Clean Prod</source>. <volume>385</volume>:<fpage>135727</fpage>. <pub-id pub-id-type="doi">10.1016/j.jclepro.2022.135727</pub-id></mixed-citation></ref>
<ref id="ref35"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Freitas</surname> <given-names>V.A</given-names></string-name>., <string-name><surname>Rodrigues Borges</surname> <given-names>L.L</given-names></string-name>., <string-name><surname>Teixeira Ribeiro Vidigal</surname> <given-names>M.C</given-names></string-name>., <string-name><surname>Henrique dos Santos</surname> <given-names>M</given-names></string-name>., and <string-name><surname>Stringheta</surname> <given-names>P.C</given-names></string-name></person-group>. <year>2024</year>. <article-title>Coffee: A comprehensive overview of origin, market, and the quality process</article-title>. <source>Trends Food Sci Technol</source>. <volume>146</volume>:<fpage>104411</fpage>. <pub-id pub-id-type="doi">10.1016/j.tifs.2024.104411</pub-id></mixed-citation></ref>
<ref id="ref36"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Grant</surname> <given-names>T</given-names></string-name></person-group>. <year>2020</year>. <article-title>A brief history of coffee pods</article-title>. <ext-link ext-link-type="uri" xlink:href="https://perfectdailygrind.com/2020/08/a-brief-history-of-coffee-pods-nespresso-keurig-capsules/">https://perfectdailygrind.com/2020/08/a-brief-history-of-coffee-pods-nespresso-keurig-capsules/</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref37"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Guglani</surname> <given-names>A</given-names></string-name></person-group>. <year>2021</year>. <article-title>NEXE&#x2019;s patented compostable capsule for Keurig<sup>&#x00AE;</sup> brewing systems is finally here</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.prnewswire.com/news-releases/nexes-patented-compostable-capsule-for-keurig-brewing-systems-is-finally-here-301412728.html">https://www.prnewswire.com/news-releases/nexes-patented-compostable-capsule-for-keurig-brewing-systems-is-finally-here-301412728.html</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref38"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Hassard</surname> <given-names>H.A</given-names></string-name>., <string-name><surname>Couch</surname> <given-names>M.H</given-names></string-name>., <string-name><surname>Techa-erawan</surname> <given-names>T</given-names></string-name>., and <string-name><surname>McLellan</surname> <given-names>B.C</given-names></string-name></person-group>. <year>2014</year>. <article-title>Product carbon footprint and energy analysis of alternative coffee products in Japan</article-title>. <source>J Clean Prod</source>. <volume>73</volume>:<fpage>310</fpage>&#x2013;<lpage>321</lpage>.</mixed-citation></ref>
<ref id="ref39"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Hejna</surname> <given-names>A</given-names></string-name></person-group>. <year>2021</year>. <article-title>Potential applications of by-products from the coffee industry in polymer technology&#x2013;current state and perspectives</article-title>. <source>Waste Manag</source>. <volume>121</volume>:<fpage>296</fpage>&#x2013;<lpage>330</lpage>. <pub-id pub-id-type="doi">10.1016/j.wasman.2020.12.018</pub-id></mixed-citation></ref>
<ref id="ref40"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Heller</surname> <given-names>M</given-names></string-name></person-group>. <year>2017</year>. <article-title>Food Product Environmental Footprint Literature Summary: coffee</article-title>. <source>Center for Sustainable Systems, University of Michigan, MI (with support from the Oregon Sustainability Board)</source>. <ext-link ext-link-type="uri" xlink:href="https://docslib.org/doc/2428585/food-product-environmental-footprint-literature-summary-coffee#google_vignette">https://docslib.org/doc/2428585/food-product-environmental-footprint-literature-summary-coffee#google_vignette</ext-link> (Accessed on: 29 May 2025).</mixed-citation></ref>
<ref id="ref41"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Henris</surname> <given-names>K</given-names></string-name></person-group>. <year>2025</year>. <article-title>The ideal coffee temperature to serve coffee</article-title>. <ext-link ext-link-type="uri" xlink:href="https://coffeenatics.com/brewing-tips/the-ideal-coffee-temperature-to-serve-coffee/">https://coffeenatics.com/brewing-tips/the-ideal-coffee-temperature-to-serve-coffee/</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref42"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Hicks</surname> <given-names>A.L</given-names></string-name></person-group>. <year>2017</year>. <article-title>Environmental implications of consumer convenience: coffee as a case study</article-title>. <source>J Ind Ecol</source>. <volume>22</volume>(<issue>1</issue>):<fpage>79</fpage>&#x2013;<lpage>91</lpage>. <pub-id pub-id-type="doi">10.1111/jiec.12487</pub-id></mixed-citation></ref>
<ref id="ref43"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>House of Switzerland</collab></person-group>. <year>2017</year>. <article-title>&#x00C9;ric Favre &#x2013; the Swiss inventor who put coffee into capsules</article-title>. <ext-link ext-link-type="uri" xlink:href="https://houseofswitzerland.org/swissstories/economics/eric-favre-swiss-inventor-who-put-coffee-capsules">https://houseofswitzerland.org/swissstories/economics/eric-favre-swiss-inventor-who-put-coffee-capsules</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref44"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Humbert</surname> <given-names>S</given-names></string-name>., <string-name><surname>Loerincik</surname> <given-names>Y</given-names></string-name>., <string-name><surname>Rossi</surname> <given-names>V</given-names></string-name>., <string-name><surname>Margni</surname> <given-names>M</given-names></string-name>., and <string-name><surname>Jolliet</surname> <given-names>O</given-names></string-name></person-group>. <year>2009</year>. <article-title>Life cycle assessment of spray dried soluble coffee and comparison with alternatives (drip filter and capsule espresso)</article-title>. <source>J Clean Prod</source>. <volume>17</volume>:<fpage>1351</fpage>&#x2013;<lpage>1358</lpage>.</mixed-citation></ref>
<ref id="ref45"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Iascone</surname> <given-names>B</given-names></string-name></person-group>. <year>2020</year>. <article-title>Caff&#x00E8;&#x0026;t&#x00E8;: ilmercato in Italia</article-title>. <ext-link ext-link-type="uri" xlink:href="https://italiaimballaggio.it/fatti-e-dati/caffe-te-il-mercato-italia">https://italiaimballaggio.it/fatti-e-dati/caffe-te-il-mercato-italia</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref46"><mixed-citation publication-type="book"><person-group person-group-type="author"><collab>International Coffee Organization (ICO)</collab></person-group>. <year>2022</year>. <article-title>2021 Coffee Development Report: The Future of Coffee</article-title>. <publisher-name>ICO</publisher-name>, <publisher-loc>London</publisher-loc>, pp. <fpage>68</fpage>&#x2013;<lpage>78</lpage>. <ext-link ext-link-type="uri" xlink:href="https://www.icocoffee.org/wp-content/uploads/2022/11/coffee-development-report-2021.pdf">https://www.icocoffee.org/wp-content/uploads/2022/11/coffee-development-report-2021.pdf</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref47"><mixed-citation publication-type="other"><person-group person-group-type="author"><collab>International Organization for Standardization (ISO)</collab></person-group>. <year>2006a</year>. <article-title>14040-Environmental Management e Life Cycle Assessment &#x2013; Principles and Framework</article-title>. <publisher-name>ISO</publisher-name>, <publisher-loc>Gen&#x00E8;ve, CH</publisher-loc>.</mixed-citation></ref>
<ref id="ref48"><mixed-citation publication-type="other"><person-group person-group-type="author"><collab>International Organization for Standardization (ISO)</collab></person-group>. <year>2006b</year>. <article-title>14044-Environmental Management &#x2013; Life Cycle Assessment &#x2013; Requirements and Guidelines</article-title>. <publisher-name>ISO</publisher-name>, <publisher-loc>Gen&#x00E8;ve, CH</publisher-loc>.</mixed-citation></ref>
<ref id="ref49"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Italia Insights</collab></person-group>. <year>2024</year>. <article-title>Il Mercato delle capsule di caff&#x00E8; in Italia</article-title>. <ext-link ext-link-type="uri" xlink:href="https://italiainsights.it/ricerche-di-mercato/agroalimentare-alimenti/il-mercato-delle-capsule-di-caffe-in-italia/">https://italiainsights.it/ricerche-di-mercato/agroalimentare-alimenti/il-mercato-delle-capsule-di-caffe-in-italia/</ext-link> (Accessed on: 26 May 2025).</mixed-citation></ref>
<ref id="ref50"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Italian Institute for Environmental Protection and Research (ISPRA)</collab></person-group>. <year>2024</year>. <article-title>Tasso di riciclaggio dei rifiuti urbani organici</article-title>. <ext-link ext-link-type="uri" xlink:href="https://indicatoriambientali.isprambiente.it/it/rifiuti/tasso-di-riciclaggio-dei-rifiuti-urbani-organici">https://indicatoriambientali.isprambiente.it/it/rifiuti/tasso-di-riciclaggio-dei-rifiuti-urbani-organici</ext-link> (Accessed on: 8 June 2025).</mixed-citation></ref>
<ref id="ref51"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Janissen</surname> <given-names>B</given-names></string-name>., and <string-name><surname>Huynh</surname> <given-names>T</given-names></string-name></person-group>. <year>2018</year>. <article-title>Chemical composition and value-adding applications of coffee industry by-products: a review</article-title>. <source>Resour Conserv Recycl</source>. <volume>128</volume>:<fpage>110</fpage>&#x2013;<lpage>117</lpage>. <pub-id pub-id-type="doi">10.1016/j.resconrec.2017.10.001</pub-id></mixed-citation></ref>
<ref id="ref52"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Jeszka-Skowron</surname> <given-names>M</given-names></string-name>., <string-name><surname>Sentkowska</surname> <given-names>A</given-names></string-name>., <string-name><surname>Pyrzy&#x0144;ska</surname> <given-names>K</given-names></string-name>., and <string-name><surname>De Pe&#x00F1;a</surname> <given-names>M.P</given-names></string-name></person-group>. <year>2016</year>. <article-title>Chlorogenic acids, caffeine content and antioxidant properties of green coffee extracts: influence of green coffee bean preparation</article-title>. <source>Eur Food Res Technol</source>. <volume>242</volume>:<fpage>1403</fpage>&#x2013;<lpage>1409</lpage>. <pub-id pub-id-type="doi">10.1007/s00217-016-2643-y</pub-id></mixed-citation></ref>
<ref id="ref53"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Kadirvel</surname> <given-names>V</given-names></string-name>., <string-name><surname>Palanisamy</surname> <given-names>Y</given-names></string-name>., and <string-name><surname>Ganesan</surname> <given-names>N.D</given-names></string-name></person-group>. <year>2025</year>. <article-title>Active packaging system&#x2013;an overview of recent advances for enhanced food quality and safety</article-title>. <source>Packag Technol Sci</source>. <volume>38</volume>(<issue>2</issue>):<fpage>145</fpage>&#x2013;<lpage>162</lpage>. <pub-id pub-id-type="doi">10.1002/pts.2863</pub-id></mixed-citation></ref>
<ref id="ref54"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Killian</surname> <given-names>B</given-names></string-name>., <string-name><surname>Rivera</surname> <given-names>L</given-names></string-name>., <string-name><surname>Soto</surname> <given-names>M</given-names></string-name>., and <string-name><surname>Navichoc</surname> <given-names>D</given-names></string-name></person-group>. <year>2013</year>. <article-title>Carbon footprint across the coffee supply chain: the case of Costa Rican coffee</article-title>. <source>J Agr Sci Technol</source>. <volume>3</volume>:<fpage>151</fpage>&#x2013;<lpage>170</lpage>.</mixed-citation></ref>
<ref id="ref55"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Kraeutler</surname> <given-names>T</given-names></string-name>., <string-name><surname>Krowiak</surname> <given-names>A</given-names></string-name>., <string-name><surname>Mercurio</surname> <given-names>D</given-names></string-name>., and <string-name><surname>Oriol</surname> <given-names>L</given-names></string-name></person-group>. <year>2015</year>. <article-title>Coffee energy audit: an analysis of coffee energy consumption and efficiency at Boston College</article-title>. <source>Environmental Seminar ENVS4943</source>. <ext-link ext-link-type="uri" xlink:href="https://www.bc.edu/content/dam/files/schools/cas_sites/envstudies/pdf/Student%20Research/2015%20project%20paper/paper-1.pdf">https://www.bc.edu/content/dam/files/schools/cas_sites/envstudies/pdf/Student%20Research/2015%20project%20paper/paper-1.pdf</ext-link> (Accessed on: 22 January 2021).</mixed-citation></ref>
<ref id="ref56"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Ludmir</surname> <given-names>C</given-names></string-name></person-group>. <year>2023</year>. <article-title>Nespresso launches its first paper-based compostable capsules</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.forbes.com/sites/claraludmir/2023/09/13/nespresso-launches-its-pilot-of-home-compostable-capsules/">https://www.forbes.com/sites/claraludmir/2023/09/13/nespresso-launches-its-pilot-of-home-compostable-capsules/</ext-link> (Accessed on: 22 May 2025).</mixed-citation></ref>
<ref id="ref57"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Maletic</surname> <given-names>M</given-names></string-name></person-group>. <year>2023</year>. <article-title>Coffee production and export statistics: latest data on global coffee trade</article-title>. <ext-link ext-link-type="uri" xlink:href="https://craftcoffeespot.com/coffee-production-and-export-statistics/">https://craftcoffeespot.com/coffee-production-and-export-statistics/</ext-link> (Accessed on: 26 May 2025).</mixed-citation></ref>
<ref id="ref58"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Marinello</surname> <given-names>S</given-names></string-name>., <string-name><surname>Balugani</surname> <given-names>E</given-names></string-name>., and <string-name><surname>Gamberini</surname> <given-names>R</given-names></string-name></person-group>. <year>2021</year>. <article-title>Coffee capsule impacts and recovery techniques: a literature review</article-title>. <source>Packag Technol Sci</source>. <volume>34</volume>:<fpage>665</fpage>&#x2013;<lpage>682</lpage>.</mixed-citation></ref>
<ref id="ref59"><mixed-citation publication-type="book"><person-group person-group-type="author"><string-name><surname>McCarrick</surname> <given-names>A</given-names></string-name>., <string-name><surname>Letter</surname> <given-names>B</given-names></string-name>., <string-name><surname>O&#x2019;Dwyer</surname> <given-names>S</given-names></string-name>., <string-name><surname>Knighton</surname> <given-names>M</given-names></string-name>., and <string-name><surname>Neal</surname> <given-names>S.J</given-names></string-name></person-group>. <year>2019</year>. <chapter-title>Carbon monoxide release from whole bean roasted coffee in storage</chapter-title>. In: <source>Proceedings of the 49th International Conference on Environmental Systems ICES-2019-172, Boston, MA, 7&#x2013;11 July;</source> pp. <fpage>1</fpage>&#x2013;<lpage>15</lpage>. <ext-link ext-link-type="uri" xlink:href="https://ttu-ir.tdl.org/bitstream/handle/2346/84940/ICES-2019-172.pdf">https://ttu-ir.tdl.org/bitstream/handle/2346/84940/ICES-2019-172.pdf</ext-link> (Accessed on: 7 June 2025).</mixed-citation></ref>
<ref id="ref60"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Medical News Today</collab></person-group>. <year>2023</year>. <article-title>Caffeine content of different types of coffee</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.medicalnewstoday.com/articles/324986">https://www.medicalnewstoday.com/articles/324986</ext-link> (Accessed on: 7 June 2025).</mixed-citation></ref>
<ref id="ref61"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Mindful Sip</collab></person-group> <year>2024</year>. <article-title>The environmental impact of styrofoam cups</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.mindfulsip.org/the-environmental-impact-of-styrofoam-cups/">https://www.mindfulsip.org/the-environmental-impact-of-styrofoam-cups/</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref62"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Murthy</surname> <given-names>P.S</given-names></string-name>., and <string-name><surname>Naidu</surname> <given-names>M.M</given-names></string-name></person-group>. <year>2012</year>. <article-title>Recovery of phenolic antioxidants and functional compounds from coffee industry by-products</article-title>. <source>Food Bioprocess Technol</source>. <volume>5</volume>(<issue>3</issue>):<fpage>897</fpage>&#x2013;<lpage>903</lpage>. <pub-id pub-id-type="doi">10.1007/s11947-010-0363-z</pub-id>.</mixed-citation></ref>
<ref id="ref63"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Nab</surname> <given-names>C</given-names></string-name>., and <string-name><surname>Maslin</surname> <given-names>M</given-names></string-name></person-group>. <year>2020</year>. <article-title>Life cycle assessment synthesis of the carbon footprint of Arabica coffee: case study of Brazil and Vietnam conventional and sustainable coffee production and export to the United Kingdom</article-title>. <source>Geogr Environ</source>. <volume>7</volume>(<issue>2</issue>):<fpage>e00096</fpage>. <pub-id pub-id-type="doi">10.1002/geo2.96</pub-id></mixed-citation></ref>
<ref id="ref64"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Nestl&#x00E8;</collab></person-group>. <year>2022</year>. <article-title>Nespresso, pioneer of premium single-serve coffee, unveils new range of home compostable coffee capsules</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.nestle.com/media/news/nespresso-unveils-compostable-coffee-capsules">https://www.nestle.com/media/news/nespresso-unveils-compostable-coffee-capsules</ext-link> (Accessed on: 22 May 2025).</mixed-citation></ref>
<ref id="ref65"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Noponen</surname> <given-names>M.R.A</given-names></string-name>., <string-name><surname>Edwards-Jones</surname> <given-names>G</given-names></string-name>., <string-name><surname>Haggar</surname> <given-names>J.P</given-names></string-name>., <string-name><surname>Soto</surname> <given-names>G</given-names></string-name>., <string-name><surname>Attarzadeh</surname> <given-names>N</given-names></string-name>., and <string-name><surname>Healey</surname> <given-names>J.R</given-names></string-name></person-group>. <year>2012</year>. <article-title>Greenhouse gas emissions in coffee grown with differing input levels under conventional and organic management</article-title>. <source>Agr Ecosyst Environ</source>. <volume>151</volume>:<fpage>6</fpage>&#x2013;<lpage>15</lpage>.</mixed-citation></ref>
<ref id="ref66"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>OnWin</collab></person-group>. n.d.a. <article-title>CM03 seria aluminum empty Nespresso compatible capsules</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.capsulemate.com/post/cm03-seria-aluminum-empty-nepsresso-compatible-capsules">https://www.capsulemate.com/post/cm03-seria-aluminum-empty-nepsresso-compatible-capsules</ext-link> (Accessed on: 10 June 2025).</mixed-citation></ref>
<ref id="ref67"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>OnWin</collab></person-group>. n.d.b. <article-title>CM21PB-C compostable/bio-base empty Nespresso compatible capsules</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.capsulemate.com/post/cm21pb-c-compostable-bio-base-empty-nepsresso-compatible-capsules">https://www.capsulemate.com/post/cm21pb-c-compostable-bio-base-empty-nepsresso-compatible-capsules</ext-link> (Accessed on: 10 June 2025).</mixed-citation></ref>
<ref id="ref68"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Pavan</surname> <given-names>A</given-names></string-name></person-group>. <year>2024</year>. <article-title>La gestione del rifiuto indifferenziato in Italia</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.consorziosea.it/la-gestione-del-rifiuto-indifferenziato-italia/">https://www.consorziosea.it/la-gestione-del-rifiuto-indifferenziato-italia/</ext-link> (Accessed on: 7 June 2025).</mixed-citation></ref>
<ref id="ref69"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>PCF Pilotprojekt Deutschland</collab></person-group>. <year>2008</year>. <article-title>Case study Tchibo private kaffee: rarity machare by Tchibo</article-title>. <ext-link ext-link-type="uri" xlink:href="http://www.pcf-projekt.de/files/1232962944/pcf_tchibo_coffee.pdf">http://www.pcf-projekt.de/files/1232962944/pcf_tchibo_coffee.pdf</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref70"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Pergolizzi</surname> <given-names>A</given-names></string-name></person-group>. <year>2024</year>. <article-title>Il Tesoro nascosto dei rifiuti organici</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.rigeneriamoterritorio.it/il-tesoro-nascosto-dei-rifiuti-organici/">https://www.rigeneriamoterritorio.it/il-tesoro-nascosto-dei-rifiuti-organici/</ext-link> (Accessed on: 8 June 2025).</mixed-citation></ref>
<ref id="ref71"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Phrommarat</surname> <given-names>B</given-names></string-name></person-group>. <year>2019</year>. <article-title>Life cycle assessment of ground coffee and comparison of different brewing methods: a case study of organic Arabica coffee in northern Thailand</article-title>. <source>Environ Nat Res J</source>. <volume>17</volume>(<issue>2</issue>):<fpage>96</fpage>&#x2013;<lpage>108</lpage>.</mixed-citation></ref>
<ref id="ref72"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Quantis</collab></person-group>. <year>2015</year>. <article-title>Life cycle assessment of coffee consumption: comparison of single-serve coffee and bulk coffee brewing</article-title>. <source>Final report</source>. <ext-link ext-link-type="uri" xlink:href="https://kidv.nl/LCA%20of%20coffee%20consumption:%20comparison%20of%20single-serve%20coffee%20and%20bulk%20coffee%20brewing">https://kidv.nl/LCA%20of%20coffee%20consumption:%20comparison%20of%20single-serve%20coffee%20and%20bulk%20coffee%20brewing</ext-link> (Accessed on: 6 June 2025).</mixed-citation></ref>
<ref id="ref73"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Quantis</collab></person-group>. <year>2024</year>. <article-title>Life cycle assessment (LCA) of a lungo cup of coffee made from a Nespresso original capsule compared with other coffee systems in Europe</article-title>. <ext-link ext-link-type="uri" xlink:href="https://nestle-nespresso.com/sites/site.prod.nestle-nespresso.com/files/Nespresso_European_LCA_Executive_Summary_Quantis_2024.pdf">https://nestle-nespresso.com/sites/site.prod.nestle-nespresso.com/files/Nespresso_European_LCA_Executive_Summary_Quantis_2024.pdf</ext-link> (Accessed on: 6 June 2025).</mixed-citation></ref>
<ref id="ref74"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Rahmah</surname> <given-names>D.M</given-names></string-name>., <string-name><surname>Putra</surname> <given-names>A.S</given-names></string-name>., <string-name><surname>Ishizaki</surname> <given-names>R</given-names></string-name>., <string-name><surname>Noguchi</surname> <given-names>R</given-names></string-name>., and <string-name><surname>Ahamed</surname> <given-names>T</given-names></string-name></person-group>. <year>2022</year>. <article-title>A life cycle assessment of organic and chemical fertilizers for coffee production to evaluate sustainability toward the energy&#x2013;environment&#x2013;economic nexus in Indonesia</article-title>. <source>Sustainability</source>. <volume>14</volume>:<fpage>3912</fpage>. <pub-id pub-id-type="doi">10.3390/su14073912</pub-id></mixed-citation></ref>
<ref id="ref75"><mixed-citation publication-type="journal"><person-group person-group-type="author"><collab>Redazione Beverfood.com</collab></person-group>. <year>2024</year>. <article-title>Report Beverfood.com sul mercato del caff&#x00E8; in Italia 2023: import, export e consumi</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.beverfood.com/report-beverfoodcom-mercato-caffe-italia-2023-import-export-e-consumi-wd/">https://www.beverfood.com/report-beverfoodcom-mercato-caffe-italia-2023-import-export-e-consumi-wd/</ext-link> (Accessed on: 11 July 2025).</mixed-citation></ref>
<ref id="ref76"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Ridder</surname> <given-names>M</given-names></string-name></person-group>. <year>2024</year>. <article-title>Major coffee importing countries worldwide 2023</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.statista.com/statistics/1096400/main-import-countries-for-coffee-worldwide/">https://www.statista.com/statistics/1096400/main-import-countries-for-coffee-worldwide/</ext-link> (Accessed on: 11 July 2025).</mixed-citation></ref>
<ref id="ref77"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Ridder</surname> <given-names>M</given-names></string-name></person-group>. <year>2025</year>. <article-title>Major coffee exporting countries worldwide 2024</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.statista.com/statistics/1096413/main-export-countries-for-coffee-worldwide/">https://www.statista.com/statistics/1096413/main-export-countries-for-coffee-worldwide/</ext-link> (Accessed on: 11 July 2025).</mixed-citation></ref>
<ref id="ref78"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Sala</surname> <given-names>S</given-names></string-name>., <string-name><surname>Cerutti</surname> <given-names>A.K</given-names></string-name>., and <string-name><surname>Pant</surname> <given-names>R</given-names></string-name></person-group>. <year>2018</year>. <article-title>Development of a Weighting Approach for the Environmental Footprint</article-title>. <source>Publications Office, European Union, Luxembourg</source>. <ext-link ext-link-type="uri" xlink:href="https://op.europa.eu/en/publication-detail/-/publication/6c24e876-4833-11e8-be1d-01aa75ed71a1/language-en">https://op.europa.eu/en/publication-detail/-/publication/6c24e876-4833-11e8-be1d-01aa75ed71a1/language-en</ext-link> (Accessed on: 16 May 2025).</mixed-citation></ref>
<ref id="ref79"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Sala</surname> <given-names>S</given-names></string-name>., <string-name><surname>Crenna</surname> <given-names>E</given-names></string-name>., <string-name><surname>Secchi</surname> <given-names>M</given-names></string-name>., and <string-name><surname>Pant</surname> <given-names>R</given-names></string-name></person-group>. <year>2017</year>. <article-title>Global normalisation factors for the environmental footprint and life cycle assessment</article-title>. <source>JRC scientific report</source>. <publisher-name>Publications Office</publisher-name>, <publisher-loc>European Union, Luxembourg</publisher-loc>. <ext-link ext-link-type="uri" xlink:href="https://op.europa.eu/en/publication-detail/-/publication/3ec9e2cb-f1cc-11e7-9749-01aa75ed71a1/language-en">https://op.europa.eu/en/publication-detail/-/publication/3ec9e2cb-f1cc-11e7-9749-01aa75ed71a1/language-en</ext-link> (Accessed on: 16 May 2025).</mixed-citation></ref>
<ref id="ref80"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Sarmento dos Muchangos</surname> <given-names>L</given-names></string-name>., <string-name><surname>Mejia</surname> <given-names>C</given-names></string-name>., <string-name><surname>Gupta</surname> <given-names>R</given-names></string-name>., <string-name><surname>Sadreghazi</surname> <given-names>S</given-names></string-name>., and <string-name><surname>Kajikawa</surname> <given-names>Y</given-names></string-name></person-group>. <year>2025</year>. <article-title>A systematic review of life cycle assessment and environmental footprint for the global coffee value chain</article-title>. <source>Environ Impact Assess Rev</source>. <volume>111</volume>:<fpage>107740</fpage>. <pub-id pub-id-type="doi">10.1016/j.eiar.2024.107740</pub-id></mixed-citation></ref>
<ref id="ref81"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Schwizgebel</surname> <given-names>C</given-names></string-name>., <string-name><surname>Napierska</surname> <given-names>D</given-names></string-name>., <string-name><surname>Copello</surname> <given-names>L</given-names></string-name>., <string-name><surname>Veillard</surname> <given-names>L</given-names></string-name>., <string-name><surname>Musso</surname> <given-names>M</given-names></string-name>., <string-name><surname>Falkenberg</surname> <given-names>M</given-names></string-name>., and <string-name><surname>Lujan</surname> <given-names>T</given-names></string-name></person-group>. <year>2025</year>. <article-title>Packaging and packaging waste regulation implementation</article-title>. <ext-link ext-link-type="uri" xlink:href="https://rethinkplasticalliance.eu/wp-content/uploads/2025/03/PPWR-implementation-guide-for-national-and-local-governments.pdf">https://rethinkplasticalliance.eu/wp-content/uploads/2025/03/PPWR-implementation-guide-for-national-and-local-governments.pdf</ext-link> (Accessed on: 12 May 2025).</mixed-citation></ref>
<ref id="ref82"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Shabbir</surname> <given-names>S</given-names></string-name></person-group>. <year>2024</year>. <article-title>Coffee brewing methods: 16 different ways to make it</article-title>. <ext-link ext-link-type="uri" xlink:href="https://coffeebrewster.com/coffee-brewing-methods/">https://coffeebrewster.com/coffee-brewing-methods/</ext-link> (Accessed on: 27 May 2025).</mixed-citation></ref>
<ref id="ref83"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Shahbandeh</surname> <given-names>M</given-names></string-name></person-group>. <year>2024</year>. <article-title>Global UTZ certified coffee production volume 2011&#x2013;2023</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.statista.com/statistics/758463/utz-certified-coffee-production-volume-worldwide/">https://www.statista.com/statistics/758463/utz-certified-coffee-production-volume-worldwide/</ext-link> (Accessed on: 26 May 2025).</mixed-citation></ref>
<ref id="ref84"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Shahbandeh</surname> <given-names>M</given-names></string-name></person-group>. <year>2025</year>. <article-title>Coffee production worldwide in 2023/24, by region (in million 60-kilogram bags)</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.statista.com/statistics/545433/global-coffee-production-region/">https://www.statista.com/statistics/545433/global-coffee-production-region/</ext-link> (Accessed on: 21 May 2025).</mixed-citation></ref>
<ref id="ref85"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>Sustainable Plastics</collab></person-group>. <year>2020</year>. <article-title>Ingeo-based GEA coffee capsules comply with industrial composting standard</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.sustainableplastics.com/news/ingeo-based-gea-coffee-capsules-comply-industrial-composting-standard">https://www.sustainableplastics.com/news/ingeo-based-gea-coffee-capsules-comply-industrial-composting-standard</ext-link> (Accessed on:18 May 2023).</mixed-citation></ref>
<ref id="ref86"><mixed-citation publication-type="journal"><person-group person-group-type="author"><string-name><surname>Vasuki</surname> <given-names>M.T</given-names></string-name>., <string-name><surname>Kadirvel</surname> <given-names>V</given-names></string-name>., and <string-name><surname>Pejavara Narayan</surname> <given-names>G</given-names></string-name></person-group>. <year>2023</year>. <article-title>Smart packaging&#x2014;an overview of concepts and applications in various food industries</article-title>. <source>Food Bioeng</source>. <volume>2</volume>(<issue>1</issue>):<fpage>25</fpage>&#x2013;<lpage>41</lpage>. <pub-id pub-id-type="doi">10.1002/fbe2.12038</pub-id></mixed-citation></ref>
<ref id="ref87"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Wang</surname> <given-names>A</given-names></string-name></person-group>. <year>2021</year>. <article-title>Application of laser particle size analyzer in coffee</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.3p-instruments.com/wp-content/uploads/2021/06/Application-of-Laser-Particle-Size-Analyzer-In-Coffee.pdf">https://www.3p-instruments.com/wp-content/uploads/2021/06/Application-of-Laser-Particle-Size-Analyzer-In-Coffee.pdf</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref88"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>World Bank</collab></person-group>. <year>2020</year>. <article-title>Why biodiversity matters to your daily cup of coffee: preserving the birthplace of wild Arabica coffee in Ethiopia&#x2019;s highlands</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.worldbank.org/en/news/feature/2020/06/04/why-biodiversity-matters-to-your-daily-cup-of-coffee">https://www.worldbank.org/en/news/feature/2020/06/04/why-biodiversity-matters-to-your-daily-cup-of-coffee</ext-link> (Accessed on: 5 July 2025).</mixed-citation></ref>
<ref id="ref89"><mixed-citation publication-type="web"><person-group person-group-type="author"><collab>World Population Review</collab></person-group>. <year>2025</year>. <article-title>Coffee consumption by country 2025</article-title>. <ext-link ext-link-type="uri" xlink:href="https://worldpopulationreview.com/country-rankings/coffee-consumption-by-country">https://worldpopulationreview.com/country-rankings/coffee-consumption-by-country</ext-link> (Accessed on: 11 May 2025).</mixed-citation></ref>
<ref id="ref90"><mixed-citation publication-type="web"><person-group person-group-type="author"><string-name><surname>Yaqub</surname> <given-names>M</given-names></string-name></person-group>. <year>2025</year>. <article-title>Coffee consumption statistics: a must know in 2025</article-title>. <ext-link ext-link-type="uri" xlink:href="https://www.coffeedasher.com/coffee-consumption-statistics/">https://www.coffeedasher.com/coffee-consumption-statistics/</ext-link> (Accessed on: 11 May 2025).</mixed-citation></ref>
<ref id="ref91"><mixed-citation publication-type="journal"><person-group person-group-type="author"><collab>YouGov&#x00AE;</collab></person-group>. <year>2021</year>. <article-title>Italian coffee report 2021: analysis of coffee consumption in Italy</article-title>. <source>Coffee Promotion Consortium</source>. <ext-link ext-link-type="uri" xlink:href="https://www.caffebenessere.it/wp-content/uploads/2022/02/YouGov_Coffee_Study_ITA.pdf">https://www.caffebenessere.it/wp-content/uploads/2022/02/YouGov_Coffee_Study_ITA.pdf</ext-link> (Accessed on: 11 May 2025).</mixed-citation></ref>
</ref-list>
</back>
</article>